A process includes combining a copolymer and mono- or di-valent metal ions to form a mixture, wherein the copolymer has from about 70 to about 98 wt % of an alpha-olefin moiety and about 2 to about 30 wt % of a (meth)acrylate moiety; reactively extruding the mixture to form a neutralized copolymer having a melt flow index of from about 5 to about 1500 g/10 min, wherein about 2 to about 50 wt % of the (meth)acrylate moiety is neutralized to form a mono- or di-valent metal salt present in an amount of from about 0.2 to about 20% based on the total (meth)acrylic acid content of the copolymer; and grinding the neutralized copolymer to form the powder having a Dv50 particle size of from about 10 to about 600 μm as determined using ASTM D5861, wherein the process is free of utilizing a liquid and/or a slurry.

A layered tetravalent metal phosphate composition (e.g., a layered zirconium phosphate composition) and a first corrosion inhibitor (e.g., cerium (III), a vanadate, a molybdate, a tungstate, a manganous, a manganate, a permanganate, an aluminate, a phosphonate, a thiazole, a triazole, and/or an imidazole) is dispersed in an aqueous solution and stirred to form a first solution. A precipitate of the first solution is collected and washed to form a first corrosion inhibiting material (CIM), which includes the first corrosion inhibitor intercalated in the layered tetravalent metal phosphate composition. The first CIM is added to a first sol-gel composition to form a first CIM-containing sol-gel composition. The first CIM-containing sol-gel composition is applied on a substrate to form a CIM-containing sol-gel layer, cured by UV radiation, and thermally cured to form a corrosion-resistant coating. One or more additional sol-gel composition may be applied on the substrate.

The invention pertains to a graphene painting. The graphene painting comprises: a component A and a component B, the component A includes 40 to 50 parts by weight of epoxy resin, 6 to 10 parts by weight of acrylic resin, 15 to 20 parts by weight of zinc powder, 0.4 to 2 parts by weight of graphene, 2 to 5 parts by weight of dispersant, 0.5 to 4 parts by weight of coupling agent, 1 to 3 parts by weight of leveling agent, 6 to 10 parts by weight of filler, 9 to 14 parts by weight of synergist, 22 to 30 parts by weight of solvent; the component B includes 1 to 4 parts by weight of curing agent, 3 to 5 parts by weight of diluent. The graphene painting is coated on the surface of a magnet, which improves the corrosion resistance of the magnet and heat dissipation performance.

A preparation method for a corrosion-resistant coating of a reinforcing steel for marine concrete, comprising the steps: (1) pretreating the surface of a reinforcing steel; (2) preparing self-repairing corrosion microcapsules; (3) preparing a cathodic electrophoresis coating; (4) carrying out cathodic electrophoresis; and (5) curing. The electrophoresis coating of the present invention contains the self-repairing corrosion microcapsules, metal powder, and graphene oxide powder. The corrosion resistance of the coating is improved under the co-action of the self-repairing properties of the self-repairing microcapsules and cathodic protection. The corrosion-resistant coating has excellent adhesion and corrosion resistance, prolonging the service life of reinforcing steel. It is widely used for the protection of reinforcing steels for marine concrete, and also for the protection of metal structures in general environment.

The invention discloses a corrosion resistant coating for marine engineering concrete and a preparation method thereof, the corrosion resistant coating being sprayed or brushed on the concrete surface after being uniformly mixed by component A and component B,wherein the component A is calculated by weight including: waterborne non-ionic epoxy resin, C10-C12 alkyl glycidyl ether, polyhedral oligomeric silsesquioxane, metal powder, magnesium aluminum hydrotalcite powder,dispersant,defoamer; and the component B is calculated by weight including: modified aromatic amine curing agent, C10-C12 alkyl glycidyl ether, self-healing micro capsules, leveling agent, antioxidant, adhesion promoter, and other additives. The corrosion resistant coating of the present invention has excellent adhesion and corrosion resistance, while being able to achieve self-healing of the corrosion-resistant coating and prevent the migration of chloride ions, thereby prolonging the service life of the concrete structure, so that it can be widely used for the protection of marine engineering concrete structures.

Exemplary articles may comprise a surface alloyed layer, a base metal comprising a steel, and a transitional layer between the surfaced alloyed layer and the base metal. The surface alloyed layer may comprise nickel (Ni), chromium (Cr), manganese (Mn), molybdenum (Mo), silicon (Si), or combinations thereof. Exemplary methods of making an article may comprise coating a portion of a sand mold with a metal slurry, pouring a molten steel alloy onto the sand mold, and removing the article from the sand mold.

A tiecoat coating composition for use in a coating system for a metallic substrate comprising at least three coating layers is disclosed. The system has a primer coating layer which overlies the metallic substrate, a tiecoat coating layer which overlies the primer coating layer, and a finish coating layer which overlies the tiecoat coating layer. The primer coating layer is formed from a primer composition, the tiecoat coating layer is formed from a tiecoat composition, and the finish coating layer is formed from a finish composition. The primer composition comprises a primer carrier medium and a primer corrosion inhibitor in which the primer inhibitor has a galvanic cathodic mechanism. The finish composition is formulated to give a predetermined surface texture and appearance. The tiecoat composition comprises a tiecoat carrier medium and a tiecoat corrosion inhibitor. The tiecoat corrosion inhibitor has a barrier mechanism.

A corrosion-protecting layer system, e.g., for a bearing component used in a wind turbine, includes a base layer that contains polyurethane, zinc, and vinylphosphonic acid or silane. An intermediate layer is formed on the base layer and contains polyurethane and zinc. A top layer is formed on the intermediate layer and contains polyurethane and micaceous iron oxide. A sealing layer is formed on the top layer and contains polyurethane.

A curing agent composition and a curing agent coating formula thereof are provided. The curing agent composition includes 5 to 25 wt % of an ester group-containing amine end group adduct, 2 to 25 wt % of a C8-C22 hydrophobic saturated or unsaturated fatty amine, 2 to 25 wt % of a polyamine compound, 2 to 20 wt % of a silane compound, and 10 to 60 wt % of an ether solvent.

A curing agent composition and a curing agent coating formula thereof are provided. The curing agent composition includes 5 to 25 wt % of an ester group-containing amine end group adduct, 2 to 25 wt % of a C8-C22 hydrophobic saturated or unsaturated fatty amine, 2 to 25 wt % of a polyamine compound, 2 to 20 wt % of a silane compound, and 10 to 60 wt % of an ether solvent.