This invention involves a coated flaky metal effect pigment comprising a metal effect flake as substrate coated by the following consecutive coating sequences: a) optionally a discontinuous or a continuous layer of Mo-oxide, b1) an inorganic metal oxide layer comprising mainly SiO.sub.2, c1) a hybrid layer comprising SiO.sub.2 modified by a diphenyl silane, a phenylsilane or mixtures thereof or c2) a hybrid layer comprising SiO.sub.2 modified by a diphenyl silane, a phenylsilane or mixtures thereof, b2) an inorganic metal oxide layer comprising mainly SiO.sub.2, and d) optionally a further top-coat of organofunctional silanes, titanates, aluminates or zirconates.

Temperature-stable effect pigments based on multicoated flake-form substrates, and the use thereof in paints, coatings, printing inks, plastics and in particular in glazes, enamels, ceramic or glass-like materials.

Interference pigments based on SiO.sub.2 flakes coated with crystallites of alpha-Fe.sub.2O.sub.3. Also, a process for the preparation of interference pigments that comprise SiO.sub.2 flakes coated with a crystallite of alpha-Fe.sub.2O.sub.3, by a wet-chemical process in a fluidised bed, by a CVD process, by a PVD process, or by any combination of said processes. Also, the use of interference pigments based on SiO.sub.2 flakes coated with crystallites of alpha-Fe.sub.2O.sub.3, in particular in paints, coatings, industrial and automobile paints, ceramic materials, plastics and cosmetic formulations.

An asymmetric pigment including a first Fabry-Perot structure; and a second Fabry-Perot structure; wherein the first Fabry-Perot structure and the second Fabry-Perot structure have a similar hue angle within +/45 degrees is disclosed. Other asymmetric pigments are also disclosed as well as methods of making the disclosed pigments.

An optical device includes a reflector layer; a selective light modulating layer external to the reflector layer; and functional molecules present in at least one of the selective light modulating layer, in a functional layer external to a surface of the selective light modulating layer, in the selective light modulating layer near an external surface, in the selective light modulating layer near the reflector layer, and in a functional layer external to the reflector layer. A method of making an optical device is also disclosed.

A composition including a dual cavity color shirting pigment and a single cavity color shifting pigment is disclosed. A method of making the composition is also disclosed.