This invention relates to fusion bonded epoxy rebar powder coating compositions of enough latency overtime, which cure in seconds upon residual heat up to 239.0° C., exhibiting low temperature flexibility to achieve crack-free rebar bending at −45° C. and a glossy finish without yellowing or discoloration. This invention further relates to rebar powder coatings compounded using suitable dihydrazide amines as the curing agent, in combination with an executive resin blend including a compatible toughening epoxy, and a synergic catalyst package to meet the intended application challenges.

Method for the preparation of moldings in a layer-by-layer process in which selectively areas of a powdered layer are melted, sintered, fused, or otherwise solidified, characterized in that as a powder for the powdered layer a thermoplastic, ground polyamide powder is used, in which the polyamide comprises laurolactam and caprolactam, preferably exclusively, and wherein the proportion of caprolactam is in the range of 40-60 mol % of the lactams used.

Useful thermoplastic polymer powders are formed by a method comprising: cooling a foam comprised of a thermoplastic foam below the brittleness temperature of the thermoplastic polymer, wherein the foam has an average strut dimension of 10 to 500 micrometers, and comminuting the cooled foam to form a thermoplastic polymer powder. The method allows for the efficient grinding of the thermoplastic polymer having improved morphology and desirable characteristics such as dry flow without flow aids.

In one instance a semicrystalline polyketone powder useful for additive manufacturing is comprised of a bimodal melt peak determined by an initial differential scanning calorimetry (DSC) scan at 20° C./min and a D.sub.90 particle size of at most 300 micrometers and average particle size of 1 micrometer to 150 micrometers equivalent spherical diameter. In another instance, A composition is comprised of a semicrystalline polyketone powder having a melt peak and a recrystallization peak, wherein the melt peak and recrystallization peak fail to overlap.

This application provides a coating film having excellent durability and wear resistance that, when applied to a mold surface, has excellent releasability (non-adhesiveness) over a long period of time, and a fluoropolymer coating composition that is able to form such a coating film. The fluoropolymer coating composition contains a fluoropolymer and a fluoro oil, where the decomposition temperature of the fluoro oil is higher than the melting point of the fluoropolymer.

A free-flowing dry mix of various chemical components can be applied in its dried form, as is contemplated by typical powder coating operations, as well as dispersed within a liquid carrier and applied in liquid form. When liquefied, this bifunctional composition retains similar viscosity to liquid coatings, while simultaneously avoiding any reaction with or degradation by the liquid carrier. The liquefied powder is preferable to existing liquid coatings because it avoids the use of any volatile organic compounds or other solvents, whereas the final, cured coating produced by these bifunctional compositions are indistinguishable regardless of whether they are applied in dry or liquefied form.

The present disclosure concerns a powder fastener retention material for application to metal sub-miniature fasteners formulated from a nylon 11 powder having a median average particle size by volume of more than 67 and less than 80 micrometers, a metal sub-miniature fastener having a patch of the reusable fastener retention material, a method for forming a patch of the fastener retention material on a metal sub-miniature fastener, a method of forming a reusable fastener retention patch on a region of a metal sub-miniature fastener, and a kit of parts comprising (a) a metal sub-miniature fastener, and (b) a powder retention material powder.

A method, composition, and article of manufacture. The method can include depositing a layer, which includes a set of particles and a set of microcapsules encapsulating polymerizing agents. The method can also include fusing particles in selected areas of the layer with a laser, and rupturing at least a portion of microcapsules using at least one energy source selected from the laser, an ultraviolet (UV) radiation source, and a heat source. The composition can include a set of particles and a set of microcapsules, each containing a polymerizing agent encapsulated by a degradable shell. The article of manufacture can include fused layers that include fused particles and pores sealed in reactions with polymerizing agents released from degradable microcapsules.

Powder coating compositions, particularly metal packaging powder coating compositions, coated metal substrates, and methods; wherein the powder coating compositions include powder polymer particles comprising a polymer having a number average molecular weight of at least 2000 Daltons, wherein the powder polymer particles have a particle size distribution having a D50 of less than 25 microns; and, in certain embodiments, one or more charge control agents in contact with the powder polymer particles.

A wear-resistant super-hydrophobic protective coating for a substrate includes a pretreated surface and a composite coating. The composite coating is formed of a mixture of a ZrO.sub.2 powder, a PTFE powder and a silicone powder by spraying. A method for preparing the protective coating on a substrate is also provided.