A process for preparing a polymeric membrane for materials used in crop production comprising: a) providing an aqueous dispersion of a polyurethane or polyurethane-urea elastomer comprising segments formed from the copolymer segment of Formula I
A.sup.1-[Y.sup.1].sub.n-L-[Y.sup.2].sub.q-A.sup.2  Formula I
wherein A.sup.1 is an end capping group; A.sup.2 is hydrogen or an end capping group; each [Y.sup.1].sub.n and [Y.sup.2].sub.q is independently selected from a polyether macrodiol, polycarbonate macrodiol, polyester macrodiol, and wherein at least one of [Y.sup.1].sub.n and [Y.sup.2].sub.q is a polyester macrodiol; L is a divalent linking compound independently selected from urethane, urea, carbonate, ester, and phosphonate; n is an integer of 2 to 50; q is an integer of 2 to 50; and b) spraying the aqueous dispersion onto materials to be used in crop production to form a polymeric membrane on the materials.

A process for preparing a polymeric membrane for materials used in crop production comprising: a) providing an aqueous dispersion of a polyurethane or polyurethane-urea elastomer comprising segments formed from the copolymer segment of Formula I
A.sup.1-[Y.sup.1].sub.n-L-[Y.sup.2].sub.q-A.sup.2  Formula I
wherein A.sup.1 is an end capping group; A.sup.2 is hydrogen or an end capping group; each [Y.sup.1].sub.n and [Y.sup.2].sub.q is independently selected from a polyether macrodiol, polycarbonate macrodiol, polyester macrodiol, and wherein at least one of [Y.sup.1].sub.n and [Y.sup.2].sub.q is a polyester macrodiol; L is a divalent linking compound independently selected from urethane, urea, carbonate, ester, and phosphonate; n is an integer of 2 to 50; q is an integer of 2 to 50; and b) spraying the aqueous dispersion onto materials to be used in crop production to form a polymeric membrane on the materials.

A process for preparing a polymeric membrane for materials used in crop production comprising: a) providing an aqueous dispersion of a polyurethane or polyurethane-urea elastomer comprising segments formed from the copolymer segment of Formula I
A.sup.1-[Y.sup.1].sub.n-L-[Y.sup.2].sub.q-A.sup.2  Formula I
wherein A.sup.1 is an end capping group; A.sup.2 is hydrogen or an end capping group; each [Y.sup.1].sub.n and [Y.sup.2].sub.q is independently selected from a polyether macrodiol, polycarbonate macrodiol, polyester macrodiol, and wherein at least one of [Y.sup.1].sub.n and [Y.sup.2].sub.q is a polyester macrodiol; L is a divalent linking compound independently selected from urethane, urea, carbonate, ester, and phosphonate; n is an integer of 2 to 50; q is an integer of 2 to 50; and b) spraying the aqueous dispersion onto materials to be used in crop production to form a polymeric membrane on the materials.

Polymers are disclosed that incorporate portions of secondary or tertiary polyamide segments connected with polyisocyanates. These polymers have enhanced matting properties. The enhanced matting properties are from creating an inherently matt surface from the polymer without the use of any separate fine particle size matting additives. Conventional matting agents such as fine particle size silica usually results in loss of physical properties such as haze development and porosity in the coating from the matting agent. Composites and hybrids of these polymers and other polyamides, polyurethane with vinyl polymers (acrylates) are also disclosed and claimed.

Polymers are disclosed that incorporate portions of secondary or tertiary polyamide segments connected with polyisocyanates. These polymers have enhanced matting properties. The enhanced matting properties are from creating an inherently matt surface from the polymer without the use of any separate fine particle size matting additives. Conventional matting agents such as fine particle size silica usually results in loss of physical properties such as haze development and porosity in the coating from the matting agent. Composites and hybrids of these polymers and other polyamides, polyurethane with vinyl polymers (acrylates) are also disclosed and claimed.

The present invention relates to a two-component coating system comprising a first component and a second component each of which is separate and distinct from each other, wherein the first component comprises a carboxylic acid functional polymer dissolved and/or dispersed in an aqueous medium, and the second component comprises a multi-aziridine compound having: a) from 2 to 6 of the following structural units (A): b) whereby m is an integer from 1 to 8; and o R′ and R″ are both H b) one or more linking chains wherein each one of these linking chains links two of the structural units A; c) one or more connecting groups whereby each one of the connecting groups connects two of the structural units A; and d) a molecular weight in the range from 840 Daltons to 5000 Daltons, wherein the molecular weight is measured using MALDI-TOF mass spectrometry.

##STR00001##

The present invention relates to a two-component coating system comprising a first component and a second component each of which is separate and distinct from each other, wherein the first component comprises a carboxylic acid functional polymer dissolved and/or dispersed in an aqueous medium, and the second component comprises a multi-aziridine compound having: a) from 2 to 6 of the following structural units (A): b) whereby m is an integer from 1 to 8; and o R′ and R″ are both H b) one or more linking chains wherein each one of these linking chains links two of the structural units A; c) one or more connecting groups whereby each one of the connecting groups connects two of the structural units A; and d) a molecular weight in the range from 840 Daltons to 5000 Daltons, wherein the molecular weight is measured using MALDI-TOF mass spectrometry.

##STR00001##

There is provided an erosion protective polyurethane elastomer produced from a polyurethane composition with a polyisocyanate component and an isocyanate-reactive component. The polyisocyanate component has a first isocyanate-terminated prepolymer obtained from the reaction of a first polyol with 1,4-bis(isocyanatomethyl cyclohexane) (1,4-H6XDI) or with a mixture of 1,4-H6XDI and a second aliphatic diisocyanate, an aromatic diisocyanate, and/or an arylalkyl diisocyanate, with at least 50 wt. % of diisocyanate used to produce the prepolymer is aliphatic diisocyanate. The isocyanate-reactive component has at least two low molecular weight (Mw<400 g/mol) diols and a second polyol with hydroxyl groups to react with the prepolymer to produce a polyurethane elastomer. The polyurethane composition having a molar ratio of NCO/OH in the range of 1.00-1.50; whereby said polyurethane composition is curable to produce an elastomer having a mechanical strength >20 MPa, an elongation at break >500%, a tensile set <30%, and hydrolytic stability.

The present invention provides a coating composition which is capable of forming a coating film that has excellent adhesion to a base material. The coating composition contains: an isocyanate-reactive group-containing resin (A); a polyisocyanate compound (B); and a hydroxyl group-containing aromatic compound (C) having a number average molecular mass of 100-1,000. The isocyanate-reactive group-containing resin (A) in the coating composition contains at least one type of resin selected from a hydroxyl group-containing resin (A1) and an amino group-containing resin (A2).

The present invention provides a coating composition which is capable of forming a coating film that has excellent adhesion to a base material. The coating composition contains: an isocyanate-reactive group-containing resin (A); a polyisocyanate compound (B); and a hydroxyl group-containing aromatic compound (C) having a number average molecular mass of 100-1,000. The isocyanate-reactive group-containing resin (A) in the coating composition contains at least one type of resin selected from a hydroxyl group-containing resin (A1) and an amino group-containing resin (A2).