A porous polymer aerogel, wherein the aerogel has greater than 5 wt % of amine containing vinyl monomers integrated into a polymer backbone. A method of fabrication of a porous polymer aerogel amine material, includes preparing a solution comprising at least a solvent, amine monomers having protected amino groups, one or more crosslinkers, one or more radical initiators, and a nitroxide mediator, removing oxygen from the solution, heating the solution to promote polymerization and to produce a polymerized material, performing solvent exchange with the polymerized material, causing a deprotection reaction in the polymerized material to remove groups protecting the amino groups, soaking and rinsing the material to remove excess reagents and any byproducts of the deprotection reaction, and drying the material to produce the amine sorbent. A system to separate CO2 from other gases, comprising a polymer porous aerogel sorbent having greater than 5 wt % of amine containing vinyl monomers integrated into a polymer backbone.

A solid electrolyte of the present disclosure includes: a porous dielectric having a plurality of pores interconnected; and an electrolyte including a metal salt and at least one selected from the group consisting of an ionic compound and a bipolar compound and at least partially filling an interior of the plurality of pores. The porous dielectric includes a polyether structure. The plurality of pores have an average pore diameter of 20 nm or more and 100 nm or less.

A primary amine polymer aerogel comprising greater than 5 wt. % of primary amine monomers covalently bound to cross-linking monomers, wherein the primary amine monomers are selected from vinyl amine. A secondary amine polymer aerogel comprising secondary amine monomers covalently bound to cross-linking monomers, the secondary amine monomers being a result of substituting a hydrogen atom from a primary amine polymer aerogel, the primary amine polymer aerogel comprising vinyl amine monomers covalently bound to the cross-linking monomers. A tertiary amine polymer aerogel comprising tertiary amine monomers covalently bound to cross-linking monomers, the tertiary amine monomers being a result of substituting hydrogen atoms from a primary amine polymer aerogel, the primary amine polymer aerogel comprising vinyl amine monomers covalently bound to the cross-linking monomers.

A method for producing a polyurethane polymer comprises the steps of: (a) providing a polyol; (b) providing an additive composition comprising a polyethylenimine compound and a sulfite compound; (c) combining the polyol and the additive composition to produce a polyol composition; (d) providing an isocyanate compound; and (e) combining and reacting the polyol composition and the isocyanate composition to produce a polyurethane polymer.

A monolithic organic porous ion exchanger having a continuous skeleton and continuous pores, wherein the continuous skeleton is formed of an organic polymer being a hydrolysate of a crosslinked polymer of a (meth)acrylic acid ester and divinylbenzene, the organic polymer having any one or both of a —COOH group and a —COONa group as ion-exchange groups, the continuous skeleton has a thickness of 0.1 to 100 μm, the continuous pores have an average diameter of 1.0 to 1000 μm, the monolithic organic porous ion exchanger has a total pore volume of 0.5 to 50.0 mL/g, and has a total ion-exchange capacity of the —COOH group and the —COONa group per weight in a dry state of 4.0 mg equivalent/g or more.

A porous polyimide film has a low dielectric loss tangent. The porous polyimide film is a reaction product of a diamine component and an acid dianhydride component. The diamine component contains an aromatic diamine represented by the following formula (1).

##STR00001##

(In formula, Y represents at least one selected from the group consisting of a single bond, —COO—, —S—, —CH(CH.sub.3)—, —C(CH.sub.3).sub.2—, —CO—, —NH—, and —NHCO—.) The porosity is 50% or more.

A method of fabrication of a porous polymer aerogel amine material includes preparing a solution comprising at least a solvent, amine monomers having protecting groups, one or more crosslinkers, and one or more radical initiators, heating the solution to promote polymerization and to produce a polymerized material, performing solvent exchange with the polymerized material, causing a deprotection reaction in the polymerized material to remove the protecting groups to produce a deprotected material, soaking and rinsing the deprotected material to remove excess reagents and any byproducts of the deprotection reaction, and drying the deprotecting material to produce the amine sorbent. A system to separate CO.sub.2 from other gases has a polymer porous aerogel sorbent having greater than 5 wt % of amine containing vinyl monomers integrated into a polymer backbone, and the amine containing vinyl monomers may have a molecular weight of less than 100 g/mol.

An air-permeable filter material that includes a polymeric aerogel having a polymeric matrix comprising an open-cell structure is disclosed. The air-permeable filter material can be included in a mask, which can be configured to be placed over a user's mouth and/or nose. The mask can include at least one layer of the air-permeable filter material and is positioned such that inhaled and/or exhaled air of the user passes through the filter material.

The present invention discloses novel porous polymeric compositions comprising random copolymers of amides, imides, ureas, and carbamic-anhydrides, useful for the synthesis of monolithic bimodal microporous/macroporous carbon aerogels. It also discloses methods for producing said microporous/macroporous carbon aerogels by the reaction of a polyisocyanate compound and a polycarboxylic acid compound, followed by pyrolytic carbonization, and by reactive etching with CO.sub.2 at elevated temperatures. Also disclosed are methods for using the microporous/macroporous carbon aerogels in the selective capture and sequestration of carbon dioxide.

The present disclosure relates to a method for producing polymer microparticles, this method including a step for polymerizing vinyl monomers in a hydrophilic solvent, which dissolves the vinyl monomers and a dispersion stabilizer but does not dissolve a polymer formed, in the presence of the dispersion stabilizer. The present disclosure is a method for producing these polymer microparticles, wherein the dispersion stabilizer contains a macromonomer having carboxyl groups and ethylenically unsaturated groups at an intermediate location in a molecular chain thereof, the macromonomer has, on average, 1.4 to 2.5 ethylenically unsaturated groups per molecule, and an average value of a carboxyl group content in the macromonomer is 0.5 meq/g to 2.5 meq/g.