The present invention generally relates a polymer-metal junction comprising PEEK-PEmEK copolymers compositions, in contact with a metal substrate, wherein the PEEK-PEmEK copolymer having R.sub.PEEK and R.sub.PEmEK repeat units in a molar ratio R.sub.PEEK/R.sub.PEmEK ranging from 95/5 to 45/55. The present invention also relates to shaped articles including the polymer-metal junction, and methods of making the polymer-metal junctions.

Tunable thermoplastic polymer powder feedstock formulations and tunable conductive thermoplastic polymer powder feedstock formulations are disclosed for delivery to a high-velocity sprayer are presently disclosed, along with tunable coatings made from the disclosed formulations, and methods for delivering such tunable thermoplastic polymer coatings to substrates.

Tunable thermoplastic polymer powder feedstock formulations and tunable conductive thermoplastic polymer powder feedstock formulations are disclosed for delivery to a high-velocity sprayer are presently disclosed, along with tunable coatings made from the disclosed formulations, and methods for delivering such tunable thermoplastic polymer coatings to substrates.

A method of making a shaped article comprising printing layers of a polymer composition comprising at least one PEEK-PEmEK copolymer having R.sub.PEEK and R.sub.PEmEK repeat units in a molar ratio R.sub.PEEK/R.sub.PEmEK ranging from 95/5 to 45/55, the polymer composition optionally including at least one reinforcing filler, at least one additive, or a combination thereof, and shaped articles obtained from the method. Also described are methods of making the PEEK-PEmEK copolymer and methods of making the polymer composition.

A method of making a shaped article comprising printing layers of a polymer composition comprising at least one PEEK-PEmEK copolymer having R.sub.PEEK and R.sub.PEmEK repeat units in a molar ratio R.sub.PEEK/R.sub.PEmEK ranging from 95/5 to 45/55, the polymer composition optionally including at least one reinforcing filler, at least one additive, or a combination thereof, and shaped articles obtained from the method. Also described are methods of making the PEEK-PEmEK copolymer and methods of making the polymer composition.

A material for use in a fused filament fabrication (FFF) printer comprises a polyaryletherketone (PAEK) having an amorphous morphology. In some embodiments, the material also includes a PAEK having a semi-crystalline morphology.

A material for use in a fused filament fabrication (FFF) printer comprises a polyaryletherketone (PAEK) having an amorphous morphology. In some embodiments, the material also includes a PAEK having a semi-crystalline morphology.

The present invention generally relates a polymer-metal junction comprising PEEK-PEmEK copolymers compositions, in contact with a metal substrate, wherein the PEEK-PEmEK copolymer having R.sub.PEEK and R.sub.PEmEK repeat units in a molar ratio R.sub.PEEK/R.sub.PEmEK ranging from 95/5 to 45/55. The present invention also relates to shaped articles including the polymer-metal junction, and methods of making the polymer-metal junctions.

A method of making a PEEK-PEmEK copolymer having R.sub.PEEK and R.sub.PEmEK repeat units in a molar ratio R.sub.PEEK/R.sub.PEmEK ranging from 95/5 to 45/55, the PEEK-PEmEK copolymer obtained from the method and the polymer composition including the PEEK-PEmEK copolymer, at least one reinforcing filler, at least one additive, or a combination thereof, shaped articles including the polymer composition, polymer-metal junctions including the polymer composition. Also described are methods of making the polymer composition, methods of making the shaped articles, and methods of making the polymer-metal junctions.

A method of making a PEEK-PEmEK copolymer having R.sub.PEEK and R.sub.PEmEK repeat units in a molar ratio R.sub.PEEK/R.sub.PEmEK ranging from 95/5 to 45/55, the PEEK-PEmEK copolymer obtained from the method and the polymer composition including the PEEK-PEmEK copolymer, at least one reinforcing filler, at least one additive, or a combination thereof, shaped articles including the polymer composition, polymer-metal junctions including the polymer composition. Also described are methods of making the polymer composition, methods of making the shaped articles, and methods of making the polymer-metal junctions.