The present invention provides an aqueous paint composition comprising by dry weight based on total dry weight of the pigment composition, from 11% to 35% of a polymeric duller of (co)polymeric particles having an average diameter of from 1 to 20 μm, and from 25% to 70% of titanium dioxide particles; wherein from 50% to 100% of the titanium dioxide particles are encapsulated by polymer shell of (co)polymeric particles.

The present invention provides a coating agent for leather, the coating agent containing: in terms of solid content ratio, (I) an aqueous urethane resin; (II) a matting agent; and (III) a silicone acryl graft copolymer resin emulsion in which the weight ratio of a polyorganosiloxane represented by a specified formula relative to acrylic ester units or methacrylic ester units is 50:50 to 90:10, and a leather on which a coating by the coating agent for leather is formed. This coating agent for leather has exceptional wear resistance and anti-fouling properties, and a leather on which a coating by the coating agent is formed can maintain a high-quality external appearance and high wear resistance.

The present invention provides a coating agent for leather, the coating agent containing: in terms of solid content ratio, (I) an aqueous urethane resin; (II) a matting agent; and (III) a silicone acryl graft copolymer resin emulsion in which the weight ratio of a polyorganosiloxane represented by a specified formula relative to acrylic ester units or methacrylic ester units is 50:50 to 90:10, and a leather on which a coating by the coating agent for leather is formed. This coating agent for leather has exceptional wear resistance and anti-fouling properties, and a leather on which a coating by the coating agent is formed can maintain a high-quality external appearance and high wear resistance.

There are provided a decorative sheet having excellent contamination resistance/tape resistance while maintaining high flaw resistance and a decorative plate. The decorative sheet includes: a base material; a matte layer formed on one surface of the base material; and a surface protective layer formed on the surface on the side of the matte layer of the base material, in which the matte layer and the surface protective layer are formed of an ultraviolet curable resin and the matte layer contains a spherical filler.

There are provided a decorative sheet having excellent contamination resistance/tape resistance while maintaining high flaw resistance and a decorative plate. The decorative sheet includes: a base material; a matte layer formed on one surface of the base material; and a surface protective layer formed on the surface on the side of the matte layer of the base material, in which the matte layer and the surface protective layer are formed of an ultraviolet curable resin and the matte layer contains a spherical filler.

Provided is a silica that exhibits a high matting property when utilized as a matting agent for a paint, and can also suppress the occurrence of cloudiness. The silica has an aggregated structure in which primary particles are aggregated, has a particle diameter ratio R represented by the following equation (1) of from 4.3 to 5.2, has an absorbance of 0.6 or less for light having a wavelength of 700 nm as an aqueous dispersion having a concentration of 1.48 mass %, and has a particle density measured with a He pycnometer of 2.18 g/cm.sup.3 or more: Equation (1) R=.sup.LD50/.sup.CD50 (in the equation (1), .sup.LD50 represents a volume-based 50% cumulative particle diameter (μm) of the silica measured based on a laser diffraction/scattering method, and .sup.CD50 represents a volume-based 50% cumulative particle diameter (μm) of the silica measured based on a Coulter counter method).

Provided is a silica that exhibits a high matting property when utilized as a matting agent for a paint, and can also suppress the occurrence of cloudiness. The silica has an aggregated structure in which primary particles are aggregated, has a particle diameter ratio R represented by the following equation (1) of from 4.3 to 5.2, has an absorbance of 0.6 or less for light having a wavelength of 700 nm as an aqueous dispersion having a concentration of 1.48 mass %, and has a particle density measured with a He pycnometer of 2.18 g/cm.sup.3 or more: Equation (1) R=.sup.LD50/.sup.CD50 (in the equation (1), .sup.LD50 represents a volume-based 50% cumulative particle diameter (μm) of the silica measured based on a laser diffraction/scattering method, and .sup.CD50 represents a volume-based 50% cumulative particle diameter (μm) of the silica measured based on a Coulter counter method).

The present disclosure relates to a matting agent including emulsion polymer particles, a matting polymer composition including a matting agent, and a method of producing emulsion polymer particles. The emulsion polymer particles may be produced by a simple process using an emulsion polymerization method, and have the advantage of being relatively easy to control a degree of crosslinking. In addition, in a case where a matting polymer composition is prepared using a matting agent including the emulsion polymer particles, it is possible to manufacture a molded article having excellent appearance and matting effect without deterioration of the existing mechanical properties such as impact strength and tensile strength of a thermoplastic polymer, and in particular, an excellent matting effect may be exerted even in the extrusion processing, which has been difficult to achieve in the related art.

The present disclosure relates to a matting agent including emulsion polymer particles, a matting polymer composition including a matting agent, and a method of producing emulsion polymer particles. The emulsion polymer particles may be produced by a simple process using an emulsion polymerization method, and have the advantage of being relatively easy to control a degree of crosslinking. In addition, in a case where a matting polymer composition is prepared using a matting agent including the emulsion polymer particles, it is possible to manufacture a molded article having excellent appearance and matting effect without deterioration of the existing mechanical properties such as impact strength and tensile strength of a thermoplastic polymer, and in particular, an excellent matting effect may be exerted even in the extrusion processing, which has been difficult to achieve in the related art.

The present disclosure relates to a matting agent including polymer particles, a matting polymer composition including a matting agent, and a method of producing polymer particles. The polymer particles may be produced by a simple process using a suspension polymerization method, and is relatively easy to control a degree of crosslinking. In addition, in a case where a matting polymer composition is prepared using a matting agent including the polymer particles, it is possible to manufacture a molded article having excellent appearance and matting effect without deterioration of the existing mechanical properties such as impact strength and tensile strength of a thermoplastic polymer, and in particular, an excellent matting effect may be exerted even in the extrusion processing, which has been difficult to achieve in the related art.