Patent classifications
C08J2433/26
ENHANCED PVOH-BASED BARRIER LAYER COMPOSITION, BARRIER LAYER AND METHODS FOR ITS MANUFACTURE
There is provided a packaging material comprising a fibre based substrate and a gas barrier layer based on a polyvinyl alcohol (PVOH), wherein said gas barrier layer comprises an interpolymer complex forming agent (IPCFA), which IPCFA is a water-soluble polymer exhibiting functional groups capable of forming hydrogen bonds with —OH groups of the PVOH. Said PVOH has a weight average molecular weight (M.sub.w) measured according to ASTM D4001-13 in the range of about 80 kg/mol to 135 kg/mol, the proportion of said IPCFA to PVOH in said gas barrier layer is in the range of 0.5 to 7.0% (w/w) and said packaging material has an oxygen permeability (OP) below 14 ml μm/m.sup.2 day atm, which OP is obtained by multiplying the oxygen transmission rate (OTR) of the packaging material measured according to ASTM F1927-7 at a relative humidity (RH) of 80% and 23° C. by the thickness of the gas barrier layer.
ADHESIVE COMPOSITION
An adhesive composition having excellent adhesive properties and adhesiveness to a variety of plastics such as polypropylene, polyethylene, or a cycloolefin resin. The adhesive composition includes a polymer having a repeating unit derived from a polymerizable compound of the following formula (I):
##STR00001##
in which X.sup.1 and X.sup.2 each independently represent a C7 to C20 alkyl group or a C7 to C20 alkoxy group; n represents 0 or 1; Z.sup.1 and Z.sup.2 each independently represent a single bond or a C1 to C3 alkylene group; R each independently represents an organic group or a halogeno group; m1 and m2 each independently represent any integer of 0 to 4; and Y represents a polymerizable functional group.
FORMALDEHYDE-FREE BINDER COMPOSITION
Aqueous binder compositions for binding fibers comprise a vinyl acetate-ethylene copolymer of 60 to 94% by weight vinyl acetate, 5 to 30% by weight ethylene and 0 to 20% by weight of further ethylenically unsaturated comonomers copolymerizable therewith, polymerized in the presence of polyvinyl alcohol in aqueous medium, wherein the polymerization is carried out in the presence of a copolymer B) containing 20 to 50% by weight of monomer units derived from ethylenically unsaturated carboxamides, 20 to 50% by weight of monomer units derived from ethylenically unsaturated monocarboxylic acids, and 20 to 50% by weight of monomer units derived from ethylenically unsaturated dicarboxylic acids or anhydrides thereof.
COATED SILICONE MEMBER MANUFACTURING METHOD
The purpose of the present invention is to provide a coated silicone member manufacturing method which enables, even when a highly water-repellent silicone member having a water surface contact angle of more than 110° is processed at a low temperature, formation of, on the surface, a coating having a sufficiently low surface contact angle with respect to an aqueous solution containing a salt and a protein. The present invention provides a coated silicone member manufacturing method comprising: (A) a degradative reaction step for degrading the surface of a silicone member; (B) a contact step b for bringing a solution b containing a polycarbodiimide into contact with the surface-degraded silicone member; and (C) a contact step c for bringing a solution c containing a polymer C into contact with the surface-degraded silicone member. The polymer C has an alkyl amide group and hydroxyl group.
Silicone hydrogel lens with a crosslinked hydrophilic coating
The invention is related to a cost-effective method for making a silicone hydrogel contact lens having a crosslinked hydrophilic coating thereon. A method of the invention involves heating a silicone hydrogel contact lens in an aqueous solution in the presence of a water-soluble, highly branched, thermally-crosslinkable hydrophilic polymeric material having positively-charged azetidinium groups, to and at a temperature from about 40° C. to about 140° C. for a period of time sufficient to covalently attach the thermally-crosslinkable hydrophilic polymeric material onto the surface of the silicone hydrogel contact lens through covalent linkages each formed between one azetidinium group and one of the reactive functional groups on and/or near the surface of the silicone hydrogel contact lens, thereby forming a crosslinked hydrophilic coating on the silicone hydrogel contact lens. Such method can be advantageously implemented directly in a sealed lens package during autoclave.
Antifouling Polymeric Coating Compositions
Provided herein are compositions comprising: (a) a polymeric catechol binder, such as: polymeric dopamine, polymeric norepinephrine, polymeric epinephrine; polymeric pyrogallol, polymeric tannic acid, polymeric hydroxyhydroquinone, polymeric catechin, polymeric epigallocatechin etc.; and (b) a hydrophilic polymer, methods for using the compositions to coat a substrate, and methods for making the compositions. In particular, the substrate may form part of an apparatus on which it would be beneficial to limit biofouling and/or protein binding.
SILICONE HYDROGEL LENSES WITH WATER-RICH SURFACES
The invention is related to a hydrated silicone hydrogel contact lens having a layered structural configuration: a lower water content silicone hydrogel core (or bulk material) completely covered with a layer of a higher water content hydrogel totally or substantially free of silicone. A hydrated silicone hydrogel contact lens of the invention possesses high oxygen permeability for maintaining the corneal health and a soft, water-rich, lubricious surface for wearing comfort.
Antifouling polymeric coating compositions
Provided herein are compositions comprising: (a) a polymeric catechol binder, such as: polymeric dopamine, polymeric norepinephrine, polymeric epinephrine; polymeric pyrogallol, polymeric tannic acid, polymeric hydroxyhydroquinone, polymeric catechin, polymeric epigallocatechin etc.; and (b) a hydrophilic polymer, methods for using the compositions to coat a substrate, and methods for making the compositions. In particular, the substrate may form part of an apparatus on which it would be beneficial to limit biofouling and/or protein binding.
Surface Modified Membranes
A composite ion exchange membrane comprising components (a) and (b): (a) a membrane layer comprising ionic groups, two opposing surfaces and optionally a porous support; (b) a layer comprising sulpho groups bound to at least one of the at least two opposing surfaces of the membrane layer (a);
wherein the layer comprising sulpho groups has a thickness of less than 100 nm and the composite ion exchange membrane has a surface zeta potential of 0 to −7.5 mV.
MONOVALENT ANION SELECTIVE ION EXCHANGE MEMBRANE
Provided are a monovalent anion selective ion exchange membrane and a method of manufacturing the ion exchange membrane. In regard to the monovalent anion selective ion exchange membrane, a surface portion thereof has a high amount ratio of a cation exchange polymer electrolyte, a central portion thereof has a high amount ratio of an anion exchange polymer electrolyte, and an amount ratio of the anion exchange polymer electrolyte with respect to the cation exchange polymer electrolyte continuously increases in the thickness direction thereof from the surface toward the center. Due to this structure, compared to monovalent anions, polyvalent anions may permeate much less through the exchange membrane. Thus, high selectivity for monovalent anions may be obtained.