The invention relates to a laminate comprising a first layer and a second layer directly covering the first layer, the first layer being a layer of a silicone rubber composition comprising a micrometric silicone powder and a mixture of crosslinkable organopolysiloxanes, the second layer being a layer of a silicone rubber composition comprising a hydrophobic silica and a mixture of crosslinkable organopolysiloxanes, the first layer and the second layer being crosslinked. The laminate, in particular when it is used as a coating for the outer surface of an expandable bladder for a tyre curing mould, makes it possible to eliminate moulding defects on the inner liner of the tyre.

A negative-working photosensitive resin composition including an epoxy group-containing resin, a metal oxide, and a cationic polymerization initiator, in which a photosensitive resin film having a film thickness of 20 μm obtained by applying the negative-working photosensitive resin composition onto a silicon wafer and performing a bake treatment at 90° C. for 5 minutes has a Martens hardness of less than 235 [N/mm.sup.2], and when a viscoelasticity of a cured film, which is obtained by exposing the photosensitive resin film to i-rays at an irradiation amount of 200 mJ/cm.sup.2, performing a bake treatment after the exposure at 90° C. for 5 minutes, and then performing a bake treatment at 200° C. for 1 hour to cure the photosensitive resin film, is measured at a frequency of 1.0 Hz, a tensile elastic modulus (E*) of the cured film at a temperature of 175° C. is 2.1 [GPa] or more.

A negative-working photosensitive resin composition including an epoxy group-containing resin, a metal oxide, and a cationic polymerization initiator, in which a photosensitive resin film having a film thickness of 20 μm obtained by applying the negative-working photosensitive resin composition onto a silicon wafer and performing a bake treatment at 90° C. for 5 minutes has a Martens hardness of less than 235 [N/mm.sup.2], and when a viscoelasticity of a cured film, which is obtained by exposing the photosensitive resin film to i-rays at an irradiation amount of 200 mJ/cm.sup.2, performing a bake treatment after the exposure at 90° C. for 5 minutes, and then performing a bake treatment at 200° C. for 1 hour to cure the photosensitive resin film, is measured at a frequency of 1.0 Hz, a tensile elastic modulus (E*) of the cured film at a temperature of 175° C. is 2.1 [GPa] or more.

Provided is a rubber composition being excellent in cut resistance while maintaining good elongation fatigue resistance. The rubber composition of the present disclosure contains a rubber component containing 70% by mass or more of natural rubber, a filler containing at least silica, and a cyclic polyol compound having a hydrocarbyl group of 0.1 parts by mass to 2 parts by mass with respect to 100 parts by mass of the natural rubber in the rubber component.

Provided is a rubber composition being excellent in cut resistance while maintaining good elongation fatigue resistance. The rubber composition of the present disclosure contains a rubber component containing 70% by mass or more of natural rubber, a filler containing at least silica, and a cyclic polyol compound having a hydrocarbyl group of 0.1 parts by mass to 2 parts by mass with respect to 100 parts by mass of the natural rubber in the rubber component.

Provided is a rubber composition being excellent in cut resistance while maintaining good elongation fatigue resistance. The rubber composition of the present disclosure contains a rubber component containing 70% by mass or more of natural rubber, a filler containing at least silica, and a cyclic polyol compound having a hydrocarbyl group of 0.1 parts by mass to 2 parts by mass with respect to 100 parts by mass of the natural rubber in the rubber component.

Provided are a rubber composition which provides a self-healing rubber with improved strength and wet grip performance, and a pneumatic tire including the rubber composition. The present disclosure relates to a rubber composition containing a rubber component having a functional group containing a cationic functional group and/or an anionic functional group, a filler capable of generating a charge paired with the functional group, and sulfur.

Provided are a rubber composition which provides a self-healing rubber with improved strength and wet grip performance, and a pneumatic tire including the rubber composition. The present disclosure relates to a rubber composition containing a rubber component having a functional group containing a cationic functional group and/or an anionic functional group, a filler capable of generating a charge paired with the functional group, and sulfur.

Provided are a rubber composition which provides a self-healing rubber with improved strength and wet grip performance, and a pneumatic tire including the rubber composition. The present disclosure relates to a rubber composition containing a rubber component having a functional group containing a cationic functional group and/or an anionic functional group, a filler capable of generating a charge paired with the functional group, and sulfur.

The invention relates to a method of additive manufacturing an object using a 3D printing apparatus, in which at least one layer or part of at least one layer is formed by an addition-crosslinking electro-conductive silicone composition comprising : (A) at least one organopolysiloxane compound A comprising, per molecule at least two C.sub.2- C.sub.6 alkenyl radicals bonded to silicon atoms, (B) at least one organohydrogenopolysiloxane compound B comprising, per molecule, at least two hydrogen atoms bonded to an identical or different silicon atom, (C) at least one catalyst C comprising at least one metal from the platinum group or the compound thereof, (D) at least one reinforcing silica filler D, (E) at least one thixotropic agent which is selected from compounds having epoxy group, (poly)ether group, and/or (poly)ester group, organopolysiloxane having an aryl group and mixtures thereof; (F) at least one electro-conductive filler F, which is selected from nickel coated carbon, preferably graphite, graphene or mixtures thereof; (G) optionally at least one crosslinking inhibitor G.