A composition is provided comprising 55 to 75 wt % Z-1,1,1,4,4,4-hexafluoro-2-butene and 45 to 25 wt % E-1,1,1,4,4,4-hexafluoro-2-butene, the combined weight of these isomers totaling 100 wt %, along with a process comprising forming a foamed reaction product obtained by reacting polyisocyanate with active hydrogen-containing compound such as polyol in the presence of this composition as a blowing agent to obtain the foamed reaction product, such as polyurethane or polyisocyanurate.

The invention provides polyurethane and polyisocyanurate foams and methods for the preparation thereof. More particularly, the invention relates to open-celled, polyurethane and polyisocyanurate foams and methods for their preparation. The foams are characterized by a fine uniform cell structure and little or no foam collapse. The foams are produced with a polyol premix composition which comprises a combination of a hydrohaloolefin blowing agent, a polyol, a silicone surfactant, and a sterically hindered amine catalyst.

A toner supply roller is provided which has the most uniform and greatest possible foam cell diameters and a lower hardness particularly even in a lower-temperature and lower-humidity environment as compared with the conventional art and is less liable to suffer from imaging failure such as uneven density and white streaks. An image forming apparatus employing the toner supply roller is also provided. The toner supply roller (1) is produced by preparing a rubber composition which contains a rubber component including an epichlorohydrin rubber and an acrylonitrile butadiene rubber, an electrically conductive carbon black, a crosslinking component and a foaming component and, while extruding the rubber composition into a tubular body, continuously foaming and crosslinking the rubber composition of the tubular body by a continuous crosslinking apparatus including a microwave crosslinking device and a hot air crosslinking device. The image forming apparatus incorporates the toner supply roller (1).

The invention provides polyurethane and polyisocyanurate foams and methods for the preparation thereof. More particularly, the invention relates to open-celled, polyurethane and polyisocyanurate foams and methods for their preparation. The foams are characterized by a fine uniform cell structure and little or no foam collapse. The foams are produced with a polyol premix composition which comprises a combination of a hydrohaloolefin blowing agent, a polyol, a silicone surfactant, and a sterically hindered amine catalyst.

A polymeric foam article with a polymer matrix defining multiple cells therein has a polymer component with a first polymer that is a polyhedral oligomeric silsesquioxane grafted polymer that has a weight-average molecular weight of two kilograms per mole or higher and 200 kilograms per mole or lower.