A cellulose fiber-based substrate, at least one side of which is coated with an aqueous mixture composed of: a) at least one water-soluble polymer (WSP) containing hydroxyl groups, b) at least one lactone substituted with at least one linear or branched and/or cyclic C.sub.8-C.sub.30 hydrocarbon chain which may contain heteroatoms, c)at least one crosslinking agent. A method of production and use thereof.

A process is disclosed herein comprising the steps: a) contacting an esterifying agent and a polysaccharide in the presence of a first solvent and suitable reaction conditions for a reaction time sufficient to form a product comprising a polysaccharide ester composition, the polysaccharide ester composition comprising a polysaccharide ester having a degree of substitution of about 0.001 to about 3; wherein the esterifying agent comprises an acyl halide, a phosphoryl halide, a carboxylic acid anhydride, a haloformic acid ester, a carbonic acid ester, or a vinyl ester; and the ratio of esterifying agent to polysaccharide is in the range of about 0.001:1 to about 3:1 on a molar equivalent basis; b) combining the product obtained in step a) with polyacrylonitrile; and c) spinning fibers.

There is provided esterified starch which can be produced without using a non-aqueous organic solvent and has water resistance and miscibility with another plastic, and a starch-containing plastic composition. The esterified starch is obtained such that a starch mixture containing starch and a polyhydric alcohol, which is subjected to a heat treatment, is esterified with a vinyl ester and carbonate. Since the starch in the starch mixture enters a state in which starch granules are disintegrated by the polyhydric alcohol, by heating the starch mixture containing starch and a polyhydric alcohol, it is possible to esterify the starch without using a non-aqueous organic solvent and to obtain esterified starch having a high ester substitution degree. According to the esterified starch of the present invention, it is possible to obtain a starch-containing plastic composition having high hydrophobicity, and excellent water resistance and miscibility with another plastic.

There is provided esterified starch which can be produced without using a non-aqueous organic solvent and has water resistance and miscibility with another plastic, and a starch-containing plastic composition. The esterified starch is obtained such that a starch mixture containing starch and a polyhydric alcohol, which is subjected to a heat treatment, is esterified with a vinyl ester and carbonate. Since the starch in the starch mixture enters a state in which starch granules are disintegrated by the polyhydric alcohol, by heating the starch mixture containing starch and a polyhydric alcohol, it is possible to esterify the starch without using a non-aqueous organic solvent and to obtain esterified starch having a high ester substitution degree. According to the esterified starch of the present invention, it is possible to obtain a starch-containing plastic composition having high hydrophobicity, and excellent water resistance and miscibility with another plastic.

There is provided esterified starch which can be produced without using a non-aqueous organic solvent and has water resistance and miscibility with another plastic, and a starch-containing plastic composition. The esterified starch is obtained such that a starch mixture containing starch and a polyhydric alcohol, which is subjected to a heat treatment, is esterified with a vinyl ester and carbonate. Since the starch in the starch mixture enters a state in which starch granules are disintegrated by the polyhydric alcohol, by heating the starch mixture containing starch and a polyhydric alcohol, it is possible to esterify the starch without using a non-aqueous organic solvent and to obtain esterified starch having a high ester substitution degree. According to the esterified starch of the present invention, it is possible to obtain a starch-containing plastic composition having high hydrophobicity, and excellent water resistance and miscibility with another plastic.

Extruded starch compositions and methods for their preparation are provided. The compositions possess a high degree of cook which imparts particular viscosity characteristics. The compositions may be formed into films having advantageous properties such as low haze, high strength and high gas barrier. The starch compositions find use in a wide range of applications, particularly, but not exclusively, in the manufacture of thin films for packaging.

Extruded starch compositions and methods for their preparation are provided. The compositions possess a high degree of cook which imparts particular viscosity characteristics. The compositions may be formed into films having advantageous properties such as low haze, high strength and high gas barrier. The starch compositions find use in a wide range of applications, particularly, but not exclusively, in the manufacture of thin films for packaging.

Disclosed is a processing method of a self-reinforced starch-based multifunctional material, and belongs to the technical field of starch deep processing. The processing method takes bulk starch as a base material, including the following steps: firstly reacting starch nanoparticles with an organic acid anhydride reagent and adding a bacteriostatic agent to prepare composite nanoparticles, then mixing the composite nanoparticles with the bulk starch, an etherifying agent, a crosslinking agent, a plasticizer and the like, and finally preparing a starch-based multifunctional material by dry extrusion modification combined with a starch-based nanoparticle assembly and reinforcement technology. The method of the disclosure is simple and convenient in step, mild and controllable in reaction, and continuous and green in production. The obtained product has good mechanical properties, high barrier properties and high antibacterial properties, can be applied to many fields such as food, textiles, daily chemicals and medicine, and has a broad market prospect.

Disclosed is a processing method of a self-reinforced starch-based multifunctional material, and belongs to the technical field of starch deep processing. The processing method takes bulk starch as a base material, including the following steps: firstly reacting starch nanoparticles with an organic acid anhydride reagent and adding a bacteriostatic agent to prepare composite nanoparticles, then mixing the composite nanoparticles with the bulk starch, an etherifying agent, a crosslinking agent, a plasticizer and the like, and finally preparing a starch-based multifunctional material by dry extrusion modification combined with a starch-based nanoparticle assembly and reinforcement technology. The method of the disclosure is simple and convenient in step, mild and controllable in reaction, and continuous and green in production. The obtained product has good mechanical properties, high barrier properties and high antibacterial properties, can be applied to many fields such as food, textiles, daily chemicals and medicine, and has a broad market prospect.

Disclosed is a processing method of a self-reinforced starch-based multifunctional material, and belongs to the technical field of starch deep processing. The processing method takes bulk starch as a base material, including the following steps: firstly reacting starch nanoparticles with an organic acid anhydride reagent and adding a bacteriostatic agent to prepare composite nanoparticles, then mixing the composite nanoparticles with the bulk starch, an etherifying agent, a crosslinking agent, a plasticizer and the like, and finally preparing a starch-based multifunctional material by dry extrusion modification combined with a starch-based nanoparticle assembly and reinforcement technology. The method of the disclosure is simple and convenient in step, mild and controllable in reaction, and continuous and green in production. The obtained product has good mechanical properties, high barrier properties and high antibacterial properties, can be applied to many fields such as food, textiles, daily chemicals and medicine, and has a broad market prospect.