The present invention relates to a composition comprises at least one random copolymer having at least one repeat unit of structure (1), The present invention also relates to novel processes for forming patterns using this novel crosslinked layer on a substrate by enable a film of a block copolymer coated on the novel crosslinked layer to undergo self-assembly. ##STR00001##

Useful articles, such as coatings, adhesives, printed graphics, 3D printed articles and molded articles are prepared by curing compositions containing one or more salts of ethylenically unsaturated carboxylic acids comprising six or more carbon atoms, one or more multifunctional (meth)acrylate oligomers and one or more mono(meth)acrylate esters of alcohols which, when polymerized as homopolymers, have glass transition temperatures of at least 50° C.

Useful articles, such as coatings, adhesives, printed graphics, 3D printed articles and molded articles are prepared by curing compositions containing one or more salts of ethylenically unsaturated carboxylic acids comprising six or more carbon atoms, one or more multifunctional (meth)acrylate oligomers and one or more mono(meth)acrylate esters of alcohols which, when polymerized as homopolymers, have glass transition temperatures of at least 50° C.

An object is to provide a resin composition having excellent performance as a binder such as adhesiveness and, at the same time, retaining solution properties favorably even after a solution is stored for a long period of time. A modified polyolefin resin composition includes a modified polyolefin resin (C), in which the modified polyolefin resin (C) is a resin made by modifying a polymer (A) that is a polymer (a) of a polyolefin resin or a chlorinated polyolefin resin and an α,β-unsaturated carboxylic acid derivative having a structure derived from at least one carboxy group or a chlorinated product (b) thereof with a modification component including an alcohol (B); and a residual ratio of the structure derived from at least one carboxy group in the modified polyolefin resin (C) is 50% or more and 80% or less.

The present invention belongs to the technical field of marine anti-fouling materials, and discloses a self-polishing zwitterionic anti-fouling resin having a main chain degradability and the preparation therefor and the use thereof. The self-polishing zwitterionic anti-fouling resin is formed by copolymerizing the following three monomers (in the total mass of the monomers): 1% to 80% of an olefinic reactive monomer, 1% to 80% of a cycloketene acetal monomer, and 1% to 80% of a betaine type precursor. The anti-fouling resin has a main chain degradability and a side chain hydrolyzability, and the transition of a coating from being hydrophobic to being hydrophilic is achieved by the hydrolysis of a surface to produce a super-hydrophilic zwitterionic surface, in order to further enhance the anti-fouling ability of the system. The material not only overcomes the disadvantages of poor mechanical properties and poor solubility in an organic solvent of a zwitterionic material, but can also effectively control the long-term stable release of an anti-fouling agent, so as to achieve a synergistic anti-fouling effect of the anti-fouling agent and an anti-protein. The method of the present invention is simple, has a relatively low cost, and is suitable for industrial production. The material is used in the field of marine anti-fouling coatings.

A disinfectant cleaning composition, the composition comprising: a nitrogen containing biocidal compound; a polymer comprising monomers of the following formulae: a) H2C═CR1-CO—NH—R2-N+R3R4R5X— wherein R1 represents hydrogen or C1-C4 alkyl; R2 represents linear or branched C1-C12 alkylene; R3, R4 and R5, independently of one another, each represent hydrogen, C1-C18 alkyl or phenyl; and X— represents an anion selected from the group consisting of halide, sulfate, alkylsulfate, hydroxide, phosphate, acetate and formate; b) 40-75% by weight of N-isopropylacrylamide, based on the water-soluble polymer; c) acrylic and/or methacrylic acid and/or salts thereof; and d) H2C═CR—CO—NH—CR′R″R′″—SO3H, and salts thereof; wherein R, R′ and R″ independently represent hydrogen, C1-C4 alkyl or C1-C4 alkylene, and R′″ independently represents C1-C4 alkyl or C1-C4 alkylene.

Disclosed herein is a polymeric film, the film comprising a polymeric matrix material, a plurality of perovskite nanocrystals and/or aggregates of perovskite nanocrystals dispersed throughout the polymeric matrix material. There is also disclosed a perovskite polymer resin composition, a perovskite-polymer resin composition, a perovskite ink and a method of forming a luminescent film using any one of the compositions or ink. Preferably, the perovskite material is a lead halide perovskite containing a cation selected from Cs, an alkylammonium ion, or a formamidinium ion. The polymeric matrix is preferably formed from monomers comprising a vinyl or an acrylate group.

Described herein is a 2K clearcoat composition including, Component I including a). at least one resin having carboxylic acid groups with acid value of 50 to 400 mg KOH/g; b). at least one resin having hydroxyl functional groups with a hydroxyl value of 10 to 800 mg KOH/g; c). at least one catalyst; and d). at least one solvent, and Component II including e). at least one epoxy-functional alkoxysilane and/or its oligomer and/or its polymer; and f). at least one crosslinker reactive to hydroxyl groups.

Also described herein are a substrate coated with the dried and cured 2K clearcoat composition and an automotive including the substrate.

Described herein is a 2K clearcoat composition including, Component I including a). at least one resin having carboxylic acid groups with acid value of 50 to 400 mg KOH/g; b). at least one resin having hydroxyl functional groups with a hydroxyl value of 10 to 800 mg KOH/g; c). at least one catalyst; and d). at least one solvent, and Component II including e). at least one epoxy-functional alkoxysilane and/or its oligomer and/or its polymer; and f). at least one crosslinker reactive to hydroxyl groups.

Also described herein are a substrate coated with the dried and cured 2K clearcoat composition and an automotive including the substrate.

Compositions are provided according to aspects of the present invention that include a hydrogel and a liner, wherein a surface of the hydrogel dissociably-engages a surface of the liner. Compositions are provided according to aspects of the present invention that include a hydrogel and a hydrophobic glue, wherein at least a portion of the gel network of the hydrogel is occupied by the hydrophobic glue. Reverse coaling processes and articles of manufacture made by reverse coating processes are provided according to aspects of the present invention. Compositions are provided according to aspects of the present invention that include a hydrogel and a substrate, wherein: the hydrogel comprises a polymer network; the substrate comprises a surface comprising a polymer network; and the polymer network of the hydrogel and the polymer network of the surface are entangled.