Patent classifications
C08L9/04
Latex and composite
A latex including: a nitrile rubber containing an α,β-ethylenically unsaturated nitrile monomer unit in a content of 8 to 50 wt % and an α,β-ethylenically unsaturated dicarboxylic acid monoester monomer unit in a content of 1 to 10 wt %, and having an iodine value of 120 g/100 g or less; and a benzisothiazoline-based compound represented by the following general formula (1), wherein the content of the benzisothiazoline-based compound is 50 ppm by weight or more, with respect to the nitrile rubber, and a redox potential of the latex is 80 to 800 mV. ##STR00001##
In the general formula (1) mentioned above, R.sup.1 represents a hydrogen atom, or a substituted or unsubstituted organic group, R.sup.2 each independently represents a hydrogen atom, or a substituted or unsubstituted organic group, and “n” represents an integer of 0 to 4.
Latex and composite
A latex including: a nitrile rubber containing an α,β-ethylenically unsaturated nitrile monomer unit in a content of 8 to 50 wt % and an α,β-ethylenically unsaturated dicarboxylic acid monoester monomer unit in a content of 1 to 10 wt %, and having an iodine value of 120 g/100 g or less; and a benzisothiazoline-based compound represented by the following general formula (1), wherein the content of the benzisothiazoline-based compound is 50 ppm by weight or more, with respect to the nitrile rubber, and a redox potential of the latex is 80 to 800 mV. ##STR00001##
In the general formula (1) mentioned above, R.sup.1 represents a hydrogen atom, or a substituted or unsubstituted organic group, R.sup.2 each independently represents a hydrogen atom, or a substituted or unsubstituted organic group, and “n” represents an integer of 0 to 4.
PNEUMATIC TIRE
The present invention is directed to a pneumatic tire having a tread comprising a vulcanizable rubber composition comprising, based on 100 parts by weight of elastomer (phr), up to 100 phr of a solution polymerized styrene-butadiene rubber; from 5 to 50 phr of a fatty acid monoester of formula 1
##STR00001##
where R.sup.1 is selected from C1 to C8 linear or branched alkyl, C1 to C8 linear or branched alkenyl, and C2 to C6 linear or branched alkyl substituted with from one to five hydroxyl groups; R.sup.2 is C11 to C21 alkyl or C11 to C21 alkenyl; from 5 to 50 phr of a hydrocarbon resin having a Tg ranging from −40° C. to 20° C.; less than 10 phr of a petroleum-derived oil; and from 50 to 130 phr of silica. optionally, from about 1 to 50 phr carbon black.
A COMPOSITION FOR MAKING HYDROPHOBIC ELASTOMERIC ARTICLE
The present invention relates to a composition for making a hydrophobic elastomeric article comprising a liquid polymer; 0.01 to 1.5 phr of carbon black; and 1 to 15 phr of hydrophobic dispersion comprises activated charcoal, a dispersing agent and a stabilizer.
A COMPOSITION FOR MAKING HYDROPHOBIC ELASTOMERIC ARTICLE
The present invention relates to a composition for making a hydrophobic elastomeric article comprising a liquid polymer; 0.01 to 1.5 phr of carbon black; and 1 to 15 phr of hydrophobic dispersion comprises activated charcoal, a dispersing agent and a stabilizer.
Polyisoprene latex graphene composites and methods of making them
The present invention relates to a method of preparing reduced graphene oxide, incorporation of the reduced graphene oxide into polyisoprene latex to provide a polyisoprene latex graphene composite and elastomeric articles prepared using the polyisoprene latex-graphene composite. In particular, the reduction of graphene oxide is accomplished without the use of strong reducing agents and organic solvents and incorporation of the reduced graphene oxide into polyisoprene latex is accomplished using room temperature latex mixing method or hot maturation. The resultant composite exhibits good colloid stability, and polyisoprene latex films produced the composite exhibit good mechanical properties with improved ageing resistance.
Polyisoprene latex graphene composites and methods of making them
The present invention relates to a method of preparing reduced graphene oxide, incorporation of the reduced graphene oxide into polyisoprene latex to provide a polyisoprene latex graphene composite and elastomeric articles prepared using the polyisoprene latex-graphene composite. In particular, the reduction of graphene oxide is accomplished without the use of strong reducing agents and organic solvents and incorporation of the reduced graphene oxide into polyisoprene latex is accomplished using room temperature latex mixing method or hot maturation. The resultant composite exhibits good colloid stability, and polyisoprene latex films produced the composite exhibit good mechanical properties with improved ageing resistance.
Dip molding composition, method of producing glove, and glove
Provided is, a glove production method including: (1) the step of immersing a glove forming mold in a liquid coagulant containing calcium ions so as to allow the coagulant to adhere to the glove forming mold; (2) the dispersion step of leaving a dip molding composition to stand with stirring; (3) the dipping step; (4) the gelling step; (5) the leaching step; (6) the beading step; (7) the precuring step; and (8) the curing step, in which method the steps (3) to (8) are performed in the order mentioned, and the dip molding composition has a specific formulation.
Dip molding composition, method of producing glove, and glove
Provided is, a glove production method including: (1) the step of immersing a glove forming mold in a liquid coagulant containing calcium ions so as to allow the coagulant to adhere to the glove forming mold; (2) the dispersion step of leaving a dip molding composition to stand with stirring; (3) the dipping step; (4) the gelling step; (5) the leaching step; (6) the beading step; (7) the precuring step; and (8) the curing step, in which method the steps (3) to (8) are performed in the order mentioned, and the dip molding composition has a specific formulation.
Method for producing carboxyl-group-containing nitrile rubber
A method of producing a carboxyl group-containing nitrile rubber including a coagulation step of coagulating a carboxyl group-containing nitrile rubber component by mixing a monovalent metal salt and a polymer flocculating agent into a carboxyl group-containing nitrile rubber latex having an iodine value of 120 or less, wherein the monovalent metal salt is compounded in an amount of 3 to 25 parts by weight and the polymer flocculating agent is compounded in an amount of 0.01 to 10 parts by weight relative to 100 parts by weight of a rubber solid content in the latex, and a weight ratio of the monovalent metal salt/the polymer flocculating agent is in the range of 10 to 500