A method for manufacturing a foam rubber by foaming a polymer latex is provided, wherein the polymer latex used has a solids content of 60.0 wt % or more, has a volume particle size distribution where the volume cumulative particle size d10 is more than 140 nm, and comprises 0.001 to 1.0 part by weight of antifoaming agent relative to 100 parts by weight of polymer in the polymer latex.

A coating fabric and method of manufacturing the same are provided. A coated fabric includes a base coating layer. The base coating layer defines a smooth coating to resist liquid penetration to the fabric. The coated fabric also includes a middle foam coating layer that is deposited on at least a portion of the base coating layer. The middle foam layer defines a middle layer foam density and is configured to absorb at least a portion of liquid. The coated fabric further includes an outer foam coating layer that is deposited on at least a portion of the middle foam coating later. The outer foam layer defines an outer layer foam density and is configured with holes to allow liquid to penetrate to the middle foam layer. The middle layer foam density is less than the outer layer foam density. A corresponding method of manufacturing is also provided.

A method for manufacturing a foam rubber by foaming a polymer latex is provided, wherein the polymer latex used has a solids content of 60.0 wt % or more, comprises 0.001 to 1.0 part by weight of antifoaming agent relative to 100 parts by weight of polymer in the polymer latex, and has a viscosity at 25 C. of 370 cps or less when the solids content is controlled to 66.0 wt %.

Disclosed is a dip-formed article obtained by dip-molding a latex composition for dip-forming, which contains a crosslinking agent and a latex for dip-forming containing a copolymer composed of 40-80% by weight of conjugated diene monomer units (A) containing an isoprene unit, 20-45% by weight of ethylenically unsaturated nitrile monomer units (B), and 2-15% by weight of ethylenically unsaturated acid monomer units (C), and having a weight ratio of butadiene unit content to isoprene unit content that falls within the range of 60:40 to 100:0. Tear strength is at least 50 N/mm, tensile strength is at least 25 MPa, and oil swelling rate does not exceed 5%.

A rubber latex elastic foam body produced using as the raw material therefor rubber latex and sodium silicofluoride, having an average radius for the cellular foam configuring the foam body of 10-200 m, a bulk density of 0.10-0.20 g/cm.sup.3, and stress at 50% compression of 0.1-1 N/cm.sup.2. This rubber latex elastic foam body has a rich texture, good adhesiveness to a skin, excellent powder adhesion, and excellent even powder application.

A method of preparing a carboxylic acid-modified nitrile-based copolymer latex is provided. The method of preparing a carboxylic acid-modified nitrile-based copolymer later includes emulsion-polymerizing a monomer mixture including a conjugated diene-based monomer, an ethylenically unsaturated nitrile-based monomer, and an ethylenically unsaturated acid monomer in the presence of a cross-linking agent including glyoxal.

A nitrile-rubber medical exam glove composed of a glove body which is a flexible layer of nitrile-butadiene rubber. The glove body has a chlorinated first surface forming a donning side of the glove body and an un-chlorinated second surface forming a grip side of the glove body. The elastomeric glove also includes a substantially uniform distribution of a release agent distributed over the un-chlorinated second surface of the glove body. The elastomeric glove has: (a) an average thickness of between about 0.03 to 0.12 mm in a palm region of the glove body as measured in accordance with ASTM D3767, procedure A; (b) an un-chlorinated second surface of the glove body characterized by a Surface Root Mean Square Roughness of from about 3.00 m to about 6.55 m; and (c) a failure rate of less than about 1 percent when the elastomeric glove is subjected to pinhole leak testing generally in accordance with ASTM D5151-06.

A dip-molding composition of the present invention contains a latex (A) of a nitrile-group-containing highly saturated copolymer rubber (a). The nitrile-group-containing highly saturated copolymer rubber (a) contains an ,-ethylenically unsaturated nitrile monomer unit and a conjugated diene monomer unit, and being obtained by hydrogenating at least part of the conjugated diene monomer unit. A dip-molded article of the present invention is produced by dip molding of the above dip-molding composition.

The present invention relates to a polymer latex composition, to a method for the preparation of such polymer latex composition, to a compounded latex composition comprising said polymer latex composition, to the use of said polymer latex composition, to a method for making dip-molded articles, to a method for the production of a continuous elastomeric film and for making an elastomeric article, to a method for repairing or reforming an elastomeric film or an article and to articles made by using said polymer latex composition.

The invention relates to an elastomeric film-forming composition comprising (a) a copolymer formed from monomers consisting of chlorobutadiene and an ethylenically unsaturated carboxylic acid or ester, and (b) one or more cross-linking agents. The invention also relates to dipped articles, gloves, methods of manufacture and uses involving the composition.