Patent classifications
C08L23/10
Heterophasic propylene polymer material and propylene-based resin composition
A heterophasic propylene polymerization material, including a propylene polymer component (I) and an ethylene-α-olefin copolymer component (II), the heterophasic propylene polymerization material satisfying features (i) to (v): (i) the heterophasic propylene polymerization material contains a xylene-soluble content by 20 wt % or more; (ii) xylene-soluble content in the heterophasic propylene polymerization material has a limiting viscosity [η].sub.CXS not less than 5 dL/g; (iii) a melt flow rate of the propylene polymer component (I) is 70 g/10 min or more; (iv) MFR of the heterophasic propylene polymerization material is not less than 5 g/10 min; and (v) the number of gels of 100 μm or more in diameter on a sheet for counting gels, including the heterophasic propylene polymerization material, is 1000 or less per 100 cm.sup.2 of the sheet.
Heterophasic propylene polymer material and propylene-based resin composition
A heterophasic propylene polymerization material, including a propylene polymer component (I) and an ethylene-α-olefin copolymer component (II), the heterophasic propylene polymerization material satisfying features (i) to (v): (i) the heterophasic propylene polymerization material contains a xylene-soluble content by 20 wt % or more; (ii) xylene-soluble content in the heterophasic propylene polymerization material has a limiting viscosity [η].sub.CXS not less than 5 dL/g; (iii) a melt flow rate of the propylene polymer component (I) is 70 g/10 min or more; (iv) MFR of the heterophasic propylene polymerization material is not less than 5 g/10 min; and (v) the number of gels of 100 μm or more in diameter on a sheet for counting gels, including the heterophasic propylene polymerization material, is 1000 or less per 100 cm.sup.2 of the sheet.
Aqueous based blend composition and method of producing the same
The instant invention is an aqueous based blend composition and method of producing the same. The aqueous based blend composition comprises (a) an aqueous polyolefin dispersion comprising the melt blending product of one or more base polymers and one or more stabilizing agents in the presence of water and optionally one or more neutralizing agents, wherein the polyolefin dispersion has an average volume particle size diameter in the range of from 400 to 1500 nm; and a pH range from 8 to 11; and (b) an acrylic emulsion acrylic solids having an average weight particle size diameter in the range of from 75 to 450 nm; an acid level in the range of from 0.25 to 5 percent by weight of acid monomers based on the weight of the acrylic monomer, and a weight average molecular weight in the range of from 200,000 to 5,000,000 g/mole, and a glass transition temperature (T.sub.g) in the range of from 7 to 100° C., wherein said acrylic emulsion has a pH in the range of from 7 to 11; wherein said aqueous based blend composition has a solid content in the range of from 15 to 70 percent by weight of solids, based on the weight of the aqueous based blend composition, and a pH in the range of from 7 to 11.
Aqueous based blend composition and method of producing the same
The instant invention is an aqueous based blend composition and method of producing the same. The aqueous based blend composition comprises (a) an aqueous polyolefin dispersion comprising the melt blending product of one or more base polymers and one or more stabilizing agents in the presence of water and optionally one or more neutralizing agents, wherein the polyolefin dispersion has an average volume particle size diameter in the range of from 400 to 1500 nm; and a pH range from 8 to 11; and (b) an acrylic emulsion acrylic solids having an average weight particle size diameter in the range of from 75 to 450 nm; an acid level in the range of from 0.25 to 5 percent by weight of acid monomers based on the weight of the acrylic monomer, and a weight average molecular weight in the range of from 200,000 to 5,000,000 g/mole, and a glass transition temperature (T.sub.g) in the range of from 7 to 100° C., wherein said acrylic emulsion has a pH in the range of from 7 to 11; wherein said aqueous based blend composition has a solid content in the range of from 15 to 70 percent by weight of solids, based on the weight of the aqueous based blend composition, and a pH in the range of from 7 to 11.
