The invention relates to a composition for the layer-by-layer building of a three-dimensional article by sintering of the composition brought about by electromagnetic radiation, the composition comprising a semicrystalline thermoplastic polymer powder and at least one wax, the wax having a dropping point which is greater than the crystallization temperature of the semicrystalline thermoplastic polymer, said composition in addition optionally comprising a flow agent.

The invention also relates to a process for the preparation of said composition and also to its use for the layer-by-layer building of a three-dimensional article.

The invention relates to a composition for the layer-by-layer building of a three-dimensional article by sintering of the composition brought about by electromagnetic radiation, the composition comprising a semicrystalline thermoplastic polymer powder and at least one wax, the wax having a dropping point which is greater than the crystallization temperature of the semicrystalline thermoplastic polymer, said composition in addition optionally comprising a flow agent.

The invention also relates to a process for the preparation of said composition and also to its use for the layer-by-layer building of a three-dimensional article.

A cross-linked polyolefin resin foam of the present invention has a total light transmittance and a thickness that satisfy a predetermined condition, and has a reflection color difference Δ* of −10 to 16, a reflection color difference Δa* of −3 to 3, and a reflection color difference ΔL* of 50 or more. According to the present invention, there can be provided a cross-linked polyolefin resin foam that can suppress a change in color tone of transmitted light while ensuring transparency, and a pressure-sensitive adhesive tape, layered product, formed product, and display member that include such a cross-linked polyolefin resin foam.

A foamable cross-linkable thermoplastic material comprises a matrix polymer of any one or a mixture of two or more of polyethylene (PE), ethylene vinyl acetate copolymer (EVA) and polypropylene (PP), a cross-linking agent, and a foaming agent. A weight ratio of the cross-linking agent to the matrix polymer is 1-5:100. A weight ratio of the foaming agent to the matrix polymer is 1-5:100. A cross-linking foaming temperature of the thermoplastic material is equal to or higher than the melting point of the matrix polymer.

A foamable cross-linkable thermoplastic material comprises a matrix polymer of any one or a mixture of two or more of polyethylene (PE), ethylene vinyl acetate copolymer (EVA) and polypropylene (PP), a cross-linking agent, and a foaming agent. A weight ratio of the cross-linking agent to the matrix polymer is 1-5:100. A weight ratio of the foaming agent to the matrix polymer is 1-5:100. A cross-linking foaming temperature of the thermoplastic material is equal to or higher than the melting point of the matrix polymer.

Methods for preparing waterborne heat seal coating compositions are disclosed, including (A) melt blending an ethylene vinyl acetate copolymer, a tackifier, and a wax in a first mixing apparatus to form a melt blend, (B) contacting the melt blend with an initial aqueous stream comprising a neutralizing agent, water, and a surfactant in an emulsification zone of the second mixing apparatus to form a dispersion, and (C) diluting the dispersion with water in a dilution zone of the second mixing apparatus to form the waterborne heat seal coating composition. Methods for preparing waterborne heat seal coating compositions are also disclosed, including (A) melt blending an ethylene vinyl acetate copolymer, a tackifier, and a wax in a mixing and conveying zone of a mixing apparatus to form a melt blend, (B) contacting the melt blend with an initial aqueous stream comprising a neutralizing agent, water, and a surfactant in an emulsification zone of the mixing apparatus to form a dispersion, and (C) diluting the dispersion with water in a dilution zone of the mixing apparatus to form the waterborne heat seal coating composition, wherein the length-to-diameter ratio of the extruder mixing apparatus is greater than or equal to 12 to 1. Waterborne heat seal coating compositions prepared according to the disclosed methods are also disclosed.

Methods for preparing waterborne heat seal coating compositions are disclosed, including (A) melt blending an ethylene vinyl acetate copolymer, a tackifier, and a wax in a first mixing apparatus to form a melt blend, (B) contacting the melt blend with an initial aqueous stream comprising a neutralizing agent, water, and a surfactant in an emulsification zone of the second mixing apparatus to form a dispersion, and (C) diluting the dispersion with water in a dilution zone of the second mixing apparatus to form the waterborne heat seal coating composition. Methods for preparing waterborne heat seal coating compositions are also disclosed, including (A) melt blending an ethylene vinyl acetate copolymer, a tackifier, and a wax in a mixing and conveying zone of a mixing apparatus to form a melt blend, (B) contacting the melt blend with an initial aqueous stream comprising a neutralizing agent, water, and a surfactant in an emulsification zone of the mixing apparatus to form a dispersion, and (C) diluting the dispersion with water in a dilution zone of the mixing apparatus to form the waterborne heat seal coating composition, wherein the length-to-diameter ratio of the extruder mixing apparatus is greater than or equal to 12 to 1. Waterborne heat seal coating compositions prepared according to the disclosed methods are also disclosed.

Disclosed herein are ethylene-based polymers generally characterized by a density of at least 0.94 g/cm.sup.3, a high load melt index from 4 to 20 g/10 min, a zero-shear viscosity at 190° C. from 20,000 to 400,000 kPa-sec, and a relaxation time at 190° C. from 225 to 3000 sec. These ethylene polymers can be produced by peroxide-treating a broad molecular weight distribution Ziegler-catalyzed resin, and can be used in large diameter, thick wall pipes and other end-use applications.

Disclosed herein are ethylene-based polymers generally characterized by a density of at least 0.94 g/cm.sup.3, a high load melt index from 4 to 20 g/10 min, a zero-shear viscosity at 190° C. from 20,000 to 400,000 kPa-sec, and a relaxation time at 190° C. from 225 to 3000 sec. These ethylene polymers can be produced by peroxide-treating a broad molecular weight distribution Ziegler-catalyzed resin, and can be used in large diameter, thick wall pipes and other end-use applications.

Disclosed herein are ethylene-based polymers having low densities and narrow molecular weight distributions, but high melt strengths for blown film processing. Such polymers can be produced by peroxide-treating a metallocene-catalyzed resin.