A composition for three-dimension (3D) printing, a method for 3D printing, and a resulting article having porous structure are provided. Such a composition includes from 50% to 100% by weight of a base polymer comprising polyolefin (such as ultra-high molecular weight polyethylene), from 0% to 50% by weight of a glue polymer (such as HDPE or PP), and optionally additive. A composition can be applied in a layer, and the base polymer and the glue polymer each has a predetermined size or size distribution. The composition is sintered in a selected area to form a layer of a solid article, which has a predetermined pore size or pore size distribution. The predetermined particle size or size distribution for each of the base polymer and the glue polymer is determined through computer simulation based on the predetermined pore size or pore size distribution in the layer of the solid article.

A method for producing a microporous material comprising the steps of: providing an ultrahigh molecular weight polyethylene (UHMWPE); providing a filler; providing a processing plasticizer; adding the filler to the UHMWPE in a mixture being in the range of from about 1:9 to about 15:1 filler to UHMWPE by weight; adding the processing plasticizer to the mixture; extruding the mixture to form a sheet from the mixture; calendering the sheet; extracting the processing plasticizer from the sheet to produce a matrix comprising UHMWPE and the filler distributed throughout the matrix; stretching the microporous material in at least one direction to a stretch ratio of at least about 1.5 to produce a stretched microporous matrix; and subsequently calendering the stretched microporous matrix to produce a microporous material which exhibits improved physical and dimensional stability properties over the stretched microporous matrix.

A semicrystalline multiblock copolymer includes alternating blocks of semicrystalline isotactic polypropylene (iPP) and semicrystalline polyethylene (PE), having a block arrangement according to formula (I):

(iPP.sub.w).sub.p(PE.sub.x)(iPP.sub.y).sub.m(PE.sub.z).sub.n   (I),

wherein p is 0 or 1; m is 0 or 1; n is 0 or 1; the sum of p, m, and n is 1, 2, or 3; and the sum of w, x, y, and z is greater than or equal to 40 kg/mol, with the provisos that: when m and n are 0, the sum of w and x is greater than or equal to 140 kg/mol; and when p and n are 0, the sum of y and x is greater than or equal to 140 kg/mol. Related compositions and methods are also provided.

In particles removal with extremely high filtration efficiency and the ability to block submicron airborne particles by a sieving mechanism is provided. This novel nanoporous filter advantageously combines extremely high transmittance for visible light and ultraviolet light, reusability after cleaning or disinfection by ultraviolet irradiation or simple washing, a customizable sieving pore size ranging from a few nanometers to 500 nanometers, and the ability to carry bactericidal, virucidal or other reagents or particles on the nano or micro scale.

A cut resistant fabric and a method of manufacturing a cut resistant fiber is disclosed herein. The fabric comprises a Ultra High Molecular Weight Polyethylene (UHMWPE) material and a sheet shaped wollastonite filler. The sheet shaped wollastonite filler is treated with a coupling agent and mixed with the UHMWPE material. A thickness of the sheet shaped wollastonite filler is less than 10 micrometers (μm). The method comprises providing the sheet shaped wollastonite filler having a thickness of less than 10 μm and treating the sheet shaped wollastonite filler with a coupling agent at a first predefined temperature to obtain a uniform solution. The method further comprises mixing the uniform solution with a fiber solution comprising UHMWPE resin at a second predefined temperature.

Use of a closure liner composition for a container used within pressurized dispense systems said composition comprising a blend of a thermoplastic elastomer (TPE) and UHMW-PE.

A polyolefin microporous film includes: a polyethylene-based resin; and a polyolefin (B) other than polyethylene. The polyolefin microporous film has peaks at temperatures of lower than 150° C. and 150° C. or higher respectively in a differential scanning calorimeter (DSC). A half width of the peak at lower than 150° C. is 10° C. or lower. A puncture strength in terms of 10 μm is 2.0 N or more.

In an embodiment, a thermoplastic vulcanizate (TPV) composition is provided. The TPV composition includes a thermoplastic polyolefin; and an ethylene based copolymer rubber, wherein the ethylene based copolymer rubber has: a Mw of from 500,000 g/mol to 3,000,000 g/mol, a Mw/Mn of 4.0 or lower, and a g′.sub.vis of 0.90 or greater. In another embodiment, a TPV composition includes a thermoplastic phase and an ethylene-propylene-diene terpolymer, wherein the thermoplastic vulcanizate composition has: a hardness of from 20 Shore A to 60 Shore D; and a stress relaxation slope of −1 to −5 (l/min) as measured by an Elastocon stress relaxation instrument.

(Co)polymer matrix composites including a porous (co)polymeric network; a multiplicity of thermally-conductive particles, and a multiplicity of endothermic particles distributed within the (co)polymeric network structure; wherein the thermally-conductive particles and endothermic particles are present in a range from 15 to 99 weight percent, based on the total weight of the particles and the (co)polymer (excluding the solvent). Optionally, the (co)polymer matrix composite volumetrically expands by at least 10% of its initial volume when exposed to a temperature of at least 135° C. Methods of making and using the (co)polymer matrix composites are also disclosed. The (co)polymer matrix composites are useful, for example, as heat dissipating or heat absorbing articles, as fillers, thermal interface materials, and thermal management materials, for example, in electronic devices, more particularly mobile handheld electronic devices, power supplies, and batteries.

(Co)polymer matrix composites including a porous (co)polymeric network; a multiplicity of thermally-conductive particles, a multiplicity of intumescent particles and optionally a multiplicity of endothermic particles distributed within the (co)polymeric network structure; wherein the thermally-conductive particles, intumescent particles and optional endothermic particles are present in a range from 15 to 99 weight percent, based on the total weight of the particles and the (co)polymer (excluding the solvent). Optionally, the (co)polymer matrix composite volumetrically expands by at least 50% over its initial volume when exposed to at least one temperature greater than 135° C. when exposed to at least one temperature greater than 135° C. Methods of making and using the (co)polymer matrix composites are also disclosed. The (co)polymer matrix composites are useful, for example, as heat dissipating or heat absorbing articles, thermally-initiated fuses, and fire-stop devices.