A breathable and waterproof membrane is made from a modified thermoplastic polyester elastomer. The breathable and waterproof membrane has a moisture permeability of greater than or equal to 25000 g/m.sup.2.Math.day. The modified thermoplastic polyester elastomer is formed from a thermoplastic polyester elastomer, a regenerated polyethylene terephthalate, and a compatibilizer. Based on a total weight of the modified thermoplastic polyester elastomer being 100 phr, a content of the regenerated polyethylene terephthalate is greater than 0 phr and up to 50 phr. Based on a total weight of the thermoplastic polyester elastomer being 100 wt %, the thermoplastic polyester elastomer includes 25 wt % to 75 wt % of hard segments and 25 wt % to 75 wt % of soft segments.

Provided is a toner that achieves low-temperature fixability, storability and charging performance all at a high level, in which a toner containing a crystalline resin and an amorphous resin, wherein a standard deviation of hydrogen nuclear relaxation times (HT1ρ-C) of the toner as measured by solid-state .sup.13C-NMR is from 0.0 to 5.0, and a hydrogen nuclear relaxation time (HT1ρ-C1) of a .sup.13C peak with the longest relaxation time out of the hydrogen nuclear relaxation times (HT1ρ-C) and a hydrogen nuclear relaxation time (HT1ρ-A1) of a .sup.13C peak with the shortest relaxation time out of the hydrogen nuclear relaxation times (HT1ρ-A) satisfy 3.0≦{(HT1ρ-C1)/(HT1ρ-A1)}≦6.0.

A process for emulsion polymerization is provided wherein a non-sulfonated polyester as a protective colloid in the process is provided. The non-sulfonated polyester may be an ethoxylated polyester. A product made by such process and a coating containing the product is also provided.

Provided are: an antistatic resin composition which not only has long-lasting and sufficient antistaticity and shows hardly any ion elution when made into a molded article but also is suitable for containers and packaging materials for storage and transport of electrical/electronic components; and a container and a packaging material which comprise the same.

The antistatic resin composition includes, with respect to 100 parts by mass of a synthetic resin, 3 to 20 parts by mass of at least one polymer compound (E) and 0.1 to 5 parts by mass of at least one alkali metal salt (F). The polymer compound (E) has a structure in which a diol, an aliphatic dicarboxylic acid, an aromatic dicarboxylic acid, a compound (B) which comprises at least one group represented by the following Formula (1) and has hydroxyl groups at both ends, and a compound (D) having a reactive functional group are bound via ester bonds, or ester bonds and amide bonds:

—CH.sub.2—CH.sub.2—O—  (1)

Provided are: an antistatic resin composition which not only has long-lasting and sufficient antistaticity and shows hardly any ion elution when made into a molded article but also is suitable for containers and packaging materials for storage and transport of electrical/electronic components; and a container and a packaging material which comprise the same.

The antistatic resin composition includes, with respect to 100 parts by mass of a synthetic resin, 3 to 20 parts by mass of at least one polymer compound (E) and 0.1 to 5 parts by mass of at least one alkali metal salt (F). The polymer compound (E) has a structure in which a diol, an aliphatic dicarboxylic acid, an aromatic dicarboxylic acid, a compound (B) which comprises at least one group represented by the following Formula (1) and has hydroxyl groups at both ends, and a compound (D) having a reactive functional group are bound via ester bonds, or ester bonds and amide bonds:

—CH.sub.2—CH.sub.2—O—  (1)

A polyester elastomer is provided, which includes a product of reacting (a) amide oligomer, (b) polyalkylene glycol, and (c) poly(alkylene arylate). (a) Amide oligomer has a chemical structure of

##STR00001##

or a combination thereof, wherein R.sup.1 is C.sub.4-8 alkylene group, R.sup.2 is C.sub.4-8 alkylene group, and each of x is independently an integer of 10 to 20. (b) Polyalkylene glycol has a chemical structure of

##STR00002##

wherein R.sup.3 is C.sub.2-10 alkylene group, and y is an integer of 20 to 30. (c) Poly(alkylene arylate) has a chemical structure of

##STR00003##

or a combination thereof, wherein Ar is

##STR00004##

R.sup.4 is C.sub.2-6 alkylene group, and z is an integer of 1 to 10.

The invention concerns a method for producing a polyester containing at least one 1,4:3,6-dianhydrohexitol unit comprising:.Math.a step of introducing, into a reactor, monomers comprising at least one monomer (A) that is a diacid or a diester and at least one monomer (B) that is a 1,4:3,6-dianhydrohexitol;.Math.a step of introducing, into the reactor, a catalytic system comprising either a catalyst comprising the element germanium and a catalyst comprising the element aluminum, or a catalyst comprising the elements germanium and aluminum, or a mixture of said two catalysts;.Math.a step of polymerising said monomers to form the polyester;.Math.a step of recovering a polyester composition comprising the polyester and the catalytic system. The invention also concerns a polyester composition containing a catalytic system comprising either a catalyst comprising the element germanium and a catalyst comprising the element aluminum, or a catalyst comprising the elements germanium and aluminum, or a mixture of said two catalysts, and the use of same to reduce the colouring of the polyester.

The invention concerns a method for producing a polyester containing at least one 1,4:3,6-dianhydrohexitol unit comprising:.Math.a step of introducing, into a reactor, monomers comprising at least one monomer (A) that is a diacid or a diester and at least one monomer (B) that is a 1,4:3,6-dianhydrohexitol;.Math.a step of introducing, into the reactor, a catalytic system comprising either a catalyst comprising the element germanium and a catalyst comprising the element aluminum, or a catalyst comprising the elements germanium and aluminum, or a mixture of said two catalysts;.Math.a step of polymerising said monomers to form the polyester;.Math.a step of recovering a polyester composition comprising the polyester and the catalytic system. The invention also concerns a polyester composition containing a catalytic system comprising either a catalyst comprising the element germanium and a catalyst comprising the element aluminum, or a catalyst comprising the elements germanium and aluminum, or a mixture of said two catalysts, and the use of same to reduce the colouring of the polyester.

A variety of forms and form components are provided, including form components for articles of footwear and athletic equipment. The articles include a composition having a form structure, wherein the composition includes a thermoplastic copolyester elastomer comprising: (a) a plurality of first segments, each first segment derived from a dihydroxy-terminated polydiol; (b) a plurality of second segments, each second segment derived from a diol; and (c) a plurality of third segments, each third segment derived from an aromatic dicarboxylic acid. Methods of making the compositions and forms are provided, as well as methods of making an article of footwear including at least one of the form components. In some aspects, the forms and form components can be made by extrusion or injection molding to form the polymeric composition, or extrusion or injection molding to form the polymeric composition followed by compression molding of the form.

This polyethylene furanoate has an intrinsic viscosity of 0.95 - 1.50 dl/g. Said intrinsic viscosity is measured (the Huggins constant is defined as 0.32) at 30° C. by using an Ubbelohde viscometer, after dissolving 0.25 g of the polyethylene furanoate in 50 ml of a solvent mixture of phenol/1,1,2,2-tetrachloroethane = 50/50 (weight ratio).