The present invention provides: a p-type organic semiconductor material which is able to be produced easily, while having high planarity in a polymer skeleton; and a photoelectric conversion layer, a photoelectric conversion element and an organic thin film solar cell, each of which uses this p-type organic semiconductor material and has high photoelectric conversion efficiency. The present invention specifically provides: a picene derivative which has at least one constituent unit represented by general formula (1); and a photoelectric conversion element which contains (A) the picene derivative serving as a p-type organic semiconductor material and (B) an n-type organic semiconductor material. The details of general formula (1) are as set forth in the description.

There is a conjugated polymer having a derivative of indacen-4-one having general formula (I): ##STR00001## wherein: R.sub.1 and R.sub.2, same or different, are selected from C.sub.1-C.sub.30 alkyl groups, linear or branched; optionally substituted cycloalkyl groups; optionally substituted aryl groups; optionally substituted heteroaryl groups; C.sub.1-C.sub.30 alkoxyl groups, linear or branched; R.sub.4—O—[CH.sub.2—CH.sub.2—O].sub.m— polyoxyethylene groups, wherein R.sub.4 is selected from C.sub.1-C.sub.30 alkyl groups, linear or branched, and m is an integer ranging from 1 to 4; —R.sub.5—OR.sub.6 groups, wherein R.sub.5 is selected from C.sub.1-C.sub.30 alkylene groups, linear or branched, and R.sub.6 represents a hydrogen atom or is selected from C.sub.1-C.sub.30 alkyl groups, linear or branched, or is selected from R.sub.4—[—OCH.sub.2—CH.sub.2—].sub.p— polyoxyethylene groups, wherein R.sub.4 has the same meanings as reported above and p is an integer ranging from 1 to 4; —COR.sub.7 groups, wherein R.sub.7 is selected from C.sub.1-C.sub.30 alkyl groups, linear or branched; —COOR.sub.8 groups, wherein R.sub.8 is selected from C.sub.1-C.sub.30 alkyl groups, linear or branched; or they represent a —CHO group or a cyano (—CN) group; R.sub.3 is selected from C.sub.1-C.sub.30 alkyl groups, linear or branched; optionally substituted cycloalkyl groups; optionally substituted aryl groups; and C.sub.1-C.sub.30 alkoxyl groups, linear or branched; n is an integer ranging from 10 to 500. There is also a photovoltaic device (or solar device) having a support having the conjugated polymer having a derivative of indacen-4-one.

Polymerize ethylenedioxythiophene (EDOT) in a polymerization process using dinonylnaphthalenesulfonic acid (DNNSA) as the dopant and Fe(III) p-toluenesulfonate (Fe (III) p-TSA) as the oxidizing agent to produce an organically soluble polyethylenedioxythiophene (PEDOT).

The present invention relates to new semiconducting compounds having at least one optionally substituted azino[1,2,3]thiadiazole moiety. The compounds disclosed herein can exhibit high carrier mobility and/or efficient light absorption/emission characteristics, and can possess certain processing advantages such as solution-processability and/or good stability at ambient conditions.

Various aspects of the present disclosure are directed to conjugated polymers, their manufacture and their implementations. As may be implemented in connection with one or more embodiments, an apparatus includes a conjugated polymer and a side chain or end chain material connected to the conjugated polymer. The amount and makeup of the side chain or end chain enhance solubility of the resulting modified conjugated polymer, relative to the conjugated polymer itself.

The invention relates to a process for producing a conjugated polymer blend. The process for producing the conjugated polymer blend comprises the mixture of: a polymer A (X-Y), where X is

##STR00001##

and Y is

##STR00002##

and h is a substituent, a polymer B (X-Y′) where X is

##STR00003##

Y′ is

##STR00004##

and j is a substituent, and an acceptor. In this process h and j are different substituents and independently selected from each other.

In one embodiment, a polymer includes a repeating unit represented by a formula (1) shown below. A weight-average molecular weight of the polymer is in a range of 3000 or more to 1000000 or less. ##STR00001##
R1 indicates a monovalent group selected from hydrogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aromatic group, and a substituted or unsubstituted hetero-aromatic group. R2, R3, and R4 indicate independently a monovalent group selected from hydrogen, halogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aromatic group, and a substituted or unsubstituted hetero-aromatic group. X, Y, and Z indicate independently an atom selected from O, S, and Se.

The invention relates to novel conjugated polymers containing one or more units based on dithieno[3,2-c;2′,3′-e]azepine-4,6-dione that is fused to further aromatic rings, to methods for their preparation and educts or intermediates used therein, to polymer blends, mixtures and formulations containing them, to the use of the polymers, polymer blends, mixtures and formulations as organic semiconductors in, or for the preparation of, organic electronic (OE) devices, especially organic photovoltaic (OPV) devices and organic photodetectors (OPD), and to OE, OPV and OPD devices comprising, or being prepared from, these polymers, polymer blends, mixtures or formulations.

The invention provides novel hydrophilic conjugated polymers, e.g., hydrophilic poly(arylene vinylenes) or PAVs, and preparation thereof, and methods and devices for their application in photovoltaics, and the resulting improved solar cells.

The organic semiconductor polymers relates to the synthesis of a carbazole-based ladder polymer. The synthesis of the ladder polymer includes forming a precursor conjugated polymer by Suzuki step growth polymerization of 2,7-dibromocarbazole with 1,4-dibromo-2,5-divinylbenzene, followed by end capping with 2-bromostyrene and 2-vinyl-phenylboronic acid. Then, the pendent vinyl groups are closed by ring-closing olefin metathesis to obtain the ladder polymer.