A curable aminoplast acrylic polyol composition containing, based on the complete weight of the solids of the composition, (a) 50 to 85% by weight of an acrylic polyol having a glass transition temperature Tg of from 50 to 70 C., an equivalent weight of hydroxyl groups on solids of from 320 to 400, and a hydroxyl number on solids of from 130 to 180 mg KOH/g, (b) 15 to 50% by weight of an alkylated amino formaldehyde resin having a formaldehyde content in accordance with DIN EN ISO 11402 4.3 of less than 0.10%, and the amino compound is melamine, guanamine, benzoguanamine, urea, toluenesulfonamide and glycoluril, containing at least two types of alkyl groups having 1 to 12 carbon atoms, and (c) 0.5 to 5.0% by weight of at least one type of an acidic catalyst, together with a process for preparation of the composition and methods of using the composition.

Glass fiber products, including glass fiber mat and insulation products, are described. A glass fiber mat may include glass fibers and a binder. The binder may include cured products from a carbohydrate binder composition. The carbohydrate binder composition may include a carbohydrate, a nitrogen-containing compound, and a thickening agent. The carbohydrate binder composition may have a Brookfield viscosity of 7 to 50 centipoise at 20? C. as measured with a Brookfield viscometer using spindle 18 at 60 rpm. Glass fiber mats may include a component of a roofing shingle. Glass fiber mats may be a facer, battery separator, a filtration media, or a backing mat.

Glass fiber products, including glass fiber mat and insulation products, are described. A glass fiber mat may include glass fibers and a binder. The binder may include cured products from a carbohydrate binder composition. The carbohydrate binder composition may include a carbohydrate, a nitrogen-containing compound, and a thickening agent. The carbohydrate binder composition may have a Brookfield viscosity of 7 to 50 centipoise at 20? C. as measured with a Brookfield viscometer using spindle 18 at 60 rpm. Glass fiber mats may include a component of a roofing shingle. Glass fiber mats may be a facer, battery separator, a filtration media, or a backing mat.

According to one or more embodiments, a method of making an antifouling coating includes forming a polythioaminal polymer by reacting a fluorinated primary amine with an aldehyde to form an intermediate imine, and then reacting the intermediate imine with a dithiol. The method further includes depositing the polythioaminal on a substrate, and increasing a temperature of the polythioaminal deposited on the substrate to crosslink the polythioaminal and increase a contact angle of the substrate with crosslinked polythioaminal.

According to one or more embodiments, a method of making an antifouling coating includes forming a polythioaminal polymer by reacting a fluorinated primary amine with an aldehyde to form an intermediate imine, and then reacting the intermediate imine with a dithiol. The method further includes depositing the polythioaminal on a substrate, and increasing a temperature of the polythioaminal deposited on the substrate to crosslink the polythioaminal and increase a contact angle of the substrate with crosslinked polythioaminal.

A double coating, curing method, cured coating, and kit are provided. A first layer of the double coating can be a first cure coating composition, which has a first hydroxy-functional resin, a first crosslinking agent, and a first catalyst. A second layer of a second cure coating composition can have a low hydrophilicity acrylic resin as a second hydroxy-functional resin, a second crosslinking agent, and a second catalyst. The first catalyst catalyzes crosslinking between the second hydroxy-functional resin and crosslinking agent, and not between the first hydroxy-functional resin and crosslinking agent. The second catalyst catalyzes crosslinking between the first hydroxy-functional resin and crosslinking agent, and not between the second hydroxy-functional resin and crosslinking agent. The first and/or second hydroxy functional resins can facilitate catalyst migration from one layer to the other. The separate compositions can be shelf-stable and/or the curing can occur at low temperature.

This invention relates to products H made by reaction of a cyclic alkyleneurea U, at least one multifunctional aldehyde A2, and at least one of (a) an aminoplast former M that is not the same as the cyclic alkyleneurea U, and (b) a monofunctional aldehyde A1, which product H is optionally etherified by reaction of at least a part of the hydroxyl groups formed by addition reaction of NH groups and aldehyde groups, with an alcohol having from one to ten carbon atoms, and wherein glyoxal is present in the at least one multifunctional aldehyde A2, to processes for their preparation, and to a method of use thereof in coating compositions.

This invention relates to products H made by reaction of a cyclic alkyleneurea U, at least one multifunctional aldehyde A2, and at least one of (a) an aminoplast former M that is not the same as the cyclic alkyleneurea U, and (b) a monofunctional aldehyde A1, which product H is optionally etherified by reaction of at least a part of the hydroxyl groups formed by addition reaction of NH groups and aldehyde groups, with an alcohol having from one to ten carbon atoms, and wherein glyoxal is present in the at least one multifunctional aldehyde A2, to processes for their preparation, and to a method of use thereof in coating compositions.

The present invention provides a nanoparticle containing a hydrophobic fluorescent substance accumulated therein and a thermosetting resin as a matrix, which nanoparticle, when used for labeling of a biological substance such as a protein or nucleic acid, has brightness sufficient for allowing pathological diagnosis using a fluorescence image obtained thereby. The present invention is a phosphor integrated dots nanoparticles wherein a thermosetting resin contains a structural unit formed from a raw material containing a hydrophobic substituent, and wherein a fluorescent substance is accumulated in the nanoparticle at least by hydrophobic interaction, preferably further by stacking interaction, with the hydrophobic substituent of the thermosetting resin.

The present invention provides a nanoparticle containing a hydrophobic fluorescent substance accumulated therein and a thermosetting resin as a matrix, which nanoparticle, when used for labeling of a biological substance such as a protein or nucleic acid, has brightness sufficient for allowing pathological diagnosis using a fluorescence image obtained thereby. The present invention is a phosphor integrated dots nanoparticles wherein a thermosetting resin contains a structural unit formed from a raw material containing a hydrophobic substituent, and wherein a fluorescent substance is accumulated in the nanoparticle at least by hydrophobic interaction, preferably further by stacking interaction, with the hydrophobic substituent of the thermosetting resin.