An object of the present invention is to provide a coating agent giving a coating film that has good adhesion and stability over time, a decorative film having at least one layer formed from the coating agent; and an article decorated with the decorative film. The coating agent of the present invention contains, in a specific ratio, an olefin polymer (A) having a heat of fusion of in the range of 0 to 50 J/g and having a weight average molecular weight (Mw) as measured by GPC of 1×10.sup.4 to 1000×10.sup.4, a hydrocarbon-based synthetic oil (B) having a 40° C. kinematic viscosity of 30 to 500,000 cSt, and a tackifier (C) having an acid value of 10 or more and having a weight average molecular weight (Mw) of 0.9×10.sup.3 to 3×10.sup.3.

An object of the present invention is to provide a coating agent giving a coating film that has good adhesion and stability over time, a decorative film having at least one layer formed from the coating agent; and an article decorated with the decorative film. The coating agent of the present invention contains, in a specific ratio, an olefin polymer (A) having a heat of fusion of in the range of 0 to 50 J/g and having a weight average molecular weight (Mw) as measured by GPC of 1×10.sup.4 to 1000×10.sup.4, a hydrocarbon-based synthetic oil (B) having a 40° C. kinematic viscosity of 30 to 500,000 cSt, and a tackifier (C) having an acid value of 10 or more and having a weight average molecular weight (Mw) of 0.9×10.sup.3 to 3×10.sup.3.

Base coats and methods of producing the same are provided. In an exemplary embodiment, a method of producing a base coat includes forming a CPO intermediate and a color intermediate. The CPO intermediate includes a CPO solvent and a chlorinated polyolefin, where the chlorinated polyolefin is present in the CPO intermediate at from about 5 to about 20 weight percent, based on a total weight of the CPO intermediate. The color intermediate includes a color imparting additive and a color solvent that is different than the CPO solvent. The CPO intermediate and the color intermediate are combined to form the base coat.

An object of the present invention is to provide a nonaqueous primer composition offering excellent discharge property and adhesion to printing media, even when applied on roll materials (acrylic, PET, etc.), board materials (glass, plastics, etc.), and other nonabsorbent media. As a solution, a nonaqueous primer composition containing a chlorinated polyolefin resin and a ketone resin is provided, wherein the chlorinated polyolefin resin and ketone resin together account for at least 10 percent by mass in the primer composition, the chlorine content in the chlorinated polyolefin resin is 30 to 50 percent by mass, and the chlorinated polyolefin resin and ketone resin are contained at a ratio by mass, calculated by “Chlorinated polyolefin resin/Ketone resin,” of 3/7 to 7/3.

An object of the present invention is to provide a nonaqueous primer composition offering excellent discharge property and adhesion to printing media, even when applied on roll materials (acrylic, PET, etc.), board materials (glass, plastics, etc.), and other nonabsorbent media. As a solution, a nonaqueous primer composition containing a chlorinated polyolefin resin and a ketone resin is provided, wherein the chlorinated polyolefin resin and ketone resin together account for at least 10 percent by mass in the primer composition, the chlorine content in the chlorinated polyolefin resin is 30 to 50 percent by mass, and the chlorinated polyolefin resin and ketone resin are contained at a ratio by mass, calculated by “Chlorinated polyolefin resin/Ketone resin,” of 3/7 to 7/3.

We describe a new approach to fabricate polymeric materials with surface structures for applications as anti-reflective, anti-icing, superhydrophobic, superhydrophilic, de-wetting, and self-cleaning coatings. In some variations, a surface-textured layer comprises first microdomains and second microdomains each containing polymerized cross-linkable photomonomer, where the first microdomains have a higher average cross-link density than that of the second microdomains. The first microdomains and the second microdomains are in a peak-valley surface topology, providing surface texture with no filler particles. In some variations, a method to fabricate a surface-textured layer comprises: applying a cross-linkable photomonomer layer to a reflective substrate; exposing the photomonomer layer to a collimated light beam with no spatial variation, to initiate polymerization in first microdomains; and polymerizing other regions of the photomonomer layer to form second microdomains that are spatially separated from the first microdomains. The first microdomains have a higher average cross-link density compared to the second microdomains.

We describe a new approach to fabricate polymeric materials with surface structures for applications as anti-reflective, anti-icing, superhydrophobic, superhydrophilic, de-wetting, and self-cleaning coatings. In some variations, a surface-textured layer comprises first microdomains and second microdomains each containing polymerized cross-linkable photomonomer, where the first microdomains have a higher average cross-link density than that of the second microdomains. The first microdomains and the second microdomains are in a peak-valley surface topology, providing surface texture with no filler particles. In some variations, a method to fabricate a surface-textured layer comprises: applying a cross-linkable photomonomer layer to a reflective substrate; exposing the photomonomer layer to a collimated light beam with no spatial variation, to initiate polymerization in first microdomains; and polymerizing other regions of the photomonomer layer to form second microdomains that are spatially separated from the first microdomains. The first microdomains have a higher average cross-link density compared to the second microdomains.

Provided is a modified polyolefin resin that is excellent in adhesion to nonpolar substrates such as a polyolefin substrate, and excellent in stability in an alcohol solvent. In the modified polyolefin resin, the following polymer (A) is grafted on the following resin (B). Polymer (A): a polymer including at least one constitutional unit selected from the group consisting of a constitutional unit derived from an α,β-unsaturated carboxylic acid and a constitutional unit derived from a derivative of an α,β-unsaturated carboxylic acid, and having a hydroxyl value in a range of 10 mgKOH/g or larger and 200 mgKOH/g or smaller. Resin (B): a polyolefin resin or a modified product thereof.

Provided is a modified polyolefin resin that is excellent in adhesion to nonpolar substrates such as a polyolefin substrate, and excellent in stability in an alcohol solvent. In the modified polyolefin resin, the following polymer (A) is grafted on the following resin (B). Polymer (A): a polymer including at least one constitutional unit selected from the group consisting of a constitutional unit derived from an α,β-unsaturated carboxylic acid and a constitutional unit derived from a derivative of an α,β-unsaturated carboxylic acid, and having a hydroxyl value in a range of 10 mgKOH/g or larger and 200 mgKOH/g or smaller. Resin (B): a polyolefin resin or a modified product thereof.

Base coats, methods of using base coats, and methods of producing base coats are provided. In an exemplary embodiment, a method of producing a base coat includes forming a CPO intermediate and a color intermediate. The CPO intermediate includes a chlorinated polyolefin at from about 5 to about 20 weight percent, based on a total weight of the CPO intermediate, as well as a CPO solvent. The color intermediate includes a color imparting additive and a color solvent that is different than the CPO solvent. The CPO intermediate and the color intermediate are combined to form the base coat, where the base coat includes from about 1 to about 3 weight percent chlorinated polyolefin and from about 5 to about 30 weight percent solids, based on a total weight of the base coat.