A hardcoat film includes a substrate; a hardcoat layer; and an anti-scratch layer, where the hardcoat layer includes a cured product of polyorganosilsesquioxane, the polyorganosilsesquioxane has a siloxane constitutional unit containing a (meth)acryloyl group and a siloxane constitutional unit containing an epoxy group and is represented by the General Formula (1), a film thickness of the anti-scratch layer is 0.05 to 5 μm, and the anti-scratch layer includes a cured product of a compound having two or more (meth)acryloyl groups in one molecule, where Ra represents a group containing a (meth)acryloyl group; Rb represents a group containing an epoxy group; Rc represents a monovalent substituent; p, q, and r represent a proportion of Ra, Rb, and Rc in the General Formula (1) respectively; p+q+r is 100; p and q are greater than 0; r is equal to or greater than 0; p/q is 0.01 to 99.

A composition containing: (a) a polysiloxane resin, wherein the polysiloxane resin contains the following siloxane units: [R3SiO.sub.1/2], [(OZ).sub.qSiO.sub.(4-q)/2] and at least one of [(OZ).sub.tR.sup.EPSiO.sub.(3-t)/2] and [(OZ).sub.dRR.sup.EPSiO.sub.(2-d)/2]; where: each R is independently in each occurrence selected from hydrocarbyls, R.sup.EP is an epoxy functional hydrocarbyl group, subscript q is in each occurrence a number selected from a range of 0-3, subscript t is in each occurrence a number selected from a range of 0-2, and subscript d is in each occurrence a number selected from a range of 0-1 provided that the average concentration of OZ groups is at least 15 mole-percent relative to moles of silicon atoms in the polysiloxane resin; (b) a photo acid generator; (c) a moisture cure catalyst; and (d) optionally, an epoxy functional diluent.

A composition containing: (a) a polysiloxane resin, wherein the polysiloxane resin contains the following siloxane units: [R3SiO.sub.1/2], [(OZ).sub.qSiO.sub.(4-q)/2] and at least one of [(OZ).sub.tR.sup.EPSiO.sub.(3-t)/2] and [(OZ).sub.dRR.sup.EPSiO.sub.(2-d)/2]; where: each R is independently in each occurrence selected from hydrocarbyls, R.sup.EP is an epoxy functional hydrocarbyl group, subscript q is in each occurrence a number selected from a range of 0-3, subscript t is in each occurrence a number selected from a range of 0-2, and subscript d is in each occurrence a number selected from a range of 0-1 provided that the average concentration of OZ groups is at least 15 mole-percent relative to moles of silicon atoms in the polysiloxane resin; (b) a photo acid generator; (c) a moisture cure catalyst; and (d) optionally, an epoxy functional diluent.

A composition containing: (a) a polysiloxane resin, wherein the polysiloxane resin contains the following siloxane units: [R3SiO.sub.1/2], [(OZ).sub.qSiO.sub.(4-q)/2] and at least one of [(OZ).sub.tR.sup.EPSiO.sub.(3-t)/2] and [(OZ).sub.dRR.sup.EPSiO.sub.(2-d)/2]; where: each R is independently in each occurrence selected from hydrocarbyls, R.sup.EP is an epoxy functional hydrocarbyl group, subscript q is in each occurrence a number selected from a range of 0-3, subscript t is in each occurrence a number selected from a range of 0-2, and subscript d is in each occurrence a number selected from a range of 0-1 provided that the average concentration of OZ groups is at least 15 mole-percent relative to moles of silicon atoms in the polysiloxane resin; (b) a photo acid generator; (c) a moisture cure catalyst; and (d) optionally, an epoxy functional diluent.

This organopolysiloxane having a structural unit represented by general formula (1):

##STR00001##

(in the formula, R.sup.1 represents an unsubstituted or substituted alkyl group having 1-12 carbon atoms or an unsubstituted or substituted aryl group having 6-10 carbon atoms) and having at least one group that directly binds to a silicon atom and that is selected from the groups represented by general formula (2);

R.sup.2O—  (2)

(in the formula, R.sup.2 represents a hydrogen atom, an unsubstituted or substituted alkyl group having 1-10 carbon atoms, or an unsubstituted or substituted aryl group having 6-10 carbon atoms), is capable of achieving both hardness and bending resistance, exhibits excellent fast curing ability even when an amine-based compound is used as a curing catalyst, and is highly safe.

This organopolysiloxane having a structural unit represented by general formula (1):

##STR00001##

(in the formula, R.sup.1 represents an unsubstituted or substituted alkyl group having 1-12 carbon atoms or an unsubstituted or substituted aryl group having 6-10 carbon atoms) and having at least one group that directly binds to a silicon atom and that is selected from the groups represented by general formula (2);

R.sup.2O—  (2)

(in the formula, R.sup.2 represents a hydrogen atom, an unsubstituted or substituted alkyl group having 1-10 carbon atoms, or an unsubstituted or substituted aryl group having 6-10 carbon atoms), is capable of achieving both hardness and bending resistance, exhibits excellent fast curing ability even when an amine-based compound is used as a curing catalyst, and is highly safe.

The present invention provides organic-inorganic composite particles of which the creep deformation is further suppressed; and a method for producing the same. Organic-inorganic composite particles 10 include a compound having a siloxane bond and has a particle diameter d0, and when a load is applied such that an amount of displacement Ds satisfies 0.08d0≤Ds≤0.15d0 and is held for 180 seconds, conditions of the following Formulae (1) and (2) are satisfied:
(D180−Ds)/d0≤1%  Formula(1); and
(Dmax−Ds)/d0≤1%  Formula (2), wherein d0 is an average particle diameter, D180 is an amount of displacement of the particle diameter after 180 seconds of application of the load, and Dmax is the maximum amount of displacement of the particle diameter during the 180 seconds.

The present invention provides organic-inorganic composite particles of which the creep deformation is further suppressed; and a method for producing the same. Organic-inorganic composite particles 10 include a compound having a siloxane bond and has a particle diameter d0, and when a load is applied such that an amount of displacement Ds satisfies 0.08d0≤Ds≤0.15d0 and is held for 180 seconds, conditions of the following Formulae (1) and (2) are satisfied:
(D180−Ds)/d0≤1%  Formula(1); and
(Dmax−Ds)/d0≤1%  Formula (2), wherein d0 is an average particle diameter, D180 is an amount of displacement of the particle diameter after 180 seconds of application of the load, and Dmax is the maximum amount of displacement of the particle diameter during the 180 seconds.

Through the present invention, by undergoing a step in which a straight-chain diorganopolysiloxane having silanol groups at both terminal ends of the molecular chain thereof, a hydrolyzable silane and/or a partial hydrolysis condensate thereof having a hydrolyzable group capable of detaching a lactic acid ester, and an amino-group-containing hydrolyzable organosilane and/or a partial hydrolysis condensate thereof are pre-mixed/reacted in advance and silanol groups at both terminal ends of the molecular chain of a main agent (base polymer) are blocked by specific hydrolyzable silyl groups, it is possible to manufacture a lactic-acid-ester-type room-temperature-curable organopolysiloxane composition excellent in all characteristics including curability, adhesive properties, workability, and the like that were not attainable by the conventional lactic-acid-ester-type room-temperature curable (RTV) silicone rubber composition.

A thermoplastic composition comprising: a homopolycarbonate; a poly(carbonate siloxane) component present in an amount effective to provide 0.5-20 wt % total siloxane content; an antimicrobial agent comprising silver zirconium phosphate, silver phosphate glass, or a combination thereof; optionally, an additive composition; each based on the total weight of the composition which totals to 100 wt %.