A process for anticorrosion treatment of a metallic surface, including bringing the surface into successive contact with the an alkaline or acidic cleaner composition, a first rinsing composition, optionally a second rinsing composition, an acidic conversion composition, optionally a third rinsing composition, and a composition including a (meth)acrylate- and/or epoxide-based cathodic electrophoretic coating. At least one of the compositions includes at least one compound of the formula R.sup.1O—(CH.sub.2).sub.x—Z—(CH.sub.2).sub.y—OR.sup.2. R.sup.1 and R.sup.2 are each, independently of one another, H or an HO—(CH.sub.2).sub.w— group with w≥2. X and y are each, independently of one another, from 1 to 4 and Z is an S atom or a C—C triple bond. An aqueous composition for reducing corrosive removal of material in anticorrosion treatment of metallic surfaces is disclosed.

A process for anticorrosion treatment of a metallic surface, including bringing the surface into successive contact with the an alkaline or acidic cleaner composition, a first rinsing composition, optionally a second rinsing composition, an acidic conversion composition, optionally a third rinsing composition, and a composition including a (meth)acrylate- and/or epoxide-based cathodic electrophoretic coating. At least one of the compositions includes at least one compound of the formula R.sup.1O—(CH.sub.2).sub.x—Z—(CH.sub.2).sub.y—OR.sup.2. R.sup.1 and R.sup.2 are each, independently of one another, H or an HO—(CH.sub.2).sub.w— group with w≥2. X and y are each, independently of one another, from 1 to 4 and Z is an S atom or a C—C triple bond. An aqueous composition for reducing corrosive removal of material in anticorrosion treatment of metallic surfaces is disclosed.

A multi-step method for anti-corrosion pretreatment of components made from metallic materials, in which a wet chemical treatment with an aqueous composition (A) containing a dissolved and/or dispersed polymer P, which is substituted with heterocycles containing at least one quaternary nitrogen heteroatom, is followed by a conversion treatment based on water-soluble compounds of the elements Zr, Ti, and/or Si before further anti-corrosion coatings are optionally applied.

A multi-step method for anti-corrosion pretreatment of components made from metallic materials, in which a wet chemical treatment with an aqueous composition (A) containing a dissolved and/or dispersed polymer P, which is substituted with heterocycles containing at least one quaternary nitrogen heteroatom, is followed by a conversion treatment based on water-soluble compounds of the elements Zr, Ti, and/or Si before further anti-corrosion coatings are optionally applied.

Disclosed is a system for treating a surface of a multi-metal article. The system includes first and second and/or third conversion compositions for contacting at least a portion of the surface. The first conversion composition includes phosphate ions and zinc ions and is substantially free of fluoride. The second conversion composition includes a lanthanide series metal cation and an oxidizing agent. The third conversion composition includes an organophosphate compound, an organophosphonate compound, or combinations thereof that optionally may include at least one transition metal. Methods of treating a multi-metal article using the system also are disclosed. Also disclosed are substrates treated with the system and method.

Disclosed is a system for treating a surface of a multi-metal article. The system includes first and second and/or third conversion compositions for contacting at least a portion of the surface. The first conversion composition includes phosphate ions and zinc ions and is substantially free of fluoride. The second conversion composition includes a lanthanide series metal cation and an oxidizing agent. The third conversion composition includes an organophosphate compound, an organophosphonate compound, or combinations thereof that optionally may include at least one transition metal. Methods of treating a multi-metal article using the system also are disclosed. Also disclosed are substrates treated with the system and method.

Described herein is a continuous coil pretreatment process used to treat the surface of an aluminum alloy sheet or coil for subsequent deposition of an acidic organophosphorus compound. The process can include applying a cleaner to a surface of an aluminum sheet or a coil; etching the surface of the aluminum sheet or the coil with an acidic solution; rinsing the surface of the aluminum sheet or the coil with deionized water; applying to the surface of the aluminum sheet or the coil a solution of an acidic organophosphorus compound; rinsing the surface of the aluminum sheet or the coil with deionized water; and drying the surface of the aluminum sheet or the coil.

Described herein is a continuous coil pretreatment process used to treat the surface of an aluminum alloy sheet or coil for subsequent deposition of an acidic organophosphorus compound. The process can include applying a cleaner to a surface of an aluminum sheet or a coil; etching the surface of the aluminum sheet or the coil with an acidic solution; rinsing the surface of the aluminum sheet or the coil with deionized water; applying to the surface of the aluminum sheet or the coil a solution of an acidic organophosphorus compound; rinsing the surface of the aluminum sheet or the coil with deionized water; and drying the surface of the aluminum sheet or the coil.

A coating composition includes a (A) binder component and a (B) pigment component. The (A) binder component includes (A1) polyvinyl butyrate, (A2) a particular film forming resin, (A3) an acid, (A4) an optional functionalized tri-alkoxy silane, and (A5) an optional polymeric phosphate ester. The (B) pigment component includes (B1) a calcium ion-exchanged silica, (B2) a corrosion inhibiting pigment, and (B3), a polyalkylene oxide phosphate. The coating composition is formed by combining the aforementioned components. In a method, the coating composition is applied to a substrate.

A coating composition includes a (A) binder component and a (B) pigment component. The (A) binder component includes (A1) polyvinyl butyrate, (A2) a particular film forming resin, (A3) an acid, (A4) an optional functionalized tri-alkoxy silane, and (A5) an optional polymeric phosphate ester. The (B) pigment component includes (B1) a calcium ion-exchanged silica, (B2) a corrosion inhibiting pigment, and (B3), a polyalkylene oxide phosphate. The coating composition is formed by combining the aforementioned components. In a method, the coating composition is applied to a substrate.