Disclosed is a cylindrical battery cell configured such that the outer surface of a cylindrical case excluding electrode terminals is wrapped by a heat-shrinkable tube, wherein the heat-shrinkable tube includes a tube substrate made of a polyester-based resin, the tube substrate being heat-shrinkable; a reinforcement agent, made of a nylon-based resin, for increasing the tensile stress and operating temperature of the heat-shrinkable tube; and an ultraviolet (UV) absorber for absorbing ultraviolet rays radiated to the heat-shrinkable tube and emitting the absorbed ultraviolet rays as thermal energy to prevent the scission of polymer chains of the nylon-based resin or the polyester-based resin as the result of reaction with oxygen.

Disclosed is a cylindrical battery cell configured such that the outer surface of a cylindrical case excluding electrode terminals is wrapped by a heat-shrinkable tube, wherein the heat-shrinkable tube includes a tube substrate made of a polyester-based resin, the tube substrate being heat-shrinkable; a reinforcement agent, made of a nylon-based resin, for increasing the tensile stress and operating temperature of the heat-shrinkable tube; and an ultraviolet (UV) absorber for absorbing ultraviolet rays radiated to the heat-shrinkable tube and emitting the absorbed ultraviolet rays as thermal energy to prevent the scission of polymer chains of the nylon-based resin or the polyester-based resin as the result of reaction with oxygen.

A solid multiphase polymer blend material comprising: (i) a polyphenolic substance having a molecular weight of at least 500 g/mol; and (ii) a polyester having a molecular weight of at least 500 g/mol; wherein at least a portion of the polyphenolic substance is covalently bonded directly or through a linking moiety to the polyester. Methods for producing the blend material are also described, e.g., homogeneously melt blending a mixture comprising components (i) and (ii) under conditions resulting in covalent attachment of at least a portion of the polyphenolic substance directly or through a linking moiety to the polyester. Methods for producing objects made of the blend material by melt extrusion are also described.

A solid multiphase polymer blend material comprising: (i) a polyphenolic substance having a molecular weight of at least 500 g/mol; and (ii) a polyester having a molecular weight of at least 500 g/mol; wherein at least a portion of the polyphenolic substance is covalently bonded directly or through a linking moiety to the polyester. Methods for producing the blend material are also described, e.g., homogeneously melt blending a mixture comprising components (i) and (ii) under conditions resulting in covalent attachment of at least a portion of the polyphenolic substance directly or through a linking moiety to the polyester. Methods for producing objects made of the blend material by melt extrusion are also described.

The present invention relates to the combination of certain halogen- free flame retardant additives in a copolyester to improve the flame retardant properties of the copolyester composition while retaining clarity and impact properties, methods of making the copolyester composition and articles made from the copolyester compositions. More specifically, the present invention relates to the use of oligomeric phosphate ester flame retardant compounds in copolyester compositions to improve the flame retardant properties while retaining clarity, glass transition temperature, and impact properties.

The present invention relates to the combination of certain halogen- free flame retardant additives in a copolyester to improve the flame retardant properties of the copolyester composition while retaining clarity and impact properties, methods of making the copolyester composition and articles made from the copolyester compositions. More specifically, the present invention relates to the use of oligomeric phosphate ester flame retardant compounds in copolyester compositions to improve the flame retardant properties while retaining clarity, glass transition temperature, and impact properties.

