In an aspect, a plurality of artificial melanin nanoparticles are provided, wherein: each melanin nanoparticle of the plurality of artificial melanin nanoparticles comprises a plurality of melanin oligomers; each melanin oligomer comprises a plurality of covalently-bonded melanin base units; and each melanin base unit comprises substituted or unsubstituted naphthalene. In an aspect, porous artificial melanin materials and methods of synthesizing porous artificial melanin materials are provided.

An object is to obtain a composition capable of: forming a uniform film even by spray coating or even when the composition is applied in the form of ink for inkjet printing; and preventing light emission from a portion other than an ITO electrode surface when the film is mounted on an organic EL device and light is emitted from the device. A conductive polymer composition contains: a composite containing a π-conjugated polymer (A) and a polymer (B) shown by a general formula (1); H.sub.2O (D) for dispersing the composite; a water-soluble organic solvent (C); and a compound (E) shown by a general formula (2). The electric conductivity of a film with a thickness of 20 to 200 nm formed from the conductive polymer composition is less than 1.00E-05 S/cm.

##STR00001##

The present disclosure relates to a responsive polymer film, a method of preparing the responsive polymer film, and a sensor using the polymer film.

An electrically conductive material includes an anionic polymer having a polymer backbone that is bonded to a plurality of terminal catechol moieties and a plurality of terminal sulfonate moieties. It also includes a cationic polymer including poly(3,4-ethylenedioxythiophene).

A conductive composition comprising a conductive polymer (A), a water-soluble polymer (B), and a solvent (C1), wherein: the water-soluble polymer (B) comprises a water-soluble polymer (B11) represented by formula (11), and an amount of a water-soluble polymer (B2) represented by formula (2) as the water-soluble polymer (B) is 0.15% by mass or less, based on a total mass of the conductive composition:

##STR00001##

wherein R.sup.1 denotes a linear or branched alkyl group with 6 to 20 carbon atoms, each of R.sup.4 and R.sup.5 independently denotes a methyl or ethyl group, R.sup.6 denotes a hydrophilic group, R.sup.7 denotes a hydrogen atom or a methyl group, Y.sup.1 denotes a single bond, —S—, —S(═O)—, —C(═O)—O— or —O—, Z denotes a cyano group or a hydroxy group, each of p1 and q denotes an average number of repetitions, and is a number of from 1 to 50, and m denotes a number of from 1 to 5.

A composite conductive polymer, a preparation method thereof and application thereof are disclosed, wherein a mixed solution A is used in the preparation process of the composite conductive polymer, which comprises the following two components: (i) a strong oxidant selected from at least one of permanganate, persulfate, dichromate and perchlorate; (ii) an oxidizing agent containing a metal ion capable of being reduced to elementary substance. The preparation process is simple and easy to operate, with low cost and favorable environmental protection and the obtained composite conductive polymer containing metal in elementary form, has good film-forming property and the film thereof can completely cover the surface of the insulating substrate, with excellent electrical conductivity, which therefore can be widely used in electroplating materials and semiconductor materials and other fields.

A copolymer, poly(thiophene-co-benzothiophene-co-dibenzothiophene), and method of preparation thereof. The copolymer, poly(thiophene-co-benzothiophene-co-dibenzothiophene), having a formula (I):

##STR00001##

wherein x=H or R, y=H or R, z=H or R, and n=500-58000, wherein R is selected from alkyl or alicyclic chain substituents, and Ar is an aromatic ring.

A polythiophene derivative including a repeating unit represented by General Formula (1) below:

##STR00001## where R.sup.1 and R.sup.2 each independently denote a group having from 2 through 9 carbon atoms represented by —(R.sup.3—S).sub.p—R.sup.4 (where R.sup.3 denotes an alkylene group having from 1 through 4 carbon atoms, R.sup.4 denotes an alkyl group having from 1 through 6 carbon atoms or an aromatic group having from 5 through 6 carbon atoms, and p denotes an integer of 1 or 2), Ar denotes an optionally substituted divalent or monovalent aromatic ring moiety or aromatic heterocyclic moiety, m denotes a natural number of 2 or more, and n denotes a natural number of 0 or 2 or more.

A method for preparing a magnetic chain structure is provided. The method comprises providing a plurality of magnetic particles; dispersing the plurality of magnetic particles in a solution comprising a dopamine-based material to form a reaction mixture; applying a magnetic field across the reaction mixture to align the magnetic particles in the reaction mixture; and polymerizing the dopamine-based material on the aligned magnetic particles to obtain the magnetic chain structure. A magnetic chain structure prepared by the method is also provided.

A mechanical ball-milling method for preparing a polydopamine-modified montmorillonite nanomaterial is disclosed. The method includes dispersing a montmorillonite material in an aqueous solution, stirring, concentrating and collecting a concentrated montmorillonite solution for use; adding dopamine hydrochloride to a buffer solution to prepare a dopamine hydrochloride solution, with a concentration of 0.2-1 g/mL, and adjusting the pH value of the dopamine hydrochloride solution; and adding the dopamine hydrochloride solution and the concentrated montmorillonite solution simultaneously into a ball mill jar to form a mixture, and then subjecting the mixture to a ball milling for 0.3-6 hours, pouring the mixture out of the ball mill jar, and subjecting to a solid-liquid separation by a centrifugation, and then washing a solid product with deionized water for 3-6 times, and removing water from the solid product, to obtain the polydopamine-modified montmorillonite nanomaterial.