A gas-barrier composition including nanocellulose containing at least one of a sulfuric acid group, a sulfo group, or a phosphoric acid group; and a reactive crosslinking agent.

A fine cellulose fiber in which when the fine cellulose fiber is formed into a dispersion, the dispersion has very high light transmittance and viscosity, and a method for producing the fine cellulose fiber.

The fine cellulose fiber has a fiber width of 1 to 200 nm. A part of hydroxy groups of the cellulose fiber are substituted with a predetermine functional group to introduce an ester of phosphorus-oxo acid, and the introduction amount of the functional group is more than 2.0 mmol per 1 g of the cellulose fiber. For producing the fine cellulose fiber, to cellulose fiber is added a solution having a pH of less than 3.0 and including an additive (A) containing at least one of a phosphorus-oxo acid and a phosphorus-oxo acid metal salt and an additive (B) containing at least one of urea and a urea derivative, and the mixture is heated to perform fibrillation.

A cellulose nanocrystal composite containing a sulfuric acid group and/or a sulfo group and an anionic functional group, and supporting fine metal particles. The total amount of the sulfuric acid group and/or the sulfo group and the anionic functional group is more than 0.17 mmol/g and not more than 4.0 mmol/g. Also disclosed is a method for producing the cellulose nanocrystal composite which includes treating a cellulose material with sulfuric acid to prepare cellulose nanocrystal containing a sulfuric acid group and/or a sulfo group; subjecting the cellulose nanocrystal to a hydrophilization treatment to prepare cellulose nanocrystal containing a sulfuric acid group and/or a sulfo group and an anionic functional group; and allowing the cellulose nanocrystal to support fine metal particles.

The present invention provides resin beads that can provide various types of products, such as a cosmetic having excellent tactile impression, spreadability on the skin, and transparency, that can be substituted for resin particles composed of a synthetic material derived from petroleum, and that have favorable biodegradability, and the present invention also provides various types of products, such as a cosmetic using the resin beads. The resin beads are formed with a resin containing cellulose as a main component. The resin beads have a cumulative 50% particle size on a volume basis of 50 μm or smaller, a degree of sphericity of 0.7 to 1.0, a degree of surface smoothness of 70 to 100%, a degree of solidity of 50 to 100%, and a biodegradation rate for 5 days, as measured in accordance with JIS K6950:2000 (ISO 14851:1999), of 20% or more, and the content of the cellulose in the resin is 90 to 100% by mass. In addition, the present invention provides a product of any one of a cosmetic, a dermatological preparation, a paint, a shaped article, a film, a coating agent, and a resin composition which contain the resin beads.

The present invention provides resin beads that can provide various types of products, such as a cosmetic having excellent tactile impression, spreadability on the skin, and transparency, that can be substituted for resin particles composed of a synthetic material derived from petroleum, and that have favorable biodegradability, and the present invention also provides various types of products, such as a cosmetic using the resin beads. The resin beads are formed with a resin containing cellulose as a main component. The resin beads have a cumulative 50% particle size on a volume basis of 50 μm or smaller, a degree of sphericity of 0.7 to 1.0, a degree of surface smoothness of 70 to 100%, a degree of solidity of 50 to 100%, and a biodegradation rate for 5 days, as measured in accordance with JIS K6950:2000 (ISO 14851:1999), of 20% or more, and the content of the cellulose in the resin is 90 to 100% by mass. In addition, the present invention provides a product of any one of a cosmetic, a dermatological preparation, a paint, a shaped article, a film, a coating agent, and a resin composition which contain the resin beads.

A fine cellulose fiber-containing substance that has excellent dispersibility in water and can be manufactured easily. A method is for manufacturing the fine cellulose fiber-containing substance, and a method is for manufacturing a fine cellulose fiber dispersion. A fine cellulose fiber-containing substance contains fine cellulose fibers into which a phosphite containing a cation of an inorganic substance is introduced. The ratio of the cation of the inorganic substance with respect to 1 g of the fine cellulose fibers is 0.14 mmol or more. In manufacturing the fine cellulose fiber-containing substance, a phosphite is introduced into cellulose fibers, and then the cellulose fibers are defibrated to obtain a dispersion containing fine cellulose fibers, during which an alkali metal ion-containing substance is added to the cellulose fibers, and the dispersion is concentrated. In manufacturing a fine cellulose fiber dispersion, the fine cellulose fiber-containing substance is mixed with water.

An object of the present invention is to provide ultrafine fibrous cellulose capable of exhibiting excellent coating suitability when added to paint. The present invention relates to fibrous cellulose having a fiber width of 1,000 nm or less, in which, when the fibrous cellulose is dispersed in water to form a dispersion liquid having a viscosity of 2,500 mPa.Math.s at 23° C., and the dispersion liquid is stirred under predetermined stirring conditions, a viscosity change rate falls within ±50%, calculated by the following formula: viscosity change rate (%)=(viscosity after stirring−viscosity before stirring)/viscosity before stirring×100

Composite particles that are biodegradable and easy to handle while maintaining the characteristics of cellulose nanofibers, a method of producing composite particles, a dry powder containing the composite particles, and a skin application composition and a method of producing the skin application composition. A composite particle contains at least one type of particle and fine cellulose with which at least part of a surface of the particle is coated, wherein the particle and the fine cellulose are inseparable.

The purpose of the present invention is to provide a composite sheet in which the dimension stability when it is tensed is high and the appearance deterioration and the yellowness change are suppressed. The present invention relates to a sheet comprising; cellulose fibers having a fiber width of 1000 nm or less and having a phosphoric acid group or a phosphoric acid group-derived substituent; and a polyvinyl alcohol-based resin, wherein the sheet has a tensile elastic modulus of 3.4 GPa or more.

The purpose of the present invention is to provide a composite sheet in which the dimension stability when it is tensed is high and the appearance deterioration and the yellowness change are suppressed. The present invention relates to a sheet comprising; cellulose fibers having a fiber width of 1000 nm or less and having a phosphoric acid group or a phosphoric acid group-derived substituent; and a polyvinyl alcohol-based resin, wherein the sheet has a tensile elastic modulus of 3.4 GPa or more.