A liquid crystal polyester resin comprising 42 to 80 mol % of structural unit (I) relative to 100 mol % of the total structural unit of the liquid crystal polyester resin, and ΔS (entropy of melting) defined by equation [1] is 0.01×10.sup.−3 to 2.7×10.sup.−3 J/g.Math.K:

ΔS(J/g.Math.K)=ΔHm(J/g)/Tm(K)  [1]

wherein Tm is an endothermic peak temperature determined by: after observation of an endothermic peak temperature (Tm.sub.1) observed when heating a liquid crystal polyester under temperature rising conditions of 20° C./minute from room temperature in differential scanning calorimetry, the liquid crystal polyester was maintained at a temperature of Tm.sub.1+20° C. for 5 minutes, followed by observation of the endothermic peak temperature observed when the temperature has fallen to room temperature under temperature falling conditions of 20° C./minute and then raised under temperature rising conditions of 20° C./minute, and ΔHm is an endothermic peak area of Tm:

##STR00001##

A liquid crystal polyester resin comprising 42 to 80 mol % of structural unit (I) relative to 100 mol % of the total structural unit of the liquid crystal polyester resin, and ΔS (entropy of melting) defined by equation [1] is 0.01×10.sup.−3 to 2.7×10.sup.−3 J/g.Math.K:

ΔS(J/g.Math.K)=ΔHm(J/g)/Tm(K)  [1]

wherein Tm is an endothermic peak temperature determined by: after observation of an endothermic peak temperature (Tm.sub.1) observed when heating a liquid crystal polyester under temperature rising conditions of 20° C./minute from room temperature in differential scanning calorimetry, the liquid crystal polyester was maintained at a temperature of Tm.sub.1+20° C. for 5 minutes, followed by observation of the endothermic peak temperature observed when the temperature has fallen to room temperature under temperature falling conditions of 20° C./minute and then raised under temperature rising conditions of 20° C./minute, and ΔHm is an endothermic peak area of Tm:

##STR00001##

Provided is a thermoplastic resin composition for cooling medium transportation pipes, which has high barrier performance, is flexible and has good extrusion moldability. A thermoplastic resin composition which comprises a matrix that comprises a thermoplastic resin and a domain that comprises a rubber and is dispersed in the matrix, the thermoplastic resin composition being characterized by having an oxygen permeability coefficient (cm.sup.3.Math.mm/(m.sup.2.Math.day.Math.mmHg)) of 0.02 or less at 21° C. and at a humidity of 0%, and being also characterized in that the melt viscosity of the thermoplastic resin constituting the matrix is 300 Pa.Math.s or less at 250° C. and at a shear rate of 243.2 s.sup.−1, the thermoplastic resin comprises a thermoplastic resin having a melting point or a glass transition temperature of 150° C. or higher and a thermoplastic resin having an oxygen permeability coefficient of 0.004 or less or comprises a thermoplastic resin having a melting point or a glass transition temperature of 150° C. or higher and an oxygen permeability coefficient of 0.004 or less, and the rubber comprises an isobutylene-based block copolymer and an olefin- or styrene-based polymer having an epoxy group, an amino group, a hydroxyl group, an acid anhydride group or a carboxyl group.

Provided is a thermoplastic resin composition for cooling medium transportation pipes, which has high barrier performance, is flexible and has good extrusion moldability. A thermoplastic resin composition which comprises a matrix that comprises a thermoplastic resin and a domain that comprises a rubber and is dispersed in the matrix, the thermoplastic resin composition being characterized by having an oxygen permeability coefficient (cm.sup.3.Math.mm/(m.sup.2.Math.day.Math.mmHg)) of 0.02 or less at 21° C. and at a humidity of 0%, and being also characterized in that the melt viscosity of the thermoplastic resin constituting the matrix is 300 Pa.Math.s or less at 250° C. and at a shear rate of 243.2 s.sup.−1, the thermoplastic resin comprises a thermoplastic resin having a melting point or a glass transition temperature of 150° C. or higher and a thermoplastic resin having an oxygen permeability coefficient of 0.004 or less or comprises a thermoplastic resin having a melting point or a glass transition temperature of 150° C. or higher and an oxygen permeability coefficient of 0.004 or less, and the rubber comprises an isobutylene-based block copolymer and an olefin- or styrene-based polymer having an epoxy group, an amino group, a hydroxyl group, an acid anhydride group or a carboxyl group.