The present invention refers to compositions comprising recombinant biopolymers made of combinations of monomers of the type “Elastin-like recombinamers” (ELR), monomers comprising the “silk” sequence and/or monomers comprising the HLF sequence that belongs to a natural class of proteins named zippers. Said compositions are useful as bio-ink for 3D printing. Furthermore, the present invention also refers to methods for obtaining the composition of the invention, as well as the 3D biomaterial and to the different uses of the composition and the obtained biomaterial.

A method of bioprinting a bioink printed structure and a bioprinted composition resulting from this method is provided. Biological cells are mixed with biomaterial inks. These biomaterial inks have a biopolymer backbone with grafted thereto a first bio-orthogonal chemical group. The mixed biological cells and biomaterial inks are extruded into a support bath. The next step is diffusing crosslinking molecules which have a second (complementary to the first) bio-orthogonal chemical group, in the support bath, whereby the diffusing crosslinking molecules react via bioorthogonal click-chemistry between the first and second bio-orthogonal chemical groups resulting in covalently crosslinking the biomaterial ink into a printed structure. Embodiments of this invention can be directed towards personalized medicine and printed tissue engineering constructs, as well as drug discovery by printing complex tissue mimics or printing model vasculature for studying cardiovascular disease.

A method of bioprinting a bioink printed structure and a bioprinted composition resulting from this method is provided. Biological cells are mixed with biomaterial inks. These biomaterial inks have a biopolymer backbone with grafted thereto a first bio-orthogonal chemical group. The mixed biological cells and biomaterial inks are extruded into a support bath. The next step is diffusing crosslinking molecules which have a second (complementary to the first) bio-orthogonal chemical group, in the support bath, whereby the diffusing crosslinking molecules react via bioorthogonal click-chemistry between the first and second bio-orthogonal chemical groups resulting in covalently crosslinking the biomaterial ink into a printed structure. Embodiments of this invention can be directed towards personalized medicine and printed tissue engineering constructs, as well as drug discovery by printing complex tissue mimics or printing model vasculature for studying cardiovascular disease.

The present invention relates to radiation curable coating composition (I) consisting essentially of: —from 20 to 95 wt % of one or more (meth)acrylated compounds (a), from 5 to 80 wt % of one or more metal salts of a C10 to C22 fatty acid (b), and—optionally, from 0 to 10 wt % of one or more additives (c), wherein the wt % of compounds (a) to (c) add up to at least 95%, preferably add up to 100%. Compositions of the invention are compatible with a whole range of radiation curable materials and with the standard additives like the standard matting agents. Compositions of the invention permit to obtain a dead matt effect using lower amounts of matting agents like silica and/or waxes. Dead matt effects can be obtained over a wide range of coating thicknesses.

The present invention relates to radiation curable coating composition (I) consisting essentially of: —from 20 to 95 wt % of one or more (meth)acrylated compounds (a), from 5 to 80 wt % of one or more metal salts of a C10 to C22 fatty acid (b), and—optionally, from 0 to 10 wt % of one or more additives (c), wherein the wt % of compounds (a) to (c) add up to at least 95%, preferably add up to 100%. Compositions of the invention are compatible with a whole range of radiation curable materials and with the standard additives like the standard matting agents. Compositions of the invention permit to obtain a dead matt effect using lower amounts of matting agents like silica and/or waxes. Dead matt effects can be obtained over a wide range of coating thicknesses.

An ink jet ink composition contains at least one disperse dye, a silicone surfactant, and water. The disperse dye content is 1.0% by mass or more and 3.0% by mass or less. When 1.0 part by mass of the silicone surfactant and 99.0 parts by mass of a 10% by mass aqueous solution of propylene glycol are mixed to give a mixture, the mixture has a cloud point of 60° C. or above.

Rhamnolipids and/or sophorolipids can be used in coating compositions for improvement of the speed of wetting of pulverulent formulation constituents in such compositions, which leads to a reduction in dust nuisance during incorporation thereof and to the increase in occupational safety in the production of coating compositions. Rhamnolipids and/or sophorolipids can also be used in coating compositions for obtaining improved homogeneous colour appearance of the dry paint film with regard to difference in hue, ascertained from the delta E and visual assessment.

The present invention provides water-based ink and coating compositions having a high renewable resin content. The ink and coating compositions of the invention comprise equal to or greater than 65% (w/w) renewable resins, based on the total combined weight of the resins. Renewable resins derived from gum rosins are preferred. The ink and coating compositions of the present invention exhibit physical properties (e.g. adhesion and resistance) that are as good as, or better than, current commercially available inks (e.g. acrylic based inks not containing renewable material).

The present invention provides water-based ink and coating compositions having a high renewable resin content. The ink and coating compositions of the invention comprise equal to or greater than 65% (w/w) renewable resins, based on the total combined weight of the resins. Renewable resins derived from gum rosins are preferred. The ink and coating compositions of the present invention exhibit physical properties (e.g. adhesion and resistance) that are as good as, or better than, current commercially available inks (e.g. acrylic based inks not containing renewable material).

To provide an active energy ray-curable ink composition that increase the content of raw materials derived from biomass and contains a material having superior pigment dispersibility, such as a rosin-modified phenol resin. An active energy ray-curable ink composition containing a compound having one or more ethylenically unsaturated bonds, a specific resin, and a specific liquid ingredient is provided, wherein the specific resin is at least one selected from the group consisting of rosin-modified phenol resins, rosin-modified maleic acid resins, rosin-modified alkyd resins, gilsonite resins, and asphalt resins, and the specific liquid ingredient is fat and oil that is derived from animals or vegetables or a modified product thereof having no ethylenically unsaturated bonds and a solubility parameter value (hereinafter referred to as sp value) of 9.0 (cal/cm.sup.3).sup.1/2 to less than 11.0 (cal/cm.sup.3).sup.1/2 as measured by turbidimetric titration.