An aqueous dispersion can contain a) 50-80 wt.-% water, b) 10-30 wt.-% hydrophilic silicon dioxide with a methanol wettability of 0 vol.-% methanol in a methanol-water mixture, c) 2-25 wt.-% alcohol alkoxylate, d) 0.1-20 wt.-% silanol, obtained by the hydrolysis of at least one dialkoxysilane, e) 0.5-4 wt.-%, amine or an amine alcohol, f) 0.1-20 wt.-%, copolymer with side chains containing ethers and esters, and g) 0.1-6.0 wt.-% polyethylene glycol or polypropylene glycol.

An aqueous dispersion can contain a) 50-80 wt.-% water, b) 10-30 wt.-% hydrophilic silicon dioxide with a methanol wettability of 0 vol.-% methanol in a methanol-water mixture, c) 2-25 wt.-% alcohol alkoxylate, d) 0.1-20 wt.-% silanol, obtained by the hydrolysis of at least one dialkoxysilane, e) 0.5-4 wt.-%, amine or an amine alcohol, f) 0.1-20 wt.-%, copolymer with side chains containing ethers and esters, and g) 0.1-6.0 wt.-% polyethylene glycol or polypropylene glycol.

Provided is a curable composition including a urethanization reaction product of: a branched polyolefin diol; at least one selected from an isocyanurate product, an adduct product, and a biuret product, of an aliphatic diisocyanate having 6 to 10 total carbon atoms; and a hydroxy saturated C.sub.1 to C.sub.4 alkyl (meth)acrylate. Also provided are a method for producing the curable composition, and a specific curable compound included in the curable composition.

Provided is a curable composition including a urethanization reaction product of: a branched polyolefin diol; at least one selected from an isocyanurate product, an adduct product, and a biuret product, of an aliphatic diisocyanate having 6 to 10 total carbon atoms; and a hydroxy saturated C.sub.1 to C.sub.4 alkyl (meth)acrylate. Also provided are a method for producing the curable composition, and a specific curable compound included in the curable composition.

Surfacing films and related processes are provided. These films include a first clear coat layer comprising a first crosslinked polyurethane that is the reaction product of an isocyanate; a polyol selected from the group consisting of: a caprolactone polyol, polycarbonate polyol, a polyester polyol, acrylic polyol, polyether polyol, polyolefin polyol, and mixtures thereof; and a hydroxy-functional silicone poly(meth)acrylate; a second clear coat layer comprising a crosslinked polymer that is essentially free of hydroxy-functional silicone poly(meth)acrylate; a bulk layer comprising a thermoplastic polyurethane; and an adhesive layer. The provided films overcome the problem of migration of solvents and other impurities into the polyurethane bulk layer because the clear coat layer is cured, and solvents removed, prior to the coating of the polyurethane bulk layer. Manufacturing of these films can provide substantially faster line speeds and reduced waste.

A resin composition for coating an optical fiber is a resin composition comprising: a base resin containing an oligomer comprising urethane (meth)acrylate, a monomer, and a photopolymerization initiator; and hydrophobic zirconium oxide, wherein the content of the zirconium oxide is 0.5% by mass or more and 65% by mass or less based on the total amount of the resin composition.

A resin composition for coating an optical fiber is a resin composition comprising: a base resin containing an oligomer comprising urethane (meth)acrylate, a monomer, and a photopolymerization initiator; and hydrophobic zirconium oxide, wherein the content of the zirconium oxide is 0.5% by mass or more and 65% by mass or less based on the total amount of the resin composition.

The present invention provides alternative polyurethane composition comprising the reaction product of an azidated polyol and a poly(alkynyl carbamate) prepolymer, wherein the poly(alkynyl carbamate) prepolymer comprises the reaction product of a polyisocyanate, an alkynol, and an oxysilane. The reaction of the polyol and the prepolymer may occur in the presence of a catalyst or at a temperature of from 20° C. to 120° C. The inventive oxysilane and azido-alkyne hybrid click formulations provide comparable performance, and in some cases better performance, to/than urethane and azido-alkyne control click formulations in terms of pencil hardness, MEK double rubs, and glass transition temperature. The inventive alternative polyurethane compositions may be used to provide coatings, adhesives, sealants, films, elastomers, castings, and composites.

The present invention provides alternative polyurethane composition comprising the reaction product of an azidated polyol and a poly(alkynyl carbamate) prepolymer, wherein the poly(alkynyl carbamate) prepolymer comprises the reaction product of a polyisocyanate, an alkynol, and an oxysilane. The reaction of the polyol and the prepolymer may occur in the presence of a catalyst or at a temperature of from 20° C. to 120° C. The inventive oxysilane and azido-alkyne hybrid click formulations provide comparable performance, and in some cases better performance, to/than urethane and azido-alkyne control click formulations in terms of pencil hardness, MEK double rubs, and glass transition temperature. The inventive alternative polyurethane compositions may be used to provide coatings, adhesives, sealants, films, elastomers, castings, and composites.

Disclosed herein is a method for forming a multilayer coating film by sequentially coating an intermediate coating material composition, a base coating material composition and a clear coating material composition on a metal for a motor vehicle body or resin material and then thermally curing the compositions, where the clear coating material composition is obtained by mixing a main agent (A) and a curing agent (B).