The present invention relates to a pigmented aqueous basecoat material comprising a carboxy-functional dimer fatty acid-based reaction product which is preparable by reaction of

(a) dimer fatty acids with
(b) at least one compound of the general structural formula (I)

##STR00001##

where R is a C.sub.3 to C.sub.6 alkylene radical and n is selected accordingly such that the polyether (b) possesses a number-average molecular weight of 120 to 6000 g/mol, components (a) and (b) are used in a molar ratio of at least 1/1 and the resulting reaction product possesses a number-average molecular weight of 1000 to 20 000 g/mol and an acid number of 10 to 120 mg KOH/g.

The present invention relates to a pigmented aqueous basecoat material comprising a carboxy-functional dimer fatty acid-based reaction product which is preparable by reaction of

(a) dimer fatty acids with
(b) at least one compound of the general structural formula (I)

##STR00001##

where R is a C.sub.3 to C.sub.6 alkylene radical and n is selected accordingly such that the polyether (b) possesses a number-average molecular weight of 120 to 6000 g/mol, components (a) and (b) are used in a molar ratio of at least 1/1 and the resulting reaction product possesses a number-average molecular weight of 1000 to 20 000 g/mol and an acid number of 10 to 120 mg KOH/g.

A water-based coil coating without amine neutralization includes the following components in percent by weight: an amine-free waterborne resin: 88-93%, a crosslinking resin: 4-9%, a first auxiliary: 0.5%, a second auxiliary: 0.5%, a third auxiliary: 2.0%, and a diluent. A solid content in the water-based coil coating is greater than 40%. A solid content ratio of the amine-free waterborne resin to the crosslinking resin is in a range of 4-9. The water-based coil coating does not include amine neutralizing agents, not only possesses performance equivalent to or even exceeding that of oil-based coatings, but also greatly reduces VOC emissions, allowing for direct exhaust of tail gases. Wastewater treatment is extremely simple, and there is no pollution from ammonia nitrogen and nitrogen oxides. Downstream coating enterprises have a very high acceptance of the water-based coil coating without the amine neutralization.

A water-based coil coating without amine neutralization includes the following components in percent by weight: an amine-free waterborne resin: 88-93%, a crosslinking resin: 4-9%, a first auxiliary: 0.5%, a second auxiliary: 0.5%, a third auxiliary: 2.0%, and a diluent. A solid content in the water-based coil coating is greater than 40%. A solid content ratio of the amine-free waterborne resin to the crosslinking resin is in a range of 4-9. The water-based coil coating does not include amine neutralizing agents, not only possesses performance equivalent to or even exceeding that of oil-based coatings, but also greatly reduces VOC emissions, allowing for direct exhaust of tail gases. Wastewater treatment is extremely simple, and there is no pollution from ammonia nitrogen and nitrogen oxides. Downstream coating enterprises have a very high acceptance of the water-based coil coating without the amine neutralization.

A resist underlayer film-forming composition containing a copolymer having a structural unit of Formula (1) and a structural unit of Formula (2), a cross-linkable compound, a cross-linking catalyst, and a solvent.

##STR00001##

wherein A is a divalent organic group containing a triazine ring, X.sup.1 is an S group or an O group, Q is a linear, branched, or cyclic hydrocarbon group having a carbon atom number of 1 to 15, the hydrocarbon group may have at least one sulfur atom or oxygen atom in a main chain and at least one hydroxy group as a substituent, n is 0 or 1, R.sup.1 and R.sup.2 are each independently a C.sub.1-3 alkylene group or a single bond, Z is a divalent group having at least one sulfur atom or oxygen atom, and when X.sup.1 is an O group, Z is a divalent group having at least one sulfur atom.

The present invention relates to a polyester resin with excellent solubility in generic solvents, especially with excellent solubility at a temperature of 0 C. or lower. According to the present invention, by using the polyester resin with excellent solubility in generic solvents, solubility at a lower temperature, especially the solubility at a temperature of 0 C. or lower, is enhanced, making it easier to prepare paints, coatings and the like. The polyester resin related to the present invention contains 0.05 to 0.5 mol of an isosorbide-derived structural unit and 0.015 to 0.4 mol of a trihydric or higher alcohol-derived structural unit relative to 1 mol of a polycarboxylic acid-derived structural unit.

The present invention relates to a polyol comprising a) at least one dimer fatty residue selected from a dimer fatty diacid residue and a dimer fatty diol residue; and b) at least one residue of a linear or branched C17 to C32 dicarboxylic acid or diol; wherein the polyol comprises at least two hydroxyl end groups. The invention also relates to a a polyurethane comprising the polyol, the use of the polyol and a method of making the polyurethane.

The invention relates to a hydroxyl-functional polyester containing a perfluoropolyether block prepared by a method comprising the following steps: a) subjecting a carboxyl-terminated perfluoropolyether C to a reaction with an epoxy-functional compound D, and b) subjecting the reaction product of step a) to a reaction with a lactone E. The polyester thus prepared can be used in a coating composition, comprising further (b) an OH-functional or epoxy-functional resin, and (c) a hardener comprising groups reactive to the OH or epoxy-functional groups of resin (b).

A pigment water dispersion including pigment-containing polyester resin particles. An alcohol component as a raw material monomer of the polyester resin satisfies the following conditions 1 and 2. Condition 1: a content of a compound (I) represented by the following formula (I) in the alcohol component is not more than 7 mol %, ##STR00001##
wherein OR.sup.1 and R.sup.2O are each independently an oxyalkylene group comprising not less than 1 and not more than 4 carbon atoms, and x and y are each independently a positive number of not less than 0. Condition 2: a content of a compound (II) comprising two secondary hydroxy groups except for the compound (I) in the alcohol component is not less than 45 mol %.

A process for producing an aqueous polyorganosiloxane hybrid resin dispersion includes emulsifying a polyorganosiloxane hybrid resin solution of a polyorganosiloxane hybrid resin and an organic or semi-organic solvent with an emulsifier solution that includes at least one emulsifier based on a partly hydrolysed polyvinylacetate and removing the organic or semi-organic solvent.