Disclosed is an impact-resistant and aging-resistant reflective plastic applied to an automobile, which is prepared by copolymerizing of polyether polyol, 4,4,4-triphenylmethane triisocyanate and a benzimidazole derivative modified ZnS-mesoporous silica composite, the benzimidazole derivative modified ZnS-mesoporous silica composite is a ZnS-mesoporous silica composite modified by an anti-aging agent and a silane coupling agent KH-560, the ZnS-mesoporous silica is obtained by mixing an amphoteric surfactant, zinc chloride, and γ-aminopropyltrimethoxysilane uniformly, then reacting in ethyl orthosilicate, and calcining with hydrogen sulfide. In the present disclosure, by dispersing zinc sulfide in the pores of mesoporous carbon dioxide, chemical grafting 2-(2-hydroxy-5-aminophenyl)benzimidazole as a bridge onto isocyanate, and then polymerizing into polyurethane, which can improve the reflective performance and aging resistance of polyurethane, and improve the abrasion resistance and impact resistance.

Disclosed is an impact-resistant and aging-resistant reflective plastic applied to an automobile, which is prepared by copolymerizing of polyether polyol, 4,4,4-triphenylmethane triisocyanate and a benzimidazole derivative modified ZnS-mesoporous silica composite, the benzimidazole derivative modified ZnS-mesoporous silica composite is a ZnS-mesoporous silica composite modified by an anti-aging agent and a silane coupling agent KH-560, the ZnS-mesoporous silica is obtained by mixing an amphoteric surfactant, zinc chloride, and γ-aminopropyltrimethoxysilane uniformly, then reacting in ethyl orthosilicate, and calcining with hydrogen sulfide. In the present disclosure, by dispersing zinc sulfide in the pores of mesoporous carbon dioxide, chemical grafting 2-(2-hydroxy-5-aminophenyl)benzimidazole as a bridge onto isocyanate, and then polymerizing into polyurethane, which can improve the reflective performance and aging resistance of polyurethane, and improve the abrasion resistance and impact resistance.

A moisture-curable composition, including: a) at least one polyurethane polymer P having isocyanate groups; b) at least one blocked polyamine BA having blocked, hydrolytically activatable amino groups; and c) at least one monoamine MA of formula (V),

##STR00001##

where R.sup.a represents a linear, cyclic, or branched alkyl or alkenyl radical or optionally substituted aryl radical with 1 to 12 C atoms and optionally including ether oxygen atoms; R.sup.b and R.sup.c either independently represent a rest R.sup.a or a hydrogen atom, where at least one of R.sup.b and R.sup.c is a hydrogen atom, or R.sup.b and R.sup.c together with the N atom of monoamine MA form an aldimine group that under influence of water hydrolyzes to a aldehyde and an amine R.sup.a—NH.sub.2; wherein polymer P is the reaction product of 2,4- and/or 2,6-toluylene diisocyanate (TDI) and at least one polyol, wherein the polyol has an average functionality of >2.

A moisture-curable composition, including: a) at least one polyurethane polymer P having isocyanate groups; b) at least one blocked polyamine BA having blocked, hydrolytically activatable amino groups; and c) at least one monoamine MA of formula (V),

##STR00001##

where R.sup.a represents a linear, cyclic, or branched alkyl or alkenyl radical or optionally substituted aryl radical with 1 to 12 C atoms and optionally including ether oxygen atoms; R.sup.b and R.sup.c either independently represent a rest R.sup.a or a hydrogen atom, where at least one of R.sup.b and R.sup.c is a hydrogen atom, or R.sup.b and R.sup.c together with the N atom of monoamine MA form an aldimine group that under influence of water hydrolyzes to a aldehyde and an amine R.sup.a—NH.sub.2; wherein polymer P is the reaction product of 2,4- and/or 2,6-toluylene diisocyanate (TDI) and at least one polyol, wherein the polyol has an average functionality of >2.

The present invention provides a flame retardant composition and a thermoplastic polyurethane composition both of which has excellent flame retardance. A phosphoramidate compound having a specific structure (component (B)) and a triazine-based compound (component (C)) are used as a flame retardant for a flame retardant composition and a flame retardant thermoplastic polyurethane composition. In one embodiment, the flame retardant thermoplastic polyurethane composition of the present invention includes a thermoplastic polyurethane resin (component (A)), a phosphoramidate compound (component (B)) and a triazine-based compound (component (C)).

The present invention provides a flame retardant composition and a thermoplastic polyurethane composition both of which has excellent flame retardance. A phosphoramidate compound having a specific structure (component (B)) and a triazine-based compound (component (C)) are used as a flame retardant for a flame retardant composition and a flame retardant thermoplastic polyurethane composition. In one embodiment, the flame retardant thermoplastic polyurethane composition of the present invention includes a thermoplastic polyurethane resin (component (A)), a phosphoramidate compound (component (B)) and a triazine-based compound (component (C)).

A nonlimiting example method of forming highly spherical carbon nanomaterial-graft-polyurethane (CNM-g-polyurethane) particles may comprising: mixing a mixture comprising: (a) carbon nanomaterial-graft-polyurethane (CNM-g-polyurethane), wherein the CNM-g-polyurethane particles comprises: a polyurethane grafted to a carbon nanomaterial, (b) a carrier fluid that is immiscible with the polyurethane of the CNM-g-polyurethane, optionally (c) a thermoplastic polymer not grafted to a CNM, and optionally (d) an emulsion stabilizer at a temperature greater than a melting point or softening temperature of the polyurethane of the CNM-g-polyurethane and the thermoplastic polymer, when included, and at a shear rate sufficiently high to disperse the CNM-g-polyurethane in the carrier fluid; cooling the mixture to below the melting point or softening temperature to form CNM-g-polyurethane particles; and separating the CNM-g-polyurethane particles from the carrier fluid.

A nonlimiting example method of forming highly spherical carbon nanomaterial-graft-polyurethane (CNM-g-polyurethane) particles may comprising: mixing a mixture comprising: (a) carbon nanomaterial-graft-polyurethane (CNM-g-polyurethane), wherein the CNM-g-polyurethane particles comprises: a polyurethane grafted to a carbon nanomaterial, (b) a carrier fluid that is immiscible with the polyurethane of the CNM-g-polyurethane, optionally (c) a thermoplastic polymer not grafted to a CNM, and optionally (d) an emulsion stabilizer at a temperature greater than a melting point or softening temperature of the polyurethane of the CNM-g-polyurethane and the thermoplastic polymer, when included, and at a shear rate sufficiently high to disperse the CNM-g-polyurethane in the carrier fluid; cooling the mixture to below the melting point or softening temperature to form CNM-g-polyurethane particles; and separating the CNM-g-polyurethane particles from the carrier fluid.

An aqueous dispersion of a hydrophobically-modified alkali-soluble multistage polymer useful as a thickener affording high thickening efficiency and an aqueous coating composition comprising such aqueous dispersion showing good stability after heat aging without compromising stability upon addition of colorants.

An aqueous dispersion of a hydrophobically-modified alkali-soluble multistage polymer useful as a thickener affording high thickening efficiency and an aqueous coating composition comprising such aqueous dispersion showing good stability after heat aging without compromising stability upon addition of colorants.