Aqueous based blend composition and method of producing the same
The instant invention is an aqueous based blend composition and method of producing the same. The aqueous based blend composition comprises (a) an aqueous polyolefin dispersion comprising the melt blending product of one or more base polymers and one or more stabilizing agents in the presence of water and optionally one or more neutralizing agents, wherein the polyolefin dispersion has an average volume particle size diameter in the range of from 400 to 1500 nm; and a pH range from 8 to 11; and (b) an acrylic emulsion acrylic solids having an average weight particle size diameter in the range of from 75 to 450 nm; an acid level in the range of from 0.25 to 5 percent by weight of acid monomers based on the weight of the acrylic monomer, and a weight average molecular weight in the range of from 200,000 to 5,000,000 g/mole, and a glass transition temperature (T.sub.g) in the range of from 7 to 100° C., wherein said acrylic emulsion has a pH in the range of from 7 to 11; wherein said aqueous based blend composition has a solid content in the range of from 15 to 70 percent by weight of solids, based on the weight of the aqueous based blend composition, and a pH in the range of from 7 to 11.
Process for enhancing the melt strength of propylene-based polymer compositions
Disclosed is a process for preparation of a propylene-based polymer composition involving the steps of: (a) mixing a propylene-based polymer and a peroxydicarbonate in a mixing device, wherein the mixing takes place at a temperature of ≤30° C., wherein the peroxydicarbonate is introduced into the mixing process in a dry form; (b) keeping the mixed composition at a temperature of ≤30° C.; (c) feeding the mixed composition into a melt extruder; (d) homogenizing the mixed composition at a temperature where the propylene-based polymer is in solid state during an average residence time of ≥6.0 and ≤30.0 seconds; (e) further homogenizing the mixed composition at a temperature at which the propylene-based polymer is in the molten state; and (f) extruding the homogenized material from a die outlet of the melt extruder followed by cooling and solidification; wherein the steps (a) through (f) are conducted in that order.
Process for enhancing the melt strength of propylene-based polymer compositions
Disclosed is a process for preparation of a propylene-based polymer composition involving the steps of: (a) mixing a propylene-based polymer and a peroxydicarbonate in a mixing device, wherein the mixing takes place at a temperature of ≤30° C., wherein the peroxydicarbonate is introduced into the mixing process in a dry form; (b) keeping the mixed composition at a temperature of ≤30° C.; (c) feeding the mixed composition into a melt extruder; (d) homogenizing the mixed composition at a temperature where the propylene-based polymer is in solid state during an average residence time of ≥6.0 and ≤30.0 seconds; (e) further homogenizing the mixed composition at a temperature at which the propylene-based polymer is in the molten state; and (f) extruding the homogenized material from a die outlet of the melt extruder followed by cooling and solidification; wherein the steps (a) through (f) are conducted in that order.
Three-dimensional printing
The present disclosure relates to a build material for 3D printing. The build material comprises polymeric particles comprising polypropylene and at least one elastomer. The polymeric particles comprise a surface-active coating.
Three-dimensional printing
The present disclosure relates to a build material for 3D printing. The build material comprises polymeric particles comprising polypropylene and at least one elastomer. The polymeric particles comprise a surface-active coating.
Molding compositions and foam molded articles made thereof
A foamed article formed by foam injection molding or foam extrusion of a composition is disclosed. The article is formed from a molding composition consisting essentially of: 100 phr of at least two different hydrogenated styrenic block copolymers (HSBC), a first HSBC and a second HSBC, having different molecular weights, a molecular weight ratio of at least 1.2:1, respectively; and a weight ratio of ranging from 5:95 to 95:5, respectively; 10-55 phr of a polypropylene having a melt flow of at least 2 g10/min; and optionally up to 55 phr of a plasticizer, selected from hydrocarbon based oils, fatty acids, triglyceride oils, and mixtures thereof. The composition has a melt flow rate of 2-50 g/10 min, a Shore A hardness of 60-90, a melt strength (F) of at least 0.010 N, and a melt strength (V) of at least 10.