The present invention is in the field of agricultural pathogen control. More specifically the invention relates to methods and compounds for controlling herbivorous arthropods, in particular insects and mites. The invention also provides for compositions comprising the same, methods of making the same, and methods of controlling plant disease.

Compounds of formula (I) wherein the substituents are as defined in claim 1, and the agrochemically acceptable salts, stereoisomers, enantiomers, tautomers and N-oxides of those compounds, can be used as insecticides.

##STR00001##

A preparation method of a sulfur-containing biphenylsulfur-containing biphenyl compound shown by the general formula (I) has a reaction formula as follows:

##STR00001##

Each substituent in the formula is defined in the description. In the method, halogeno benzene shown by the general formula (II) generates a coupling reaction in a catalytic system composed of a nickel compound and at least one ligand under the combined action of metallic zinc to obtain the sulfur-containing biphenyl compound shown by the general formula (I).

This invention provides for compounds of the formula:

##STR00001## wherein the variables are defined herein, or salt thereof, compositions comprising these compounds, and method for the treatment, control or prevention of a parasitic infestation or infection in an animal in need thereof by administering an effective amount of these compounds to said animal.

An extended-release plastic matrix formulation (PMF-ExR) comprising a polyethylene-comprising polymer, a plasticizer, and at least one insecticide as active components is described. The PMF-ExR may be used in the manufacture of a wearable device for treating ectoparasitic infestations.

The present invention relates to novel active compound combinations comprising at least one known compound of the formula (I) and at least one active compound of group (II), which combinations are highly suitable for controlling animal and microbial pests such as unwanted insects and/or unwanted acarids and/or unwanted nematodes.

The present invention relates to novel active compound combinations comprising at least one known compound of the formula (I) and at least one active compound of group (II), which combinations are highly suitable for controlling animal and microbial pests such as unwanted insects and/or unwanted acarids and/or unwanted nematodes.

Compounds of formula I (Formula I) wherein the substituents are as defined in claim 1, and the agrochemically acceptable salts, stereoisomers, enantiomers, tautomers and N-oxides of those compounds, can be used as insecticides.

##STR00001##

Compounds of formula I (Formula I) wherein the substituents are as defined in claim 1, and the agrochemically acceptable salts, stereoisomers, enantiomers, tautomers and N-oxides of those compounds, can be used as insecticides.

##STR00001##

Compositions and methods for controlling pests are disclosed. The compositions can be electrostatically charged, can be attractive for translocation by the social insects into nesting, tunneling, and/or gathering structures of the social insects, or both. Kits comprising the compositions and a powder delivery device operable to electrostatically charge a pest control composition during delivery are also disclosed.