C08G2261/72

Thiol-Based Post-Modification of Conjugated Polymers

The present invention provides novel polymer compounds and methods and processes for polymerizing and synthesizing the new polymers by post-modifying conjugated polymers bearing unsaturated functionalities. The post-modifications are facilitated by light-mediated initiators, thermal initiators, redox-based initiators, small molecule-based initiators, or a combination thereof. Syntheses and post-modifications are carried out to high conversion via thiol-ene click chemistry-based mechanisms. The products comprise monomeric, oligomeric, and polymeric materials with easily-accessible pendant functionalities which impart new, distinct, and/or improved properties.

Ladder tetrazine polymers

A ladder tetrazine polymer is disclosed.

Dibenzosilole monomers and polymers and methods for their preparation and use

Water-soluble, conjugated polymers containing one or more dibenzosilole monomer residues, as well as compositions, kits, and methods of making and using such polymers are disclosed. Also disclosed are dibenzosilole derivatives substituted with one or more water-solubilizing groups, and methods of making and using such derivatives to prepare water-soluble dibenzosilole polymers.

ASSOCIATIVE POLYMERS AND RELATED COMPOSITIONS, METHODS AND SYSTEMS
20200040141 · 2020-02-06 ·

Described herein are associative polymers capable of controlling a physical and/or chemical property of non-polar compositions and related compositions, methods and systems. Associative polymers herein described have a non-polar backbone and functional groups presented at ends of the non-polar backbone, with a number of the functional groups presented at the ends of the non-polar backbone formed by associative functional groups capable of undergoing an associative interaction with another associative functional group with an association constant (k) such that the strength of each associative interaction is less than the strength of a covalent bond between atoms and in particular less than the strength of a covalent bond between backbone atoms.

HYDROCARBON-BASED POLYMERS BEARING TWO ALKOXYSILANE END GROUPS

Hydrocarbon-based polymer of formula (1) bearing alkoxysilane end groups:

##STR00001## in which: custom-character is a double or single bond; each of R.sub.2, R.sub.3, R.sub.4 and R.sub.5 is H, a halo, an alkoxycarbonyl or an alkyl, m and p are each from 0 to 5, each of R and R is an alkyl, Z is an alkylene, optionally interrupted with COO, q is 0 or 1, r is 0, 1 or 2, and n is an integer such that the number-average molar mass Mn of the polymer is from 400 to 50 000 g/mol, and its polydispersity index (PDI) is from 1.0 to 2.0.

Preparation by ring-opening metathesis polymerization for 2 hours to 24 hours.

Adhesive composition comprising polymer (1) and crosslinking catalyst. Bonding by assembly of two substrates using this adhesive composition.

LADDER TETRAZINE POLYMERS
20200028087 · 2020-01-23 ·

A ladder tetrazine polymer is disclosed.

Composite polydots and applications thereof

The present invention relates to nanoparticle compositions and, in particular, to composite polymeric nanoparticle compositions. A composite nanoparticle described herein comprises a photoluminescent polymeric component and a photo-thermal polymeric component. The photoluminescent polymeric component and the photo-thermal polymeric component can each comprise a single polymeric species or multiple polymeric species.

Anionic electrochemical compressor and refrigeration system employing same
11940195 · 2024-03-26 · ·

An electrochemical compressor utilizes an anion conducting layer disposed between an anode and a cathode for transporting a working fluid. The working fluid may include carbon dioxide that is dissolved in water and is partially converted to carbonic acid that is equilibrium with bicarbonate anion. An electrical potential across the anode and cathode creates a pH gradient that drives the bicarbonate anion across the anion conducting layer to the cathode, wherein it is reformed into carbon dioxide. Therefore, carbon dioxide is pumped across the anion conducting layer. The compressor may be part of a refrigeration system that pumps the working fluid in a closed loop through a condenser and an evaporator.

Anion exchange polymers and anion exchange membranes incorporating same
11918959 · 2024-03-05 · ·

An anion exchange membrane is made by mixing 2 trifluoroMethyl Ketone [nominal] (1.12 g, 4.53 mmol), 1 BiPhenyl (0.70 g, 4.53 mmol), methylene chloride (3.0 mL), trifluoromethanesulfonic acid (TFSA) (3.0 mL) to produce a pre-polymer. The pre-polymer is then functionalized to produce an anion exchange polymer. The pre-polymer may be functionalized with trimethylamamine in solution with water. The pre-polymer may be imbibed into a porous scaffold material, such as expanded polytetrafluoroethylene to produce a composite anion exchange membrane.

Blue-excitable water-solvated polymeric dyes

Water solvated polymeric dyes and polymeric tandem dyes having a blue excitation spectrum are provided. The polymeric dyes are conjugated polymers that can include a thiophene-containing co-monomer. The polymeric tandem dyes further include a signaling chromophore covalently linked to the conjugated polymer in energy-receiving proximity therewith. Also provided are labelled specific binding members that include the subject polymeric dyes. Methods of evaluating a sample for the presence of a target analyte and methods of labelling a target molecule in which the subject polymeric dyes find use are also provided. Systems and kits for practicing the subject methods are also provided.