1) Hydrocarbon-based polymer of formula (I): ##STR00001## in which F.sup.1 and F.sup.2 have the respective formulae (IIa) and (IIb) or (IIa) and (IIb): ##STR00002## a process for its preparation, and use as an adhesive.

1) Hydrocarbon polymer having two azlactone end groups ##STR00001##
F.sup.1 is formula (IIa) and F.sup.2 is formula (IIb): ##STR00002## g and d are 0, 1, 2 or 3; R.sup.14 and R.sup.15 are C.sub.1-C.sub.4 or a cyclohexyl radical; R.sup.1 to R.sup.12 represents hydrogen or alkyl with 1 to 22 carbon atoms; x and y are integers, x+y is 0 to 2; R.sup.13 is oxygen or sulphur or divalent CH.sub.2 n1, n2, m, p1 and p2 are an integer or equal to 0 and such that the molecular weight Mn of the polymer of formula (I) is between 400 and 100 000 g/mol; a process for preparation of the polymer; and use as adhesive in mixture with an amino compound with at least two amine groups.

The invention provides a class of wedge-type block copolymers having a plurality of chemically different blocks, at least a portion of which incorporates a wedge group-containing block providing useful properties. For example, use of one or more wedge group-containing blocks in some block copolymers of the invention significantly inhibits chain entanglement and, thus, the present block copolymers materials provide a class of polymer materials capable of efficient molecular self-assembly to generate a range of structures, such as periodic nanostructures and microstructures. Materials of the present invention include copolymers having one or more wedge group-containing blocks, and optionally for some applications copolymers also incorporating one or more polymer side group-containing blocks. The present invention also provides useful methods of making and using wedge-type block copolymers.

A dicarbamate telechelic unsaturated polyolefin pre-polymer comprising a reaction product of reacting alkyl-cis-cyclooctene and optionally cis-cyclooctene, in the presence of a multifunctional chain transfer agent possessing two or more amino groups wherein the two or more amino groups are protected by one or more protecting groups under ring opening metathesis polymerization conditions is provided.

There are provided a novel cyclic olefin compound having a photoreactive group and a photoreactive polymer. The cyclic olefin compound is applicable to various photoreactions, such as of liquid crystal alignment layers and can be preferably used as a precursor of various organic compounds or polymers.

A process to produce a polyolefin reactive telechelic pre-polymer comprising reacting alkyl-c/5-cyclooctene and optionally czs-cyclooctene, in the presence of a multifunctional chain transfer agent possessing two or more amino groups wherein the two or more amino groups are protected by one or more protecting groups under ring opening metathesis polymerization conditions to form a dicarbamate telechelic unsaturated polyolefm pre-polymer is provided.

A method of forming a polymer comprising a conjugated backbone and side-groups pendant from the conjugated backbone wherein the method comprises the steps of: polymerizing one or more monomers to form a precursor polymer comprising the conjugated backbone and precursor groups pendant from the conjugated backbone, and subsequently converting the precursor groups to the side-groups.

A carbazole-based graft copolymer capable of controlling a self-assembled structure and a method of synthesizing the same are provided. Specifically, the copolymer is capable of controlling a self-assembled structure which can control the morphology of a polymer structure and the size of pores by controlling the molecular weights of polylactic acid (PLA) functioning as a coil and of a carbazole copolymer to prepare a poly(carbazole)-coil graft copolymer of Formula 1 below and the method of synthesizing the same is provided. In Formula 1, X represents 0.05 to 0.1, m represents an integer of 7 to 8, and n represents an integer of 56 to 84. ##STR00001##

A carbazole-based graft copolymer capable of controlling a self-assembled structure and a method of synthesizing the same are provided. Specifically, the copolymer is capable of controlling a self-assembled structure which can control the morphology of a polymer structure and the size of pores by controlling the molecular weights of polylactic acid (PLA) functioning as a coil and of a carbazole copolymer to prepare a poly(carbazole)-coil graft copolymer of Formula 1 below and the method of synthesizing the same is provided. In Formula 1, X represents 0.05 to 0.1, m represents an integer of 7 to 8, and n represents an integer of 56 to 84.

##STR00001##

The present invention provides a method for producing polythiophene star copolymer capable of being self-doped by an external stimulus, which includes the steps of: forming a polythiophene macroinitiator made by introducing a living radical polymerizable functional group into an end of polythiophene or a derivative thereof; forming through living radical polymerization a polymer macroinitiator for providing by an external stimulus at least a dopant selected from the group consisting of sulfonic acid radical, carboxylic acid radical and phosphoric acid radical; and polymerizing the polythiophene macroinitiator added with the polymer macroinitiator and at least one kind of divinyl monomer to produce the polythiophene star copolymer. The polythiophene star copolymer capable of being self-doped by an external stimulus according to the present invention is a self-doped material to stably increase conductivity, and can be used as a material for a conductive film.