A formulation includes a base resin, a nucleating agent, and a blowing agent. The formulation can be used to form a container.

The present invention provides a polyolefin resin foam sheet having an area density of 5 g/m.sup.2 or more and 400 g/m.sup.2 or less, and satisfying at least one of the following conditions (1) and (2) in thermogravimetric-mass spectrometry carried out at a heating rate of 10° C.min over an entire measurement temperature range of a 200 to 550° C. measurement temperature, condition (1): a combustion gas generation ratio X defined as a ratio of a peak area value of an amount of a combustion gas P having a mass-to-charge ratio m/z of 55 generated at a measurement temperature of 200 to 364° C. with respect to the peak area value of an amount of the combustion gas P generated over the entire measurement temperature range is 25% or less; and condition (2): a combustion gas generation ratio Y defined as a ratio of a peak area value of an amount of a combustion gas Q having a mass-to-charge ratio m/z of 69 generated at a measurement temperature of 200 to 364° C. with respect to the peak area value of an amount of the combustion gas Q generated over the entire measurement temperature range is 25% or less.

According to the present invention, a polyolefin resin foam sheet can be provided that has a high fire retardancy while maintaining a lightweight property.

A barrier layer is provided. The barrier layer includes a porous structure, which includes a polymer material, an oxide and a fluoro-containing material. A chemical bond is formed between the oxide and the polymer material. The fluoro-containing material, the polymer material and the oxide are assembled as a composite structure.

The present invention relates to processes for the preparation of polyurethane foams comprising a step wherein a chemical compound with a low particle size releases a chemical and/or physical blowing agent by decomposition, polyurethane foams prepared by such processes as well as compositions comprising at least one polyol and a chemical compound with a low particle size capable of releasing a chemical and/or physical blowing agent by thermally- and/or chemically-induced degradation and uses of such compositions.

Disclosed herein is a method for producing polyurethane or polyisocyanurate foams. The method involves reacting a composition (Z1) with at least one polyisocyanate, and occurs in the presence of at least one nucleating agent and a blowing agent, in which the nucleating agent and the blowing agent are mixed to obtain a composition (Z2) that is added to the composition (Z1) before it is reacted with the at least one polyisocyanate. The composition (Z1) contains (i) 100 parts by mass of a composition (ZP) including at least one polyol and at least one catalyst that catalyzes formation of a urethane, urea or isocyanuarate bond, and (ii) from 0.05 to 10 parts by mass of a surfactant TD having an HLB value below 6 and no silicon atom.

To produce quickly and easily an open cell rigid polyurethane foam having a uniform and low density, a method for producing an open cell rigid polyurethane foam is provided, the method comprising foaming a mixed liquid of (1) a polyol-containing component comprising (a) a polyol mixture, (b) a catalyst, and (c) a foaming agent (c), and (2) a polyisocyanate component. The foaming agent consists of water and an adduct of a primary or secondary amine compound and carbon dioxide, the amount of the water is 10 to 80 parts by mass based on 100 parts by mass of the polyol mixture, and the amount of the adduct is 1 to 20 parts by mass based on 100 parts by mass of the polyol mixture.

Antioxidant-containing expandable resin particles including composite resin particles containing 100 to 400 parts by mass of polystyrene-based resin relative to 100 parts by mass of polypropylene-based resin, and a blowing agent and an antioxidant contained in the composite resin particles, wherein the polypropylene-based resin is abundantly present on the surface of the composite resin particles and poorly present at the center of the particles, and the composite resin particles contain 150 to 1500 ppm of antioxidant.

The present invention provides a recyclable flame-retardant expandable styrene-based resin composition that attains high flame retardancy and high heat stability with a small addition amount of a bromine-containing flame retardant. Specifically, the present invention provides a flame-retardant expandable styrene-based resin composition comprising a styrene-based resin (A), a flame retardant (B), fatty acid zinc (C), a heat stabilizer (D), and a foaming agent (F), wherein the flame retardant (B) comprises tetrabromobisphenol A-bis(2,3-dibromo-2-methylpropyl ether) (B1) and a bromine-containing flame retardant (B2) other than (B1).

The present disclosure relates to a resin composition for preparing polyolefin-based foamed articles having flame retardancy and flame retardant foamed articles formed therefrom. The resin composition according to the present disclosure can provide foamed articles having excellent flame retardancy and flame resistance while exhibiting a high fusion ratio and a low shrinkage ratio in the foam molding.

A spray foam formulation used to form a spray foam insulation layer in a wall structure is described. The formulation may include the reaction product of a polyisocyanate compound and a polyol compound; a fire retardant chosen from at least one of a non-halogenated fire retardant; and a reactive halogen-containing fire retardant, and a carbohydrate. The spray foam insulation layer has an insulative R value of 3.0 to 7.2 per inch, and a density of between about 0.3 to about 4.5 pcf. Further, spray foam insulation made from the spray foam formulation may have fire retardant characteristics that are equivalent to or better than a similar spray insulation foam insulation using non-reactive halogenated fire retardants such as tris(1-chloro-2-propyl)phosphate (TCPP).