A material web is disclosed. The material web includes a fiber layer having a first side and an opposing second side. The fiber layer has a plurality of fibers, each of which having an intimate admixture of a thermoplastic polymer, and a wax and/or oil, wherein at least some of the wax and/or oil is exposed at an outer surface of the fibers. A surface energy treatment is disposed on the first side and/or the second side of the fiber layer.

A material web is disclosed. The material web includes a fiber layer having a first side and an opposing second side. The fiber layer has a plurality of fibers, each of which having an intimate admixture of a thermoplastic polymer, and a wax and/or oil, wherein at least some of the wax and/or oil is exposed at an outer surface of the fibers. A surface energy treatment is disposed on the first side and/or the second side of the fiber layer.

Provided herein are back sheets comprising and/or otherwise made from thermoplastic vulcanizates, PV modules comprising such TPV-based back sheets, and methods for forming the TPV back sheets and PV modules. TPV-based back sheets provide particular advantages over incumbent back sheets, including increased flexibility, greater electrical insulation properties, and more desirable barrier properties. The TPV-based back sheets of some embodiments provide PV modules improved endurance, particularly under the changing and often harsh environmental conditions in which PV modules are often deployed. The TPV-based back sheets of some embodiments also enable efficient construction of unusual PV module geometries, such as non-planar (e.g., curved and/or hinged) geometries.

Provided herein are back sheets comprising and/or otherwise made from thermoplastic vulcanizates, PV modules comprising such TPV-based back sheets, and methods for forming the TPV back sheets and PV modules. TPV-based back sheets provide particular advantages over incumbent back sheets, including increased flexibility, greater electrical insulation properties, and more desirable barrier properties. The TPV-based back sheets of some embodiments provide PV modules improved endurance, particularly under the changing and often harsh environmental conditions in which PV modules are often deployed. The TPV-based back sheets of some embodiments also enable efficient construction of unusual PV module geometries, such as non-planar (e.g., curved and/or hinged) geometries.

The present invention provides aqueous polyolefin dispersion compositions for use in metal coatings, such as can coatings, comprising one or more polyolefin base polymer, one or more at least partially neutralized olefinic stabilizing agent having an acid number (AN) of from 80 to 250, preferably, a polyolefin stabilizing agent, such as an olefin-carboxylic acid copolymer or a blend of two such polymers, an optional coupling agent having an acid number (AN) of from 10 to 70 and a melt index of from 500 to 5,000,000 grams of polymer melt passing in 10 minutes through a heated syringe or cylinder at 190 C. with a plunger loaded with 2.16 kg, preferably, a polymer, and a hindered phenolic antioxidant containing an ester linkage dispersed in the polyolefin dispersion composition. The hindered phenolic antioxidant containing an ester linkage can be masterbatched with a polyolefin base polymer, polyolefin stabilizing agent or a coupling agent which is a polymer, melt mixed with the remaining polyolefin composition and then dispersed with aqueous media and a neutralizing agent to form the aqueous dispersion.

The present invention provides aqueous polyolefin dispersion compositions for use in metal coatings, such as can coatings, comprising one or more polyolefin base polymer, one or more at least partially neutralized olefinic stabilizing agent having an acid number (AN) of from 80 to 250, preferably, a polyolefin stabilizing agent, such as an olefin-carboxylic acid copolymer or a blend of two such polymers, an optional coupling agent having an acid number (AN) of from 10 to 70 and a melt index of from 500 to 5,000,000 grams of polymer melt passing in 10 minutes through a heated syringe or cylinder at 190 C. with a plunger loaded with 2.16 kg, preferably, a polymer, and a hindered phenolic antioxidant containing an ester linkage dispersed in the polyolefin dispersion composition. The hindered phenolic antioxidant containing an ester linkage can be masterbatched with a polyolefin base polymer, polyolefin stabilizing agent or a coupling agent which is a polymer, melt mixed with the remaining polyolefin composition and then dispersed with aqueous media and a neutralizing agent to form the aqueous dispersion.

The present invention provides aqueous polyolefin dispersion compositions for use in metal coatings, such as can coatings, comprising one or more polyolefin base polymer, one or more at least partially neutralized olefinic stabilizing agent having an acid number (AN) of from 80 to 250, preferably, a polyolefin stabilizing agent, such as an olefin-carboxylic acid copolymer or a blend of two such polymers, an optional coupling agent having an acid number (AN) of from 10 to 70 and a melt index of from 500 to 5,000,000 grams of polymer melt passing in 10 minutes through a heated syringe or cylinder at 190 C. with a plunger loaded with 2.16 kg, preferably, a polymer, and a hindered phenolic antioxidant containing an ester linkage dispersed in the polyolefin dispersion composition. The hindered phenolic antioxidant containing an ester linkage can be masterbatched with a polyolefin base polymer, polyolefin stabilizing agent or a coupling agent which is a polymer, melt mixed with the remaining polyolefin composition and then dispersed with aqueous media and a neutralizing agent to form the aqueous dispersion.

A method of making a coating applied to an article is provided. The method includes preparing at least one substrate on the article to be coated, to obtain at least one prepared substrate. The method further includes preparing the coating, obtained by disposing a plurality of high density metal pellets in an adhesive material, to form a metal adhesive matrix, and adding a polymer material over the metal adhesive matrix. The plurality of high density metal pellets is in an amount of at least 90% (ninety percent) by weight of the total weight percent of the coating. The method further includes applying the coating to the prepared substrate, to obtain a mass-enhanced, coated article. The coating thickness and the amount of high density metal pellets are sufficient to provide an attenuation of vibration of the coated article and a reduced risk of unwanted ergonomic effects.

This invention describes the manufacture of partially cured binder compositions based upon modification of drying oils with at least one multi-functional co-vulcanizing agent. The partially cured binder compositions can be blended with polymeric materials to prepare polymer blends. These polymer blends can be used to produce products such as cured solid layers. Methods of manufacturing the partially cured binder compositions and cured solid layers are described.

This invention describes the manufacture of partially cured binder compositions based upon modification of drying oils with at least one multi-functional co-vulcanizing agent. The partially cured binder compositions can be blended with polymeric materials to prepare polymer blends. These polymer blends can be used to produce products such as cured solid layers. Methods of manufacturing the partially cured binder compositions and cured solid layers are described.