The present disclosure relates to compositions comprising 2,3,3,3-tetrafluoropropene that may be useful as heat transfer compositions, aerosol propellants, foaming agents, blowing agents, solvents, cleaning agents, carrier fluids, displacement drying agents, buffing abrasion agents, polymerization media, expansion agents for polyolefins and polyurethane, gaseous dielectrics, extinguishing agents, and fire suppression agents in liquid or gaseous form. Additionally, the present disclosure relates to compositions comprising 1,1,2,3-tetrachloropropene, 2-chloro-3,3,3-trifluoropropene, or 2-chloro-1,1,1,2-tetrafluoropropane, which may be useful in processes to produce 2,3,3,3-tetrafluoropropene.

The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a fluoroolefin and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.

A catalyst composition comprising at least one compound with a general formula I:

##STR00001##

wherein A is N—R.sup.3, R.sup.3 is C.sub.1-C.sub.8 linear or branched, x=0-6, n and m are each independently 1 to 6, R.sup.1 and R.sup.2 are each independently C.sub.2-C.sub.8 alkyl, and R.sup.4 and R.sup.5 are —CH.sub.3 groups; or A=O, x=0-6. n and m are each independently 1 to 6. R.sup.1 and R.sup.2 are each independently C.sub.2-C.sub.8 alkyl, and R.sup.4 and R.sup.5 are —CH.sub.3 groups; or A=O or N—R.sup.3, R.sup.3 is C.sub.1-C.sub.8 linear or branched, and N(R.sup.1-R.sup.4) and N(R.sup.2-R.sup.5) each independently represent a C.sub.3-C.sub.7 ring amine moiety of the type:

##STR00002##

HCFO-containing isocyanate-reactive compositions, foam-forming compositions containing such isocyanate-reactive compositions, rigid PUR-PIR foams made using such foam-forming compositions, and methods for producing such foams, including use of such foams as insulation in discontinuous foam panel applications. The isocyanate-reactive composition includes a polyol blend, a blowing agent composition, and a tertiary amine catalyst. The polyol blend includes: (1) an aromatic polyester polyol having a functionality of 1.5 to less than 2.5 and an OH number of 150 to 360 mg KOH/g; (2) an aromatic polyester polyol having a functionality of at least 2.5 and an OH number greater than 360 mg KOH/g, which is present in an amount of at least 10% by weight, based on the total weight of the aromatic polyester polyol in the polyol blend; and (3) an amine-initiated polyether polyol having an OH number of at least 500 mg KOH/g and a functionality of 2.5 to 4. The blowing agent composition includes a hydrochlorofluoroolefin and a carbon dioxide generating chemical blowing agent.

A thermoset foam comprises from 0.2 to 4.0 wt. % of at least one aliphatic brominated polyether polyol, from 2.0 to 7.0 wt. % of at least one aromatic brominated polyester polyol, and from 2.0 to 7.5 wt. % of at least one flame retardant comprising organo-phosphate, organo-phosphonate, or organo-phosphite, wherein the ratio of the amount of aliphatic bromine expressed as a percentage of total bromine to the amount of aromatic bromine expressed as a percentage of total bromine is from 10:90 to 50:50.

A phenolic resin foam has a density of 30 kg/m.sup.3 to 80 kg/m.sup.3, a closed cell ratio of 85% or more, and reaches a total amount of heat release of 8 MJ/m.sup.2 in a time of 20 minutes or more in a heat release test performed using a cone calorimeter.

To provide a composite comprising a resin foam and a resin member different from the resin foam, which can suppress deterioration of the outer appearance of the resin member.

A composite comprising a resin foam formed by using a blowing agent containing 1-chloro-2,3,3,3-tetrafluoropropene, and a resin member different from the resin foam, containing a resin selected from the group consisting of a polycarbonate resin, a polystyrene resin, a polyphenylene ether resin, an acrylonitrile/butadiene/styrene resin and a styrene/acrylonitrile copolymer resin.

Disclosed herein is a process for producing rigid polyisocyanurate foams, where (a) aromatic polyisocyanate, (b) isocyanate-reactive compounds including at least one polyetherol (b1) and/or polyesterol (b2), wherein where the number-average content of isocyanate-reactive hydrogen atoms of components (b 1) and (b2) is at least 1.7, (c) catalyst, (d) blowing agents, (e) flame retardants, (f) optionally auxiliary and additive substances and (g) optionally compounds having aliphatic hydrophobic groups and not falling under the definition of compounds (a) to (f) are mixed to afford a reaction mixture and allowed to cure to afford a rigid polyisocyanurate foam. Further disclosed herein is a rigid polyisocyanurate foam obtainable by the process.

Disclosed is a mixture comprising the compound trans-1,1,1,4,4,4-hexafluoro-2-butene and at least one additional compound selected from the group consisting of HFOs, HFCs, HFEs, CFCs, CO2, olefins, organic acids, alcohols, hydrocarbons, ethers, aldehydes, ketones, and others such as methyl formate, formic acid, trans-1,2 dichloroethylene, carbon dioxide, cis-HFO-1234ze+HFO-1225yez; mixtures of these plus water; mixtures of these plus CO2; mixtures of these trans 1,2-dichloroethylene (DCE); mixtures of these plus methyl formate; mixtures with cis-HFO-1234ze+CO2; mixtures with cis-HFO-1234ze+HFO-1225yez+CO2; and mixtures with cis-HFO-1234ze+HFC-245fa. Also disclosed are methods of using and products of using the above compositions as blowing agents, solvents, heat transfer compositions, aerosol propellant compositions, fire extinguishing and suppressant compositions.

A method of applying a closed cell spray foam insulation may include spraying a first layer of a closed cell spray foam insulation into a wall cavity. A B-side mixture of the closed cell spray foam insulation may include a polyol blend having a polyester polyol having a functionality of at least about 3.0 and a polyether polyol. The method may include spraying at least one additional layer of the closed cell spray foam insulation against the first layer within 5 minutes of spraying the first layer.