The present invention is directed towards an electrodepositable coating composition comprising (a) a fluoropolymer; (b) an electrochemically active material and/or electrically conductive agent; (c) a pH-dependent rheology modifier; and (d) an aqueous medium comprising water; wherein water is present in an amount of at least 45% by weight, based on the total weight of the electrodepositable coating composition. Also disclosed herein is a method of coating a substrate, as well as coated substrates and electrical storage devices.

Provided a nano/micro composite fiber of the present invention, capable of storing electrical energy, comprising (a) one or more pairs of microfiber bundles consisting of graphene or graphene/carbon nanotube as an electrode active material; (b) nanofiber web surrounding the microfiber bundles, wherein the nanofiber web is coated by one or more materials selected from the group consisting of metal, carbon nanotube, activated carbon and metal oxide nanoparticle; (c) an electrolyte layer surrounding the nanofiber web and filling inner void of the microfibers and nanofiber web; (d) an insulating film sheathing the electrolyte layer.

The electrodeposition dispersion of the present invention is an electrodeposition dispersion for electrodepositing an electrodeposited film on a conductive base material, the solution including water, a dispersion medium, and a solid component, in which the solid component includes a polyimide-based resin and a fluorine-based resin, the fluorine-based resin content included in the solid component is in a range of 72 mass % or more and 95 mass % or less, an average particle diameter of the solid component dispersed in the water and the dispersion medium is 50 nm or more and 500 nm or less, and a standard deviation of the particle diameter of the solid component is 250 nm or less.

Provided is a fluororesin-containing electrodeposition coating composition which, although being an electrodeposition coating material, has sufficient storage stability. The electrodeposition coating composition comprises: a fluorocopolymer comprising perhaloolefin units, units of a monomer represented by the following general formula (1), units of a carboxylated vinyl monomer, and units of a hydroxylated vinyl monomer; and an acrylic polymer. In the following general formula (1), R is preferably a C.sub.9 or higher hydrocarbon group.

CH.sub.2CHOCOR(1)

(In the formula, R is a C.sub.6 or higher hydrocarbon group.)

Disclosed herein are an aqueous dispersion including cationic polyvinyl alcohol modified polymer particles, an aqueous electrocoating material containing the dispersion and a process to produce an at least partially coated substrate using the aqueous electrocoating material. The aqueous dispersion can be prepared by reacting an intermediate including at least one polyvinyl alcohol polymer chain with a compound including at least one epoxide group and a least two blocked primary amino groups. Aqueous coating compositions including the aqueous dispersion result in improved leveling properties during film formation as well as an improved edge protection of the substrate without negatively influencing the surface roughness and adhesion as well as the deposition properties.

The invention relates to a method for grafting an organic film onto an electrically conductive or semiconductive surface by electro-reduction of a solution, wherein the solution comprises one diazonium salt and one monomer bearing at least one chain polymerizable functional group. During the electrolyzing process, at least one protocole consisting of an electrical polarization of the surface by applying a variable potential over at least a range of values which are more cathodic that the reduction or peak potential of all diazonium salts in said solution is applied. The invention also relates to an electrically conducting or semiconducting surface obtained by implementing this method.

The invention further relates to electrolytic compositions.

Disclosed is a sealing composition for treating a metal substrate comprising: a polyolefin component; and a colloidal layered silicate. Also disclosed is a system for treating a metal substrate comprising: a cleaner composition; and/or a pretreatment composition for treating at least a portion of the substrate, the pretreatment composition comprising a Group IVB metal; and a sealing composition for treating at least a portion of the substrate treated with the cleaner composition and/or the pretreated composition, the sealing composition comprising a polyolefin component. Also disclosed is a method of treating a substrate comprising contacting at least a portion of a surface of the substrate with any of the compositions disclosed herein or any of the systems disclosed herein. Also disclosed is a method of treating a substrate comprising passing electric current between a cathode and the substrate, serving as an anode, said cathode and anode being immersed in a sealing composition comprising a polyolefin component. Also disclosed is a substrate comprising a surface treated with any of the compositions disclosed herein, any of the systems disclosed herein, or any of the methods disclosed herein.

A method for high rate assembly of nanoelements into two-dimensional void patterns on a non-conductive substrate surface utilizes an applied electric field to stabilize against forces resulting from pulling the substrate through the surface of a nanoelement suspension. The electric field contours emanating from a conductive layer in the substrate, covered by an insulating layer, are modified by a patterned photoresist layer, resulting in an increased driving force for nanoelements to migrate from a liquid suspension to voids on a patterned substrate having a non-conductive surface. The method can be used for the production of microscale and nanoscale circuits, sensors, and other electronic devices.

Electrodepositable coating compositions containing 1,1-di-activated vinyl compounds are described. The coating compositions produce cured coating layers that exhibit resistance to cratering. The coating compositions can be used in electrodepositable coating composition formulations.

A method for high rate assembly of nanoelements into two-dimensional void patterns on a non-conductive substrate surface utilizes an applied electric field to stabilize against forces resulting from pulling the substrate through the surface of a nanoelement suspension. The electric field contours emanating from a conductive layer in the substrate, covered by an insulating layer, are modified by a patterned photoresist layer, resulting in an increased driving force for nanoelements to migrate from a liquid suspension to voids on a patterned substrate having a non-conductive surface. The method can be used for the production of microscale and nanoscale circuits, sensors, and other electronic devices.