An anion-exchange membrane of the present invention includes a substrate made of polyolefin-based woven fabric and an anion-exchange resin, and has an electrical resistance measured using 0.5 M NaCl solution at 25° C. of 1.0 Ω•cm.sup.2 or more to 2.5 Ω•cm.sup.2 or less, a bursting strength of 0.7 MPa or more to 1.2 MPa or less, a water permeation rate measured using pressured water at 0.1 MPa of 300 ml/(m.sup.2•hr) or less, a thickness of the substrate of 90 .Math.m or more to 160 .Math.m or less, and an open area ratio of the substrate of 35% or more to 55% or less.

Described herein are anionic phenylene oligomers and polymers, and devices including these materials. The oligomers and polymers can be prepared in a convenient and well-controlled manner, and can be used in cation exchange membranes. Also described is the controlled synthesis of anionic phenylene monomers and their use in synthesizing anionic oligomers and polymers, with precise control of the position and number of anionic groups.

An object of the present invention is to provide an ion-exchange membrane for simply and inexpensively separating and purifying exosomes present in a biological sample such as serum. The invention relates to a cellulose-based ion-exchange membrane containing a cellulose-based polymer having at least one hydroxyl group or acetyl group at the 2-, 3-, or 6-position being replaced with a positively charged compound. The invention also relates to a method for purifying exosomes, including subjecting a sample containing exosomes to membrane permeation by using the cellulose-based ion-exchange membrane to allow for adsorption of the exosomes, bringing the membrane into contact with a washing liquid to remove impurities, and bringing the membrane into contact with an eluent to allow for desorption of the exosomes.

The invention is in the field of methods for preparing polymer films, and of such polymer films. The method involves phase separation and requires only aqueous solution, eliminating the need for organic solvents. The aqueous phase separation involves contacting a polymer solution comprising a trigger-responsive polymer with an aqueous coagulation solution in which the trigger-responsive polymer is not soluble.

A monolithic organic porous ion exchanger having a continuous skeleton and continuous pores, wherein the continuous skeleton is formed of an organic polymer being a hydrolysate of a crosslinked polymer of a (meth)acrylic acid ester and divinylbenzene, the organic polymer having any one or both of a —COOH group and a —COONa group as ion-exchange groups, the continuous skeleton has a thickness of 0.1 to 100 μm, the continuous pores have an average diameter of 1.0 to 1000 μm, the monolithic organic porous ion exchanger has a total pore volume of 0.5 to 50.0 mL/g, and has a total ion-exchange capacity of the —COOH group and the —COONa group per weight in a dry state of 4.0 mg equivalent/g or more.

A monolithic organic porous ion exchanger having a continuous skeleton and continuous pores, wherein the continuous skeleton is formed of an organic polymer being a hydrolysate of a crosslinked polymer of a (meth)acrylic acid ester and divinylbenzene, the organic polymer having any one or both of a —COOH group and a —COONa group as ion-exchange groups, the continuous skeleton has a thickness of 0.1 to 100 μm, the continuous pores have an average diameter of 1.0 to 1000 μm, the monolithic organic porous ion exchanger has a total pore volume of 0.5 to 50.0 mL/g, and has a total ion-exchange capacity of the —COOH group and the —COONa group per weight in a dry state of 4.0 mg equivalent/g or more.

An anion exchange membrane is composed of a copolymer of 1,1-diphenylethylene and one or more styrene monomers, such as 4-tert-butylstyrene. The copolymer includes a backbone substituted with a plurality of ionic groups coupled to phenyl groups on the backbone via hydrocarbyl tethers between about 1 and about 7 carbons in length. High-temperature conditions enabled by these copolymers enhance conductivity performance, making them particularly suitable for use in anion exchange membranes in fuel cells, electrolyzers employing hydrogen, ion separations, etc. The properties of the membranes can be tuned via the degree of functionalization of the phenyl groups and selection of the functional groups, such as quaternary ammonium groups. Several processes can be used to incorporate the desired ionic functional groups into the polymers, such as chloromethylation, radical bromination, Friedel-Crafts acylation and alkylation, sulfonation followed by amination, or combinations thereof.

Ion exchange membranes obtainable by curing a composition comprising: (a) a monomer comprising an aromatic group and at least one polymerisable ethylenically unsaturated group; (b) a photoinitiator which has an absorption maximum at a wavelength longer than 380 nm when measured in one or more of the following solvents at a temperature of 23° C.: water, ethanol and toluene; and (c) at least one co-initiator.

Provided is a multilayer film that is excellent in chemical resistance without change in appearance and reduction in adhesive strength by preventing the swelling of a thermoplastic polyurethane layer when a chemical attaches thereto. A layer adjacent to a surface coating layer in the thermoplastic polyurethane layer of the multilayer film is constituted by a thermoplastic polyurethane that is a reaction product obtained by using hexamethylene diisocyanate (hereinafter, referred to as “HDI”), and comprises more than 30% of the thermoplastic polyurethane formed from HDI, and the thermoplastic polyurethane layer formed from HDI has a thickness of 5 μm or larger. This achieves a multilayer film that is excellent in chemical resistance without change in appearance and reduction in adhesive strength by preventing the swelling of a thermoplastic polyurethane layer when a chemical attaches thereto.

Provided is a multilayer film that is excellent in chemical resistance without change in appearance and reduction in adhesive strength by preventing the swelling of a thermoplastic polyurethane layer when a chemical attaches thereto. A layer adjacent to a surface coating layer in the thermoplastic polyurethane layer of the multilayer film is constituted by a thermoplastic polyurethane that is a reaction product obtained by using hexamethylene diisocyanate (hereinafter, referred to as “HDI”), and comprises more than 30% of the thermoplastic polyurethane formed from HDI, and the thermoplastic polyurethane layer formed from HDI has a thickness of 5 μm or larger. This achieves a multilayer film that is excellent in chemical resistance without change in appearance and reduction in adhesive strength by preventing the swelling of a thermoplastic polyurethane layer when a chemical attaches thereto.