A coating dispersion or building article can include titanium dioxide, and a dihydrazide. The coating dispersion or building article can further include calcium carbonate, calcined aluminum silicate, acrylic polymers, and a fluoroalkyl polymer.

A paint composition for forming energy saving self-cleaning coatings includes water, a binder composition, a powder catalyst composition, a first pigment composition, a second pigment composition, and a fluoropolymer-composition. The binder composition includes a first acrylic resin having an average particle size from about 0.2 to 1 micron and a glass transition temperature less than about 10 C. The powder catalyst composition includes anatase titanium dioxide with a surface area from about 50 to 500 m.sup.2/g. It should be appreciated that anatase provides catalyst activity that is useful for providing the self-cleaning properties of the present embodiment. The first pigment composition includes rutile titanium dioxide which typically has low or no catalytic activity while the second pigment composition is different than the first pigment composition. Characteristically, the fluoropolymer-containing composition includes polyvinylidene fluoride and a second acrylic resin.

A coating dispersion or building article can include titanium dioxide, and a dihydrazide. The coating dispersion or building article can further include calcium carbonate, calcined aluminum silicate, acrylic polymers, and a fluoroalkyl polymer.

Coating a metallic surface with at least one of a pretreatment composition prior to organic coating, with a passivation composition without intent for subsequent organic coating, with a pretreatment primer composition, with a primer composition, with a paint composition and with an electrocoating composition, wherein the coating composition includes particles on a base of at least one layered double hydroxide (LDH) phase characterized by the general formula [M.sup.2+.sub.(10.5)x(M.sup.3+, M.sup.4+).sub.x(OH).sub.20.75]A.sup.n.sub.x/n.mH.sub.2O.

A fluorine-containing boric acid PVB composite comprising a condensate of a fluorine-containing alcohol, boric acid and polyvinyl butyral, wherein the fluorine-containing alcohol is represented by the general formula:

Rf(A-OH).sub.k

wherein k is 1 or 2; when k is 1, Rf is a perfluoroalkyl group having 6 or less carbon atoms, a polyfluoroalkyl group in which some of the fluorine atom or atoms of the perfluoroalkyl group are replaced by hydrogen atom or atoms, a polyfluoroalkyl group containing a terminal perfluoroalkyl group having 6 or less carbon atoms and a perfluoroalkylene group having 6 or less carbon atoms, or a linear or branched, perfluoroalkyl group containing a terminal perfluoroalkyl group having 6 or less carbon atoms, a perfluoroalkylene group having 6 or less carbon atoms and ether bonds; when k is 2, Rf is a linear or branched, perfluoroalkylene group or polyfluoroalkylene group, containing a perfluoroalkylene group having 6 or less carbon atoms and ether bonds; and A is an alkylene group having 1 to 6 carbon atoms.

Marine coatings including cationic polymers hydrolyzable to nonfouling zwitterionic polymers, coated marine surfaces, and methods for making and using the marine coatings.

According to one or more embodiments, an antifouling material may be produced by forming a nanostructured mold, where a liquid mold precursor is contacted with a textured surface of a nanostructured template, the liquid mold precursor is solidified to the nanostructured template, and the formed nanostructured mold is removed from the nanostructured template. The antifouling material may be formed by contacting a liquid precursor mixture with a textured surface of the nanostructured mold, solidifying the liquid precursor mixture onto the nanostructured mold, and removing the formed antifouling material from the nanostructured mold. The antifouling material may include a nanostructured surface and may further include a toxin.

An antimicrobial formulation that can be directly added into a composition or onto a surface of a composition (e.g., forming a surface coating on a composition or device). The antimicrobial formulation includes sodium pentaborate, di-sodium tetraborate decahydrate, titanium diborite, titanium borate, sodium pyrithione, zinc pyrithione, benzhetonium chloride, or any combination thereof.

The present application discloses a fouling control coating composition comprising a polysiloxane-based binder system, 0.01-20% by dry weight of one or more hydrophilic-modified polysiloxanes, and one or more biocides. The hydrophilic-modified polysiloxane may be a poly(oxyalkylene)-modified polysiloxane, e.g. a polysiloxane having grafted thereto poly(oxyalkylene) chains and/or having incorporated in the backbone thereof poly(oxyalkylene) chains. The poly(oxyalkylene) may e.g. be selected from polyoxyethylene, polyoxypropylene and poly(oxyethylene-co-oxypropylene) (polyethylene glycols/polypropylene glycols). The application further discloses a marine structure comprising on at least a part of the outer surface thereof an outermost coating prepared from the coating composition. Moreover, the application discloses the use of the combination of non-reactive hydrophilic-modified polysiloxanes and biocides, wherein the weight ratio between the hydrophilic-modified polysiloxanes and the biocides is in the range 1:0.2 to 1:6, for improving the antifouling properties of a polysiloxane based coating composition.

Marine coatings including cationic polymers hydrolyzable to nonfouling zwitterionic polymers, coated marine surfaces, and methods for making and using the marine coatings.