The present invention relates to a coated article comprising a partial or complete fluorinated coating on the surface of an article, wherein the coating comprises 5 to 99% by weight of a hydrophobic compound, and 1 to 95% by weight of a fluorinated surface effect agent, both based on the total solids weight of the coating, where the hydrophobic compound is selected from a hydrophobic cyclic or acyclic ester alcohol.

Provided is an anti-fogging coated transparent article including an anti-fog film, the anti-fog film being a single-layer film containing a water-absorbent resin, a hydrophobic group, and a metal oxide component. The hydrophobic group is a chain or cyclic alkyl group having 1 to 30 carbon atoms, preferably a linear alkyl group having 6 to 14 carbon atoms, in which at least one hydrogen atom is optionally substituted by a fluorine atom. The hydrophobic group is bonded directly to a metal atom of the metal oxide component. The anti-fog film contains, for example, the metal oxide component in an amount of 0.01 to 60 parts by mass and the hydrophobic group in an amount of 0.05 to 10 parts by mass per 100 parts by mass of the water-absorbent resin. The water-absorbent resin is, for example, polyvinyl acetal.

An anti-fog coating composition to form a crosslinked film comprising a prepolymer and at least one amine bearing crosslinker is disclosed. The prepolymer comprises one or more charged monomer residues, one or more hydrophilic uncharged monomer residues, and one or more amine reactive monomer residues. The crosslinked film has a change in haze value of less than 30% when exposed to fog conditions for a period longer than 30 seconds. A kit comprising a first compartment comprising the prepolymer and a second compartment comprising the amine bearing crosslinker is also disclosed. The anti-fog film and a coated article comprising the anti-fog coating are also described herein. A method of making anti-fog coated substrate by applying the composition thereto is also disclosed.

Provided is a barrier film, comprising: a base layer; and an inorganic layer including a first region and a second region, which have different elemental contents (atomic %) of Si, N, and O from each other as measured by XPS, and having a compactness expressed through an etching rate of 0.17 nm/s or less in the thickness direction for an Ar ion etching condition to etch Ta.sub.2O.sub.5 at a rate of 0.09 nm/s, wherein the second region has a higher elemental content of N than that of the first region, the first region has a thickness of 50 nm or more, and the ratio (d1/d2) of the thickness (d1) of the first region to the thickness (d2) of the second region is 2 or less, the barrier film having excellent barrier properties and optical properties. The barrier film can be used for electronic products sensitive to moisture or the like.

Provided is a barrier film, comprising: a base layer; and an inorganic layer including a first region and a second region, which have different elemental contents (atomic %) of Si, N, and O from each other as measured by XPS, and having a compactness expressed through an etching rate of 0.17 nm/s or less in the thickness direction for an Ar ion etching condition to etch Ta.sub.2O.sub.5 at a rate of 0.09 nm/s, wherein the second region has a higher elemental content of N than that of the first region, the first region has a thickness of 50 nm or more, and the ratio (d1/d2) of the thickness (d1) of the first region to the thickness (d2) of the second region is 2 or less, the barrier film having excellent barrier properties and optical properties. The barrier film can be used for electronic products sensitive to moisture or the like.

Provided is a transparent member having formed thereon a film having high reliability, the film being capable of suppressing an increase in its haze and maintaining its hydrophilicity for a long time period even when exposed to an outdoor environment. The transparent member is a transparent member including a resin base material and a porous layer arranged thereon, wherein the porous layer has a network structure in which silica particles are joined to each other with a binder, wherein the resin base material has a mixed layer that the network structure has entered, wherein the mixed layer has a thickness of 20 nm or more and 160 nm or less, and wherein a thickness variation in a range having a length of 1 ?m of a section of the mixed layer in its thickness direction along the surface of the resin base material is 15% or less.

Provided is a transparent member having formed thereon a film having high reliability, the film being capable of suppressing an increase in its haze and maintaining its hydrophilicity for a long time period even when exposed to an outdoor environment. The transparent member is a transparent member including a resin base material and a porous layer arranged thereon, wherein the porous layer has a network structure in which silica particles are joined to each other with a binder, wherein the resin base material has a mixed layer that the network structure has entered, wherein the mixed layer has a thickness of 20 nm or more and 160 nm or less, and wherein a thickness variation in a range having a length of 1 ?m of a section of the mixed layer in its thickness direction along the surface of the resin base material is 15% or less.

The invention relates to a method for preparing an optical system item having a non-zero radius of curvature and coated with an interference coating. Said method includes: a) providing a thermoplastic film coated with a multilayer interference coating containing at least one layer having a refractive index of greater than 1.65 and at least one layer having a refractive index of less than or equal to 1.65, at least one of the interference coating layers being a vacuum-deposited organic/inorganic layer, b) laminating said coated thermoplastic film, by means of an adhesive layer, onto an optical system item including a substrate, and c) recovering said optical system item, including a substrate coated with the adhesive layer, from the thermoplastic film and the multilayer interference coating.

Articles having poly(vinyl alcohol) (PVA) and silica nanoparticle multilayer coatings are provided. More specifically, the articles include a substrate and a multilayer coating attached to the substrate. The multilayer coating includes a silica layer that is the outermost layer, the silica layer containing acid-sintered interconnected silica nanoparticles arranged to form a continuous three-dimensional porous network. The multilayer coating also includes a PVA layer disposed between a surface of the substrate and the outermost silica layer. The PVA and silica nanoparticle coatings can be used on a large variety of substrates and tend to be resistant to impacts, scratches, wet abrasions, soil and fog.

A polymer brush includes a substrate material, a polymerization initiator layer containing a hydrolysis and condensation polymerization polymer comprising a first organosilane and a metal alkoxide on a surface of said substrate material, and polymer chains extending from a surface of the polymerization initiator layer. The first organosilane is a polymerization initiator group-containing organosilane having the following formula (I): XR.sup.1-Ph-(R.sup.2).sub.mSiR.sup.3.sub.nR.sup.4.sub.3-n . . . (I) where X stands for a halogen atom, R.sup.1 stands for an alkylene group having 1 to 3 carbon atoms, Ph stands for a phenylene group, R.sup.2 stands for a C1 to C10 alkylene group optionally via an oxygen atom, R.sup.3 stands for an alkoxy group having 1 to 3 carbon atoms or chloro group, R.sup.4 stands for an alkyl group having 1 to 6 carbon atoms, m is 0 or 1, n is 1, 2 or 3.