Patent classifications
C08L53/025
Ethylene-vinyl alcohol copolymer resin composition, multilayer structure and package
An ethylene-vinyl alcohol copolymer resin composition, including: an ethylene-vinyl alcohol copolymer (A); acetic acid and/or a salt thereof (B); an aliphatic carboxylic acid (C) other than acetic acid; and an aliphatic carboxylic acid metal salt (D), wherein a metal species of the salt (D) is at least one selected from long Periodic Table 4th-period d-block elements, and wherein respective contents of the acetic acid and/or the salt thereof (B), the acid (C), and the salt (D) satisfy the following formulae (1) and (2) on a weight basis is provided. The resin composition is excellent in impact resistance and adhesive strength even without being blended with any other resin:
0.001≤(content of (D) in terms of metal ion/content of (B) in terms of acetic acid ion)≤1.30 (1)
0.11≤(content of (D) in terms of metal ion/content of (C) in terms of carboxylic acid ion)≤100 (2).
Ethylene-vinyl alcohol copolymer resin composition, multilayer structure and package
An ethylene-vinyl alcohol copolymer resin composition, including: an ethylene-vinyl alcohol copolymer (A); acetic acid and/or a salt thereof (B); an aliphatic carboxylic acid (C) other than acetic acid; and an aliphatic carboxylic acid metal salt (D), wherein a metal species of the salt (D) is at least one selected from long Periodic Table 4th-period d-block elements, and wherein respective contents of the acetic acid and/or the salt thereof (B), the acid (C), and the salt (D) satisfy the following formulae (1) and (2) on a weight basis is provided. The resin composition is excellent in impact resistance and adhesive strength even without being blended with any other resin:
0.001≤(content of (D) in terms of metal ion/content of (B) in terms of acetic acid ion)≤1.30 (1)
0.11≤(content of (D) in terms of metal ion/content of (C) in terms of carboxylic acid ion)≤100 (2).
RESIN COMPOSITION AND MOLDED ARTICLE
Provided are: a resin composition containing a rubber (I), a block copolymer (II) and a crosslinking agent (III), wherein the ratio by mass of the rubber (I) to the block copolymer (II), (I)/(II) is 99/1 to 55/45, and the block copolymer (II) is a block copolymer containing a polymer block (A) that contains an aromatic vinyl compound-derived structural unit and a polymer block (B) that contains a farnesene-derived structural unit (b1), and a molded article of the resin composition.
RESIN COMPOSITION AND MOLDED ARTICLE
Provided are: a resin composition containing a rubber (I), a block copolymer (II) and a crosslinking agent (III), wherein the ratio by mass of the rubber (I) to the block copolymer (II), (I)/(II) is 99/1 to 55/45, and the block copolymer (II) is a block copolymer containing a polymer block (A) that contains an aromatic vinyl compound-derived structural unit and a polymer block (B) that contains a farnesene-derived structural unit (b1), and a molded article of the resin composition.
Rubber composition and pneumatic tire
A rubber composition of the present invention contains 100 parts by mass of a rubber component (A) containing 45 to 75% by mass of natural rubber and 25 to 55% by mass of a conjugated diene-based polymer, in which a bonded styrene amount of the conjugated diene compound moieties is 25% or less, 1 to 40 parts by mass of a non-modified conjugated diene-based polymer (B) which has a weight average molecular weight of 5,000 or more but less than 40,000 in terms of polystyrene as measured by GPC and in which a bonded styrene amount of the conjugated diene compound moieties is less than 10% and a bonded vinyl amount of the conjugated diene compound moieties is 20% or more, and a filler (C), in which at least one of the conjugated diene-based polymers contained in the rubber component (A) is a modified conjugated diene-based polymer. With the rubber composition, a tire having further enhanced on-ice performance and having both excellent on-ice performance and excellent abrasion resistance is obtained.
