Methods for manufacturing articles, including articles of footwear, apparel, and sporting equipment are provided. The methods comprise decorating a plurality of foam particles. The decorating can comprise applying a coating on the foam particles, or embossing or debossing the foam particles, or both. The decorating can comprise applying a coating on the foam particles by printing, painting, dyeing, applying a film, or any combination thereof. The plurality of foam particles are affixed utilizing aspects of additive manufacturing methods. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.

An expanded bead having a through hole and including a foamed core layer which defines the through hole therein and which is constituted of a resin composition containing two kinds of polypropylene-based resins having different melting points, and a cover layer covering the foamed core layer and constituted of a polyolefin-based resin. The expanded bead gives a DSC curve in which an endothermic peak intrinsic to the resin composition and another endothermic peak on a higher temperature side thereof appear in a specific heat of fusion ratio. Molded articles include a multiplicity of the expanded beads.

An expanded bead having a through hole and including a foamed core layer which defines the through hole therein and which is constituted of a resin composition containing two kinds of polypropylene-based resins having different melting points, and a cover layer covering the foamed core layer and constituted of a polyolefin-based resin. The expanded bead gives a DSC curve in which an endothermic peak intrinsic to the resin composition and another endothermic peak on a higher temperature side thereof appear in a specific heat of fusion ratio. Molded articles include a multiplicity of the expanded beads.

Disclosed are modified expanded polystyrene (EPS) particles and a modification method thereof, and concrete containing the modified EPS particles and a preparation method thereof, relating to the technical field of inorganic building materials. The modification method of the EPS particles includes following steps: (1) spraying adhesive materials on surfaces of the EPS particles in a stirring state, and obtaining the EPS particles with the adhesive materials attached to the surfaces; and (2) mixing the EPS particles attached with the adhesive materials with inorganic mixed materials to obtain the modified EPS particles. The preparation method of modified EPS concrete includes: mixing the modified EPS particles with a cementitious material, adding an admixture and water, and uniformly stirring to obtain the modified EPS concrete.

A process for producing shaped parts from particle foams comprising providing particle foam particles, wetting the particle foam particles with an aqueous emulsion of at least one polyolefin and thereby obtaining functionalisable particle foam particles, drying the wetted and functionalisable particle foam particles, shaping the functionalisable particle foam particles, heating the shaped functionalisable particle foam particles to a temperature below the melting range of the particle foam particles and thereby functionalising the shaped functionalisable particle foam particles, heating the shaped, functionalisable particle foam particles to a temperature below the melting range of the particle foam particles and thereby functionalising the shaped, functionalisable particle foam particles, wherein the particle foam particles are bonded together, and cooling and thereby obtaining the particle foam moulding, wherein the aqueous emulsion of the at least one polyolefin is an aqueous emulsion comprising at least one polyolefin converted to the liquid state with an anhydride of an unsaturated carboxylic acid and modified with methacrylic acid ester copolymers.

Expandable polystyrene-based resin particles may include a styrene-based monomer, a polysiloxane-containing macro monomer, and a coating composition having a melting point of 40° C. or greater. A coefficient of static friction of a foamed molded product, obtained by pre-expanding the expandable polystyrene-based resin particles and molding the pre-expanded expandable polystyrene-based resin particles, may be 4.0 or less. The expandable polystyrene-based resin particles may have a surface layer part that contains polysiloxane as a main component.

Expandable polystyrene-based resin particles may include a styrene-based monomer, a polysiloxane-containing macro monomer, and a coating composition having a melting point of 40° C. or greater. A coefficient of static friction of a foamed molded product, obtained by pre-expanding the expandable polystyrene-based resin particles and molding the pre-expanded expandable polystyrene-based resin particles, may be 4.0 or less. The expandable polystyrene-based resin particles may have a surface layer part that contains polysiloxane as a main component.

Heat-expandable microspheres including a thermoplastic resin shell and a thermally-vaporizable blowing agent encapsulated therein. The thermoplastic resin is a polymer of a polymerizable component containing a cross-linkable monomer (A) which has at least two (meth)acryloyl groups per molecule and a reactive carbon-carbon double bond in addition to the (meth)acryloyl groups and has a molecular weight of at least 500. Also disclosed are hollow resin particles manufactured by expanding the heat-expandable microspheres; fine-particle-coated hollow resin particles including the hollow resin particles; a composition including a base component and the heat-expandable microspheres, or hollow resin particles, or fine-particle coated hollow resin particles; and a formed article manufactured by forming the composition.

Heat-expandable microspheres including a thermoplastic resin shell and a thermally-vaporizable blowing agent encapsulated therein. The thermoplastic resin is a polymer of a polymerizable component containing a cross-linkable monomer (A) which has at least two (meth)acryloyl groups per molecule and a reactive carbon-carbon double bond in addition to the (meth)acryloyl groups and has a molecular weight of at least 500. Also disclosed are hollow resin particles manufactured by expanding the heat-expandable microspheres; fine-particle-coated hollow resin particles including the hollow resin particles; a composition including a base component and the heat-expandable microspheres, or hollow resin particles, or fine-particle coated hollow resin particles; and a formed article manufactured by forming the composition.

Bare porous polymer monoliths, fluidic chips, methods of incorporating bare porous polymer monoliths into fluidic chips, and methods for functionalizing bare porous polymer monoliths are described. Bare porous polymer monoliths may be fabricated ex situ in a mold. The bare porous polymer monoliths may also be functionalized ex situ. Incorporating the bare preformed porous polymer monoliths into the fluidic chips may include inserting the monoliths into channels of channel substrates of the fluidic chips. Incorporating the bare preformed porous polymer monoliths into the fluidic chips may include bonding a capping layer to the channel substrate. The bare porous polymer monoliths may be mechanically anchored to channel walls and to the capping layer. The bare porous polymer monoliths may be functionalized by ex situ immobilization of capture probes on the monoliths. The monoliths may be functionalized by direct attachment of chitosan.