C08J2429/04

Copolyesters plasticized with polymeric plasticizer

Polyester-based films contain certain copolyesters (A) and polyester plasticizers (B). The copolyesters (A) may be selected from those in which the force required to stretch a film of the copolyester (A) by itself, from 2× to 5×, increases by less than 200%. The polyester plasticizers (B) have a weight-average molecular weight of 900 to 12,000 g/mol, and contain (i) a diol component comprising residues of diols having 2 to 8 carbon atoms, and (ii) a diacid component comprising residues of dicarboxylic acids having 4 to 12 carbon atoms. These polyester-based films are particularly useful for preparing ultra-thin LCD or OLED polarizers, because they can be stretched very thin with a high stretch ratio at lower temperatures.

Method of Enhancing Adhesion of Silver Nanoparticle Inks on Plastic Substrates Using a Crosslinked Poly(vinyl butyral) Primer Layer

A primer layer comprising a polyvinyl butyral resin enhances adhesion of silver nanoparticle inks onto plastic substrates. The primer layer comprises a polyvinyl butyral (PVB) resin having a polyvinyl alcohol content between about 18 wt. % to about 21 wt. %. The PVB resin may also have a glass transition temperature greater than about 70° C. Optionally, the PVB primer layer may further be enhanced by cross-linking using a melamine-formaldehyde resin. Conductive traces formed on plastic substrates having the PVB primer layer exhibit an acceptable cross-hatch adhesion rating with little to no degradation of adhesion being observed after exposure to 4-days salt mist aging or 1-day high humidity aging.

SEA-ISLAND COMPOSITE FIBER
20220307161 · 2022-09-29 · ·

Provided is a sea-island composite fiber having excellent spinnability and thermoplastic deformability. The sea-island composite fiber comprises an island component and a sea component having a lower melting point than that of the island component, wherein the fiber has an aspect ratio of from 2.0 to 5.0 in a fiber cross section; and the sea component has a sea component thickness of from 0.2 to 2.0 μm, the sea component thickness being defined as a distance between an outer periphery of the fiber and an island component closest to the outer periphery on a minor axis of the fiber cross section.

WATER-SOLUBLE POLYVINYL ALCOHOL BLEND FILM, RELATED METHODS, AND RELATED ARTICLES

Disclosed herein are water-soluble films including a polyvinyl alcohol (PVOH) resin blend and optionally one or more additional components such as plasticizers, fillers, surfactants, and other additives. The PVOH resin blend includes a PVOH copolymer including one or more types of anionic monomer units such as a PVOH terpolymer and a PVOH polymer such as another PVOH anionic copolymer or a partially or completely hydrolyzed PVOH homopolymer. When the PVOH copolymer and PVOH polymer are blended in particular proportions and/or selected with regard to various criteria related to physical and chemical film properties, the resulting water-soluble film formed from the PVOH resin blend exhibits substantially improved aqueous dissolution properties, tensile strength properties, and/or tensile modulus properties.

WATER-SOLUBLE POLYVINYL ALCOHOL BLEND FILM, RELATED METHODS, AND RELATED ARTICLES

Disclosed herein are water-soluble films including a polyvinyl alcohol (PVOH) resin blend and optionally one or more additional components such as plasticizers, fillers, surfactants, and other additives. Also disclosed herein are articles including the water-soluble film and containing a composition such as a household care composition. The PVOH resin blend includes a PVOH copolymer including one or more types of anionic monomer units such as a PVOH terpolymer and a PVOH polymer such as a partially or completely hydrolyzed PVOH homopolymer. When the PVOH copolymer and PVOH polymer are blended in particular proportions and/or selected with regard to various criteria related to the 4% solution viscosity of one or both of the PVOH polymer(s) and PVOH copolymer(s), the resulting water-soluble film formed from the PVOH resin blend exhibits substantially improved aqueous dissolution properties.

Water Soluble Film For Thermoforming Deep-Drawn Profiles And Thermoformed Articles Comprising Same

The disclosure provides a water soluble film suitable for thermoforming deep-drawn profiles, the film including a mixture of a water soluble polyvinyl alcohol (PVOH) resin and a plasticizer, and the film being characterized by a storage modulus at 90° C. less than 1.5×10.sup.8. The disclosure further provides a thermoformed article comprising the water soluble film according to the disclosure.

GAS BARRIER LAYERED BODY, AND PACKAGING MATERIAL AND TUBE CONTAINER USING SAME
20220267067 · 2022-08-25 · ·

The present disclosure relates to a gas barrier layered body including: a substrate layer containing a polyolefin-based resin; a first polyvinyl alcohol-based resin layer; a Si or Al-containing thin film layer; and a second polyvinyl alcohol-based resin layer, in the stated order, in which a logarithmic decrement at 100° C. of the first polyvinyl alcohol-based resin layer as measured by a rigid-body pendulum type physical property testing instrument is 0.20 or less and a logarithmic decrement at 125° C. is 0.30 or less, and an indentation hardness of the second polyvinyl alcohol-based resin layer as determined by a nanoindenter is 0.5 to 1.0 GPa.

Water-soluble polyvinyl alcohol blend film, related methods, and related articles

Disclosed herein are water-soluble films including a polyvinyl alcohol (PVOH) resin blend and optionally one or more additional components such as plasticizers, fillers, surfactants, and other additives. The PVOH resin blend includes a first copolymer including a first anionic monomer unit and a second PVOH copolymer including a second anionic monomer unit. When the PVOH copolymers are blended in particular proportions and/or selected with regard to various criteria related to physical and chemical film properties, the resulting water-soluble film formed from the PVOH resin blend exhibits maintained film stiffness, and pouch tautness when in contact with liquid pouch contents, maintain acceptable clarity properties, and/or demonstrate acceptable band release without impairing the ultimate solubility of the water-soluble film.

Multilayer porous film, separator for nonaqueous electrolyte secondary battery, and nonaqueous electrolyte secondary battery

There is provided a multilayer porous film that includes a covering layer formed from a coating liquid on at least one surface of a porous film. The coating liquid has high stability and coatability. The covering layer does not decrease the intrinsic high air permeability of the porous film and has high heat resistance and adhesiveness. The multilayer porous film has excellent handleability as a battery separator without causing curling. The multilayer porous film includes the covering layer on at least one surface of a porous polyolefin resin film. The covering layer is formed from a coating liquid and contains a filler and a resin binder. The multilayer porous film satisfies the following conditions 1) and 2): 1) the filler has an average circularity of 0.3 or more and less than 0.7; and 2) an acid component in the coating liquid has a first acid dissociation constant of 5 or less and has no second acid dissociation constant or a second acid dissociation constant of 7 or more in a dilute aqueous solution at 25° C.

Process for preparing dispersion powders
09815977 · 2017-11-14 · ·

The invention provides a process for preparing dispersion powders by spray drying of aqueous polymer dispersions of polymers of one or more ethylenically unsaturated monomers selected from the group encompassing vinyl esters, methacrylic esters, acrylic esters, olefins, dienes, vinylaromatics, and vinyl halides with a drying gas in a nozzle atomization dryer, characterized in that the aqueous polymer dispersion (feed), before being atomized, is preheated under pressure to a temperature of 100° C. to 200° C. and is atomized at this temperature, the pressure being set such that the aqueous phase of the polymer dispersion does not boil at the temperature selected.