Provided is a curable organopolysiloxane composition for forming a film, which has low viscosity before curing, has excellent mechanical strength and dielectric breakdown strength after curing, and can provide a uniform and thin organopolysiloxane cured film. The curable organopolysiloxane composition comprises: a curing reactive organopolysiloxane, a curing agent, (D1) reinforcing fine particles having a BET specific surface area exceeding 100 m.sup.2/g, which have been surface treated with an organic silicon compound, and (D2) reinforcing fine particles having a BET specific surface area within a range of 10 to 100 m.sup.2/g, which have been surface treated with an organic silicon compound. The mass ratio of components (D1) and (D2) is within a range of 50:50 to 99:1, and the sum of components (D1) and (D2) is within a range of 10 to 40 mass %. A method of manufacturing an organopolysiloxane cured film using the curable organopolysiloxane composition is also provided.

A composition for forming a foamed silicone elastomer is disclosed. The composition comprises: A) an organopolysiloxane having at least two silicon-bonded ethylenically unsaturated groups per molecule; B) an organohydrogensiloxane having at least two silicon-bonded hydrogen atoms per molecule; C) a hydrosilylation catalyst; D) a chemical blowing agent; and E) a physical blowing agent. The hydrosilylation catalyst C) is present in a catalytically effective amount. The chemical blowing agent D) has at least one hydroxyl (OH) group, and is present in an amount to provide a OH content >0 and <500 parts per million (ppm). The physical blowing agent E) undergoes a phase change from a liquid to a gaseous state during exposure to atmospheric pressure and a temperature ≥0° C. The blowing agents D) and E) are different from one another. A foamed silicone elastomer, and methods of forming the composition and foamed silicone elastomer are also disclosed.

The present invention provides: porous spherical silicone rubber particles which have high light scattering performance; porous silicone composite particles; and a method for producing these particles. The porous spherical silicone rubber particles have pores inside the particles or in the surfaces of the particles.

The present invention provides a crosslinked molded article having a lower compression set; and a method for producing a crosslinked molded article by injection molding, the method enabling shortening of one cycle in injection molding, the method being suitable for obtaining a crosslinked molded article having a lower compression set. The present invention relates to a method for producing a crosslinked molded article, comprising melt-kneading a polymer composition containing a polymer having a terminal double bond, a hydrosilyl group-containing compound (Y) having at least two hydrosilyl groups per molecule, a platinum-based catalyst (Z) for hydrosilicon crosslinking, and a reaction inhibitor (D), subjecting the polymer composition to injection molding in a mold, performing primary crosslinking in the mold, removing the primary-crosslinked molded article from the mold, and then performing secondary crosslinking in a heat medium.

The disclosure provides a silicone resin film with water vapor barrier property formed by curing a curable silicone resin composition, wherein the curable silicone resin composition comprises 10 to 25 parts by weight of a linear polysiloxane; 40 to 55 parts by weight of a first silicone resin wherein the first silicone resin have at least following siloxane units represented by the general formulas: R.sup.1SiO.sub.3/2 and R.sup.2.sub.2SiO.sub.2/2, wherein the molar fraction of R.sup.1SiO.sub.3/2 unit is present in the range of 0.60 to 0.75 in the general formula; 15 to 30 parts by weight of a second silicone resin; 15 to 25 parts by weight of a polysiloxane having silicon-hydrogen bond; 10 to 40 parts by weight of microsheets; and a platinum group metal catalyst.

A sponge-forming silicone rubber composition is disclosed. The sponge-forming silicone rubber composition comprises: (A) an organopolysiloxane having at least two alkenyl groups per molecule; (B) an organopolysiloxane having at least two silicon atom-bonded hydrogen atoms per molecule; (C) water; (D) a thickener; (E) a surfactant; (F) a silane compound having silicon atom-bonded alkoxy groups, or a partially hydrolyzed condensate thereof; and (G) a hydrosilylation reaction catalyst. The sponge-forming silicone rubber composition forms a silicone rubber sponge. In general, the silicone rubber sponge has excellent water absorption and water retentivity.

A foamable silicone composition, includes: (a) at least one organopolysiloxane containing at least two alkenyl groups bonded to silicon atoms per molecule, (b) at least one organopolysiloxane containing at least two hydrogen atoms bonded to silicon atoms per molecule, (c) porogenic agents generating gaseous hydrogen in the presence of component (b) comprising (c1) an organopolysiloxane containing at least one hydroxyl group bonded to silicon atom per molecule and (c2) water, and (d) hydrosilylation catalyst; with the proviso that the ratio of the number of moles of hydroxyl groups provided by component (c2) to that provided by component (c1) is within a range of from 1:5 to 20:1. The composition has a low viscosity and a relatively high pot life, and the foam cured therefrom has a low density, uniform porosity and fine cell structure.

A layered coating system with enhanced properties capable of protecting an article or a component of an article from exposure to outdoor elements, including UV radiation, extreme temperatures, water, acid rain, other fluids and chemicals; scratching and marring from surface contact; and more. The layered coating system and articles formed therewith are characterized by properties that can include UV-absorption, abrasion and scratch resistance, adhesion to the substrate and within the coating layers, haze and visible light transparency, and impact resistance.

A process for the modification of a surface of a solid material having the step of contacting the surface with a surface-modifying composition under irradiation with light of a wavelength in the range of 200 to 800 nm, optionally in the presence of a photoinitiator, wherein the solid material is chosen from the group consisting of polyesters, polyethers, polycarbonates, polyketones polyamides, polyurethanes, (meth)acrylate and (meth)acrylamide polymers and polyetherimides and wherein the surface modifying composition includes at least a hydrosilane.

A method for surface treatment of a silicone rubber includes: providing the silicone rubber bearing a polar group on a surface of the silicone rubber, and applying a multifunctional compound to the surface of the silicone rubber bearing the polar group to allow the multifunctional compound to react with the polar group to form a coating.