Devices, systems, and methods are directed to binder jetting for forming three-dimensional parts having controlled, macroscopically inhomogeneous material composition. In general, a binder may be delivered to each layer of a plurality of layers of a powder of inorganic particles. An active component may be introduced, in a spatially controlled distribution, to at least one of the plurality of layers such that the binder, the powder of inorganic particles, and the active component, in combination, form an object. The object may be thermally processed into a three-dimensional part having a gradient of one or more physicochemical properties of a material at least partially formed from thermally processing the inorganic particles and the active component of the object.

Hydrogel three-dimensional printing kits, methods of three-dimensional printing and three-dimensional printed hydro-gels are described. In one example, a three-dimensional printing kit can comprise a particulate build material, a crosslinking agent and a structural modifier. The particulate build material may comprise a polyhydroxylated polymer having hydroxyl groups. The crosslinking gent is for crosslinking the polyhydroxylated polymer by a reaction with the hydroxyl groups. The structural modifier can have a plurality of functional groups for forming a network within the hydrogel, and where the structural modifier may have a reactivity that is chemically orthogonal to the reaction with the hydroxyl groups for crosslinking the polyhydroxylated polymer.

Hydrogel three-dimensional printing kits, methods of three-dimensional printing and three-dimensional printed hydro-gels are described. In one example, a three-dimensional printing kit can comprise a particulate build material, a crosslinking agent and a structural modifier. The particulate build material may comprise a polyhydroxylated polymer having hydroxyl groups. The crosslinking gent is for crosslinking the polyhydroxylated polymer by a reaction with the hydroxyl groups. The structural modifier can have a plurality of functional groups for forming a network within the hydrogel, and where the structural modifier may have a reactivity that is chemically orthogonal to the reaction with the hydroxyl groups for crosslinking the polyhydroxylated polymer.

A sol-gel material for overcoating a surface-relief structure includes a titanium(IV) precursor, and a titanium oxide stabilizer including R.sup.3OC(O)OR.sup.4, R.sup.5C(O)OR.sup.6, or a combination. R.sup.3 and R.sup.4 include alkyl or alkene groups optionally containing carboxylate, alcohol, or ester functionalities, such as propylene carbonate (PC). R.sup.5 and R.sup.6 include alkyl or alkene groups optionally containing carboxylate, alcohol, or ester functionalities, for example, a lactone such as gamma butyrolactone (GBL). In some embodiments, the sol-gel material includes a source of sulfate or phosphate anions, an acid, a base, a peroxide, a surfactant, a cross-linker, a flexibilizer, a toughener additive, a solvent, or a combination thereof. In some embodiments, the sol-gel material is annealed at a temperature between 50-150° C., and then annealed at a temperature between 200-300° C. In some embodiments, the sol-gel material is cured using ultraviolet light before annealing at a temperature between 200-300° C.

A sol-gel material for overcoating a surface-relief structure includes a titanium(IV) precursor, and a titanium oxide stabilizer including R.sup.3OC(O)OR.sup.4, R.sup.5C(O)OR.sup.6, or a combination. R.sup.3 and R.sup.4 include alkyl or alkene groups optionally containing carboxylate, alcohol, or ester functionalities, such as propylene carbonate (PC). R.sup.5 and R.sup.6 include alkyl or alkene groups optionally containing carboxylate, alcohol, or ester functionalities, for example, a lactone such as gamma butyrolactone (GBL). In some embodiments, the sol-gel material includes a source of sulfate or phosphate anions, an acid, a base, a peroxide, a surfactant, a cross-linker, a flexibilizer, a toughener additive, a solvent, or a combination thereof. In some embodiments, the sol-gel material is annealed at a temperature between 50-150° C., and then annealed at a temperature between 200-300° C. In some embodiments, the sol-gel material is cured using ultraviolet light before annealing at a temperature between 200-300° C.

A chemical indicator strip for detecting disinfectant that includes a film substrate, and an indicator portion with a first and a second ink. The first and the second ink can react in the presence of a threshold level of disinfectant for a threshold level of exposure time. The chemical indicator strip can be used in a method of detecting a threshold level of disinfectant. The method can include exposing a chemical indicator strip to a concentration of disinfectant for a preset amount of time. The method can include providing a visual indicator to a user that changes from a first color to a second color. The method can indicate that the chemical indicator strip has been exposed to a threshold concentration of disinfectant for a threshold amount of time when a complete color change occurs on the chemical indicator strip from the first color to the second color.

A chemical indicator strip for detecting disinfectant that includes a film substrate, and an indicator portion with a first and a second ink. The first and the second ink can react in the presence of a threshold level of disinfectant for a threshold level of exposure time. The chemical indicator strip can be used in a method of detecting a threshold level of disinfectant. The method can include exposing a chemical indicator strip to a concentration of disinfectant for a preset amount of time. The method can include providing a visual indicator to a user that changes from a first color to a second color. The method can indicate that the chemical indicator strip has been exposed to a threshold concentration of disinfectant for a threshold amount of time when a complete color change occurs on the chemical indicator strip from the first color to the second color.

The present invention relates to an aqueous gravure ink containing a pigment, a polymer, a water-soluble organic solvent, a surfactant and water, in which the water-soluble organic solvent contains a glycol ether having a boiling point of from 100 to 260° C., and a content of the glycol ether in the ink is from 1 to 10% by mass; a total content of the water-soluble organic solvent in the ink is not more than 15% by mass; the surfactant contains an acetylene glycol-based surfactant; and a content of water in the ink is from 50 to 70% by mass.

The present invention relates to an aqueous gravure ink containing a pigment, a polymer, a water-soluble organic solvent, a surfactant and water, in which the water-soluble organic solvent contains a glycol ether having a boiling point of from 100 to 260° C., and a content of the glycol ether in the ink is from 1 to 10% by mass; a total content of the water-soluble organic solvent in the ink is not more than 15% by mass; the surfactant contains an acetylene glycol-based surfactant; and a content of water in the ink is from 50 to 70% by mass.

A cleaning liquid includes water, a surfactant, and glycol ether. The surfactant is an acetylene surfactant or a silicone surfactant. A content ratio of the glycol ether is at least 5% by mass and no greater than 15% by mass relative to a mass of the cleaning liquid. Preferably, a contact angle of the cleaning liquid to an austenitic stainless steel plate is no greater than 40 degrees.