A novel dopant according to the present disclosure includes an anion represented by the following Formula (1) and a counter cation. In Formula (1), R.sup.1 and R.sup.2 may be each at least one group selected from a nitro group, a cyano group, an acyl group, a carboxyl group, an alkoxycarbonyl group, a haloalkyl group, a sulfo group, an alkylsulfonyl group, an halosulfonyl group, and a haloalkylsulfonyl group, or may be a group formed by R.sup.1 and R.sup.2 bonded to each other [—SO.sub.2-L-SO.sub.2—] (where L represents a haloalkylene group). The counter cation may be a radical cation represented by Formula (2), where R.sup.1 and R.sup.2 represent electron-withdrawing groups that may be bonded to each other to form a heterocycle, and R.sup.3 to R.sup.5 represent a hydrogen atom, a hydrocarbon group that may have a substituent, or a heterocyclic group that may have a substituent. The dopant is capable of forming an electroconductive composition that shows a high conductivity.

The invention relates to a novel composition comprising n-type organic semiconducting (OSC) polymers and p-type OSCs, to its use as organic semiconductors in, or for the preparation of, organic electronic (OE) devices, especially organic photovoltaic (OPV) devices, perovskite-based solar cell (PSC) devices, organic photo-detectors (OPD), organic field effect transistors (OFET) and organic light emitting diodes (OLED), and to OE, OPV, PSC, OPD, OFET and OLED devices comprising the compositions.

Provided is a dopant with which a conductor material having high electrical conductivity can be formed. The present disclosure relates to a dopant containing a radical cation represented by Formula (1) and a counter anion. In Formula (1), R.sup.1 to R.sup.3 may be the same or different, and each denotes a monovalent aromatic group or a group represented by Formula (r). at least one of R.sup.1 to R.sup.3 is a group represented by Formula (r), and n indicates the valence of the radical cation and is equal to the quantity (n) of nitrogen atoms in the formula. In Formula (r), Ar.sup.1, Ar.sup.2, and Ar.sup.3 may be the same or different, and each denotes a divalent aromatic group, and Ar.sup.4, Ar.sup.5, Ar.sup.6, and Ar.sup.7 may be the same or different, and each denotes a monovalent aromatic group optionally having a substituent represented by Formula (sb) below. Furthermore, m and n may be the same or different, and each represents an integer of 0 or greater.

##STR00001##

The invention relates to novel organic semiconducting compounds containing a polycyclic unit, to methods for their preparation and educts or intermediates used therein, to compositions, polymer blends and formulations containing them, to the use of the compounds, compositions and polymer blends as organic semiconductors in, or for the preparation of, organic electronic (OE) devices, especially organic photovoltaic (OPV) devices, perovskite-based solar cell (PSC) devices, organic photodetectors (OPD), organic field effect transistors (OFET) and organic light emitting diodes (OLED), and to OE, OPV, PSC, OPD, OFET and OLED devices comprising these compounds, compositions or polymer blends.

Described herein are compositions comprising hole carrier materials, typically conjugated polymers, and fluoropolymers ink compositions comprising hole carrier materials and fluoropolymers, and uses thereof, for example, in organic electronic devices.

A compound having the following formula:

##STR00001##

which can also be embedded into a conjugated oligomeric of polymeric backbone, is proposed for optical and electro optical applications.

The present specification relates to an organic solar cell including a first electrode; a second electrode; and one or more organic material layers including a photoactive layer, wherein the photoactive layer includes an electron donor and an electron acceptor, the electron donor includes a polymer including a first unit represented by Chemical Formula 1; a second unit represented by Chemical Formula 2; and a third unit represented by Chemical Formula 3, and the electron acceptor includes a non-fullerene-based compound.

The present invention relates to a process for the production of a layered body (1), at least comprising the process steps: I) provision of a photoactive layer comprising a material having a perovskite type crystal structure; II) superimposing the photoactive layer at least partially with a coating composition A) comprising an electrically conductive polymer a) and an organic solvent b); III) at least partial removal of the organic solvent b) from the coating composition A) superimposed in process step II), thereby obtaining an electrically conductive layer superimposed on the photoactive layer. The present invention also relates to a layered body obtainable by this process, to dispersions, to an electronic device, to a process for the preparation of a photovoltaic device and to the photovoltaic device that is obtainable by this process.

Described herein are compositions comprising hole carrier materials, typically conjugated polymers, and poly(aryl ether sulfones)s, ink compositions comprising hole carrier materials and poly(aryl ether sulfones)s, and uses thereof, for example, in organic electronic devices.

A composition comprising ##STR00001##
In this composition Ar1 is independently selected from the group consisting of: ##STR00002##
and Ar2 is selected from ##STR00003##
Additionally in this composition, R.sub.1, R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.9, R.sub.11, and R.sub.12 are independently selected from F, Cl, H, unsubstituted or substituted branched alkyls with 1 to 60 carbon atoms, and unsubstituted or substituted linear alkyls with 1 to 60 carbon atoms; and the compositional ratio of x/y ranges from about 1/99 to about 99/1, and n ranges from 1 to 1,000,000.