A laminate can comprise a substrate, an adhesion promoter layer, and a coating layer, wherein the adhesion promoter layer may include a silane compound of formula (1): X.sub.mSiY.sub.n (1), wherein X is at least one of OR, NR.sub.2, or SR, or a combination thereof, with R being substituted or unsubstituted alkyl or aryl; Y is CHCH.sub.2 or L-CHCH.sub.2, with L being phenyl or C.sub.1-C.sub.5alkyl; m is 1-3, n is 1-3, with m+n=4. The adhesion promoter layer can provide strong adhesion of the coating layer to the substrate by forming covalent bonds with the substrate and covalent bonds with the coating layer.

A laminate can comprise a substrate, an adhesion promoter layer, and a coating layer, wherein the adhesion promoter layer may include a silane compound of formula (1): X.sub.mSiY.sub.n (1), wherein X is at least one of OR, NR.sub.2, or SR, or a combination thereof, with R being substituted or unsubstituted alkyl or aryl; Y is CHCH.sub.2 or L-CHCH.sub.2, with L being phenyl or C.sub.1-C.sub.5alkyl; m is 1-3, n is 1-3, with m+n=4. The adhesion promoter layer can provide strong adhesion of the coating layer to the substrate by forming covalent bonds with the substrate and covalent bonds with the coating layer.