Light emitting devices (LEDs) are described herein. An LED includes a light emitting semiconductor structure, a wavelength converting material and an off state white material. The light emitting semiconductor structure includes a light-emitting active layer disposed between an n-layer and a p-layer. The wavelength converting material has a first surface adjacent the light emitting semiconductor structure and a second surface opposite the first surface. The off state white material is in direct contact with the second surface of the wavelength converting material and includes multiple core-shell particles disposed in an optically functional material. Each of the core-shell particles includes a core material encased in a polymer or inorganic shell. The core material includes a phase change material.

Provided are: coated flaky titanic acid particles, which can form a design coating film with a good silky texture and shadowed appearance when flaky titanic acid is applied to an organic solvent-based paint and, which can also sufficiently suppress discoloration (yellowing) of the coating film even in a relatively severe environment, such as prolonged exposure to ultraviolet light; and a production method therefor.

The surface of the flaky titanic acid particles has an oxide and/or hydroxide of aluminum, and an anionic surfactant present thereon. Preferably, the anionic surfactant is a hydrocarbon-based anionic surfactant having 5 or more carbon atoms in the main chain or a fluorinated anionic surfactant having 4 or more carbon atoms. Said production method comprises: a step for maintaining an aqueous slurry, which contains flaky titanic acid particles and an aluminum source, at a temperature of 50-95 C. inclusive and at a pH of 5-12 inclusive to treat the surface of the flaky titanic acid particles with an oxide and/or hydroxide of aluminum; and a subsequent step for mixing the obtained flaky titanic acid and an anionic surfactant in a solution.

A thin film structure including a reflector layer; and a hybrid layer including an organic colored material and at least one of an organic filler and an inorganic filler; wherein a concentration of the at least one of an organic filler or an inorganic filler is in a range of from about 3 wt. % to about 30 wt. %. A method of making a thin film structure is also disclosed.

There is provided a paint formulation comprising a composite pigment, said composite pigment being selected from the group consisting of metal oxide/silica, metal oxide/silicate, metal oxide/alumina, metal oxide/metal oxide and metal oxide/zirconia, wherein the size and amount of said composite pigment are selected to increase the opacity of said paint formulation.

A thin film structure including a reflector layer; and a hybrid layer including an organic colored material and at least one of an organic filler and an inorganic filler; wherein a concentration of the at least one of an organic filler or an inorganic filler is in a range of from about 3 wt. % to about 30 wt. %. A method of making a thin film structure is also disclosed.

Composite pigments are provided which comprise a mineral pigment (such as kaolin clay, titanium dioxide, talc, mica or a mixture of two or more of these mineral pigments) and calcium carbonate precipitated in-situ on the surfaces of the particles of the mineral pigment.

A stable and consistent reversible coloured photochromic additive changes colour from original buff to desired colour shade between pink to blue when exposed to sunlight and restores to original colour in the absence of the sunlight; simultaneously having synergistic SPF value of at least 3. The additive comprises titanium dioxide, psuedoboehmite, iron oxide hydroxide and tungsten oxide.

A titania-carbon-sulfur composite including a titania-carbon composite prepared by mixing cylindrical carbon materials and titania (TiO.sub.2-x), in which some oxygen is reduced (i.e., x is less than 2), to have a structure in which cylindrical carbon materials are entangled and interconnected in three dimensions; and sulfur introduced into at least a part of the external surface and inside of the titania-carbon (TiO.sub.2C) composite, and a method for preparing the same.

The invention relates to composite pigment particles containing calcium phosphate, their manufacture and their use in coatings, plastics and laminates. The composite pigment particles contain titanium dioxide pigment particles and precipitated calcium phosphate. In one embodiment, the composite pigment particles additionally contain an inorganic and/or organic filler as an extender, preferably selected from the group comprising Ca, CaMg and Mg carbonates, natural and synthetic silicon dioxide and oxides. The composite pigment particles are manufactured in a combined process of dispersion and precipitation. Depending upon the combination selected, use of composite titanium dioxide pigment particles of the invention can provide improved optical properties such as tinting strength or permits pigment savings with little to no loss of optical properties. In particular, the composite pigment particles of the invention can be used to replace part or all of the titanium dioxide contained in the user's system.

According to an example aspect of the present invention, there is provided a tint base comprising titanium dioxide, a vehicle, and conventional additives, which tint base is capable of displaying a preselected colour upon the addition of a colorant, wherein at least 4% by weight of the titanium dioxide is present in the form of opaque aggregates of titanium dioxide and precipitated calcium carbonate particles wherein the titanium dioxide particles are at least partially encased by the particles of precipitated calcium carbonate.