The present invention relates to a water-based coating composition, the preparation and use of the composition, a two-component coating system comprising the composition and use thereof, and an article obtained by coating with the composition or the two-component coating system. The water-based coating composition comprises a water-based UV resin; a silane-treated nanosized silicon oxide compound; and a photoinitiator; wherein per kilogram of the solid constituent of the water-based UV resin contains not less than 3 mol of ethylenically unsaturated groups, and wherein the weight ratio of the solid constituent of the nanosized silicon oxide compound to the solid constituent of the water-based UV resin is 11:20 to 73:100. The coating layer formed by the water-based coating composition of the present invention has high hardness and good adhesion, and is particularly suitable for electronic, electrical and communication equipment in the 5G field.

The present invention relates to a water-based coating composition, the preparation and use of the composition, a two-component coating system comprising the composition and use thereof, and an article obtained by coating with the composition or the two-component coating system. The water-based coating composition comprises a water-based UV resin; a silane-treated nanosized silicon oxide compound; and a photoinitiator; wherein per kilogram of the solid constituent of the water-based UV resin contains not less than 3 mol of ethylenically unsaturated groups, and wherein the weight ratio of the solid constituent of the nanosized silicon oxide compound to the solid constituent of the water-based UV resin is 11:20 to 73:100. The coating layer formed by the water-based coating composition of the present invention has high hardness and good adhesion, and is particularly suitable for electronic, electrical and communication equipment in the 5G field.

A preparation method for an ultraviolet-responsive coumarin controlled-release and self-repairing anti-fouling paint includes: reacting double-end-group reactive polydimethylsiloxane, polyisocyanate, and an organic diluting solvent; adding a dihydroxycoumarin compound, a cross-linking agent and an organotin catalyst; adding a simple coumarin compound, and irradiating the mixture with 365 nm ultraviolet light to obtain the anti-fouling paint. An anti-fouling coat formed by the paint of the present invention has the advantages of controllable release of a coumarin green anti-fouling agent in response to external ultraviolet stimulation and self-repairing, and the problems that the release of the conventional anti-fouling agents in the anti-fouling coat is difficult to control, and that the low-surface-energy anti-fouling coat is difficult to repair after being damaged are solved. The anti-fouling application requirements of various shallow sea light-transmitting constructions can be met, the service life is prolonged, and the application performance in a complex real sea environment is enhanced.

Embodiments provide a coating material including (A) 100 parts by mass of an active-energy-ray-curable resin, (B) 5 to 200 parts by mass of aluminum oxide particles having an average particle diameter of 1 to 100 μm, (C) 0.1 to 20 parts by mass of aluminum oxide microparticles having an average particle diameter of 1 to 100 nm, and (D) 0.1 to 40 parts by mass of a compound having at least two isocyanate groups per molecule, where the active-energy-ray-curable resin (A) includes (a1) 70 to 99% by mass of a polyfunctional (meth)acrylate and (a2) 30 to 1% by mass of an acrylamide compound having at least one hydroxyl group per molecule, and the sum total of the amount of the polyfunctional (meth)acrylate (a1) and the amount of the acrylamide compound (a2) having at least one hydroxyl group per molecule is 100% by mass.

A two-component polyurethane composition comprising a polyisocyanate and an emulsion polymer having greater than 2.2% of hydroxy groups in the emulsion polymer and comprising structural units of a polymerizable surfactant, a first hydroxy-functional monomer, an acid monomer and/or a salt thereof, an additional monoethylenically unsaturated nonionic monomer, and optionally a second hydroxy-functional alkyl (meth)acrylate; the two-component polyurethane composition providing improved alcohol resistance without compromising both acid and alkali resistance.

Thermosetting powder coating compositions and processes for making the thermosetting powder coating compositions and processes for coating an article with the thermosetting powder coating compositions are disclosed. Cured thermosetting powder coating compositions are obtained by curing of the thermosetting powder coating compositions of the invention. Articles are provided having coated thereon the thermosetting powder coating compositions as well as to articles having coated and cured thereon the thermosetting powder coating compositions. The thermosetting powder coating compositions exhibit a substantially lower T.sub.chalk-free, that is a ΔT.sub.chalk-free which is in the range of from and including 5 up to and not including 10° C., wherein ΔT.sub.chalk-free=T.sub.chalk-free.sup.REF−T.sub.chalk-free.sup.A where T.sub.chalk-free.sup.A is the T.sub.chalk-free of a thermosetting powder coating composition according to the invention (TPCC-A) and T.sub.chalk-free.sup.REF is the T.sub.chalk-free of a thermosetting powder coating composition not according to the invention (TPCC-REF) that is comparable to TPCC-A.

Thermosetting powder coating compositions and processes for making the thermosetting powder coating compositions and processes for coating an article with the thermosetting powder coating compositions are disclosed. Cured thermosetting powder coating compositions are obtained by curing of the thermosetting powder coating compositions of the invention. Articles are provided having coated thereon the thermosetting powder coating compositions as well as to articles having coated and cured thereon the thermosetting powder coating compositions. The thermosetting powder coating compositions exhibit a substantially lower T.sub.chalk-free, that is a ΔT.sub.chalk-free which is in the range of from and including 5 up to and not including 10° C., wherein ΔT.sub.chalk-free=T.sub.chalk-free.sup.REF−T.sub.chalk-free.sup.A where T.sub.chalk-free.sup.A is the T.sub.chalk-free of a thermosetting powder coating composition according to the invention (TPCC-A) and T.sub.chalk-free.sup.REF is the T.sub.chalk-free of a thermosetting powder coating composition not according to the invention (TPCC-REF) that is comparable to TPCC-A.

Provided is a prepreg containing a urethane (meth)acrylate (A), an ethylenically unsaturated monomer (B), a polymerization initiator (C), and reinforcement fibers (D), characterized in that the urethane (meth)acrylate (A) is a reaction product of a polyisocyanate (a1) and a polyol (a2) having an ethylenically unsaturated group and an aromatic skeleton, and/or a reaction product of a polyisocyanate (a1), a polyol (a3) not having an ethylenically unsaturated group but having an aromatic skeleton, and a hydroxyalkyl (meth)acrylate (a4), and that the ethylenically unsaturated monomer (B) has a molecular weight of 320 or more and a weight reduction rate (%) of less than 2 when heated under atmospheric pressure at 150° C. for 3 minutes. The prepreg has excellent moldability and enables to produce a molded article having excellent physical properties such as flexural strength and interlaminar shear strength, and therefore the prepreg can be suitably used in automobile components and the like.

Provided is a water-based coating composition capable of exhibiting high coating film performance even when cured at relatively low temperatures. Disclosed is a water-based coating composition including (A) a hydroxyl group-containing resin and (B) a hardener, wherein at least one type of (A) the hydroxyl group-containing resin is a hydroxyl group-containing acrylic resin particle (A1) having a core-shell structure containing a gradient polymer layer.

Provided is a water-based coating composition capable of exhibiting high coating film performance even when cured at relatively low temperatures. Disclosed is a water-based coating composition including (A) a hydroxyl group-containing resin and (B) a hardener, wherein at least one type of (A) the hydroxyl group-containing resin is a hydroxyl group-containing acrylic resin particle (A1) having a core-shell structure containing a gradient polymer layer.