Modified Diene Copolymers and Their Use
The present invention provides a modified diene copolymer composition having a modified A-B-C or C-B-A copolymer comprising at least one conjugated diene monomer and at least one unsubstituted vinyl aromatic monomer and at least one substituted vinyl aromatic monomer, wherein each block or segment in the modified A-B-C or C-B-A copolymer is either a homopolymer or a copolymer comprising at least one conjugated diene monomer and/or at least one unsubstituted vinyl aromatic monomer and/or at least one substituted vinyl aromatic monomer, wherein any of the copolymers have a distribution configuration that is tapered, counter tapered, random or controlled, and wherein any of the homopolymers or the copolymers comprising at least one conjugated diene monomer and/or at least one unsubstituted vinyl aromatic monomer may be in-chain and/or chain-end modified with at least one unit of at least one substituted vinyl aromatic monomer; optionally having a block copolymer made from the modified A-B-C or C-B-A copolymer, wherein the block copolymer comprises at least two of the modified A-B-C or C-B-A copolymers. The invention also provides a process for making the modified diene copolymer composition.
Medical tubing and compositions and methods for making therefor
Disclosed herein in is a medical tube comprising a hydrogenated styrenic block copolymer having a formula A-B-A, (A-B-A).sub.nX or (A-B).sub.nX is disclosed, where n is an integer from 2 to 30, and X is residue of a coupling agent. Prior to hydrogenation, each A block is a monoalkenyl arene homopolymer block having a true peak molecular weight of 5 kg/mol to 15 kg/mol. Each B block is a controlled distribution copolymer block having a true peak molecular weight of 30 kg/mol to 200 kg/mol. The hydrogenated styrenic block copolymer has a midblock poly(monoalkenyl arene) content of 35 wt. % to 50 wt. % based on the total weight of the midblock, and physical properties that makes it useful for producing medical tubes having kink resistance.
Block copolymers and uses thereof
A styrenic block copolymer having one or more polymer blocks A and one or more polymer blocks B is disclosed, where “A” is a poly(vinylaromatic) block having a molecular weight of greater than 5 kg/mol. The “B” block has a molecular weight of more than 15 kg/mol, and comprises polymerized 1,3-diene units and vinylaromatic units, wherein the polymerized vinylaromatic units represent 5-40 wt. % of the overall weight of the block “B”. The polymerized 1,3-diene units comprise more than 80 wt. % of polymerized isoprene units in which 45-80 mol % are 1,4-isoprene addition units. The blocks “A” and “B” represent from >5 to <40 wt. %, and >33 to <95 wt. %, respectively, relative to the overall weight of the block copolymer. The polymers have physical properties that make them valuable, e.g., as vibration damping materials.
Block copolymers and uses thereof
A styrenic block copolymer having one or more polymer blocks A and one or more polymer blocks B is disclosed, where “A” is a poly(vinylaromatic) block having a molecular weight of greater than 5 kg/mol. The “B” block has a molecular weight of more than 15 kg/mol, and comprises polymerized 1,3-diene units and vinylaromatic units, wherein the polymerized vinylaromatic units represent 5-40 wt. % of the overall weight of the block “B”. The polymerized 1,3-diene units comprise more than 80 wt. % of polymerized isoprene units in which 45-80 mol % are 1,4-isoprene addition units. The blocks “A” and “B” represent from >5 to <40 wt. %, and >33 to <95 wt. %, respectively, relative to the overall weight of the block copolymer. The polymers have physical properties that make them valuable, e.g., as vibration damping materials.
High energy return foam compositions having improved abrasion resistance and uses thereof
Components for articles of footwear and athletic equipment are provided including a high energy return foam having improved abrasion resistance. A variety of foams and foam components and compositions for forming the foams are provided. In some aspects, the foams and components including the foams can have exceptionally high energy return while also having improved durability and softness and an improved abrasion resistance. In particular, midsoles including the foams are provided for use in an article of footwear. Methods of making the compositions and foams are provided, as well as methods of making an article of footwear including one of the foam components. In some aspects, the foams and foam components can be made by injection molding or injection molding followed by compression molding.