A primer composition and a laminated substrate with a primer are provided. The primer composition includes 60 to 90 parts by weight of vinyl-aromatic-conjugated-diene copolymer, 1 to 16 parts by weight of a compound having at least three of terminal acryloyloxy groups and 5 to 24 parts by weight of a silane coupling agent, wherein the silane coupling agentis distinct from the compound having at least three of terminal acryloyloxy groups.

Disclosed herein is a process for laminating a polar substrate with a film cast from a sulfonated block copolymer having at least one end block A and at least one interior block B wherein each A block contains essentially no sulfonic acid or sulfonate ester functional groups and each B block is a polymer block containing from about 10 to about 100 mol percent sulfonic acid or sulfonate ester functional groups based on the number of monomer units. The film is exposed to water and dried onto a polar or active metal substrate. The laminates do not delaminate in the presence of water, or in a humidity of up to 85%, and at a temperature of at least 60° C. The laminates are used for a variety of applications including energy exchange applications.

A coating film capable of being peeled off in the shape of sheet to facilitate a coating film removal work, and is less likely to peel even after long periods of use on an underwater structure is provided. The coating film comprises an undercoat layer to be bonded to an underwater structure, and an antifouling layer bonded to the undercoat layer, wherein: a 100-gram underwater constant load peeling degree of the coating film is less than 5; a ratio of a tensile breaking strength of the coating film to an adhesive force of the coating film with respect to the underwater structure, as measured after immersing the coating film in pure water at 60° C. for 5 weeks is 1.5 or more; and a 1-mm square cross-cut stretching-caused peeling degree of the antifouling layer with respect to the undercoat layer is 0.05 or less.

A coating composition comprises at least one solvent, at least one resin, and at least one filler, wherein the filler is silica-deficient, sodium-potassium alumina silicate. The silica-deficient filler may be a sodium-potassium alumina silicate that contains less than 0.1 percent by weight crystalline silica and is 5 percent by weight or less of the coating composition or 1 percent by weight or less of the coating composition. In the later instance, the coating composition contains less than 0.001 percent crystalline silica. The resin may comprise styrene, styrenic copolymers, or mixtures including styrene. The composition provides a temporary gloss coating that may be removed physically, as by peeling for example. A method for coating a substrate with a coating that maybe removed by physical means is also provided. The method comprises applying the disclosed coating composition.

The present invention discloses a method for coating gum of self-adhesive mat with spaced-apart gum, using a mat body, gum layers being spaced apart on a bottom surface of the mat body, including the following steps of: weighing raw materials of components in a determined proportion, stirring uniformly by a stirrer that supplies hot air for dehumidification, conveying the mixture to an extruder through a screw, thermally melting by the screw extruder, extruding from rectangular discharge ports formed at intervals on the extruder and vertically falling onto an upper roller (the roller surface is a smooth surface) of a rolling and combining device, passing a mat body from an unwinding device to a lower roller of the rolling and combining device, rolling the mat body by adjusting a gap between the upper and lower rollers by a lead screw, forming self-adhesive gum layers, which are spaced apart from each other, on the back of the mat body. The gum using hydrogenated styrene-butadiene block copolymer (SEBS) as a main raw material coating on the bottom surface. According to the present invention, the gum is able to adequately adsorb the mat onto the floor due to its good flexibility, and allow the mat to move without affecting the adsorption effect due to its good detachability. Meanwhile, the mat is non-toxic and environmentally friendly, can be washed repeatedly without affecting its self-adhesive adsorption effect and can be reused. It is of great significance for the development of mats.

The present invention discloses a method for coating gum of self-adhesive mat with spaced-apart gum, using a mat body, gum layers being spaced apart on a bottom surface of the mat body, including the following steps of: weighing raw materials of components in a determined proportion, stirring uniformly by a stirrer that supplies hot air for dehumidification, conveying the mixture to an extruder through a screw, thermally melting by the screw extruder, extruding from rectangular discharge ports formed at intervals on the extruder and vertically falling onto an upper roller (the roller surface is a smooth surface) of a rolling and combining device, passing a mat body from an unwinding device to a lower roller of the rolling and combining device, rolling the mat body by adjusting a gap between the upper and lower rollers by a lead screw, forming self-adhesive gum layers, which are spaced apart from each other, on the back of the mat body. The gum using hydrogenated styrene-butadiene block copolymer (SEBS) as a main raw material coating on the bottom surface. According to the present invention, the gum is able to adequately adsorb the mat onto the floor due to its good flexibility, and allow the mat to move without affecting the adsorption effect due to its good detachability. Meanwhile, the mat is non-toxic and environmentally friendly, can be washed repeatedly without affecting its self-adhesive adsorption effect and can be reused. It is of great significance for the development of mats.

A layered film includes first, second, and third layers formed of first, second, and third resins, respectively, and provided in this order. The second resin contains an alkoxysilyl group-modified product of a hydrogenated product of a block copolymer; has 0.020% by weight or less of a moisture content as measured by the Karl-Fischer method after immersed in water at 37 C. for 24 hours and then allowed to stand at 23 C. and a humidity of 70% for 24 hours; and has a flexural modulus lower than flexural moduli of the first and third resins. One or both of the first and third resins contain a polymer containing an alicyclic structure. The first resin has a specific water vapor transmission rate. A ratio of a sum of thicknesses of the first and third layers relative to a thickness of the second layer is in a specific range.

The disclosure relates to a hydrogenated styrenic block copolymer with high vinyl content, low viscosity, low order-disorder temperature and improved processability. The hydrogenated styrenic block copolymers can be extruded or molded with a minimum of additives. The hydrogenated styrenic block copolymers have high melt flows allowing for ease in processing such as injection molding, overmolding, dipping, extrusion, roto-molding, slush molding, fiber spinning, film making, 3D printing and foaming.

The disclosure relates to an article comprising a substrate and an antifog coating layer provided on at least one surface of the substrate. The antifog coating layer comprises a sulfonated styrenic block copolymer (SSBC) having a block A, a block B, and a block D. Block A is a polymer block resistant to sulfonation and derived from a para-substituted styrene monomer, block B is a polymer block susceptible to sulfonation and derived from a vinyl aromatic monomer, and block D is a polymer block resistant to sulfonation and derived from a conjugated diene monomer. The antifog coating layer provides long-term antifog as well as anti-microbial protection properties. The selection of a specific solvent system can modify the SSBC film morphology leading to enhanced antifog property. The antifog coating layer adheres well to targeted substrates and has abrasion resistance property.

An object of the present invention is to provide a coating film that can be peeled in a sheet form, facilitates removal work and is less likely to be peeled even if used for a long period of time, and an undercoat layer-forming composition for forming an undercoat layer of the coating film. The present invention relates to an undercoat layer-forming composition for forming an undercoat layer of a coating film including the undercoat layer and an antifouling layer adhered to the undercoat layer, wherein the undercoat layer-forming composition comprises a base polymer and a silicone polymer, and a polar group-containing substituent is bonded to at least a part of the silicone polymer.